高等学校化学学报

高等学校化学学报 ›› 1997, Vol. 18 ›› Issue (4): 652.

• 论文 • 上一篇    下一篇

一种合成共轭高分子──聚(N,N-二甲基苯胺)的新方法

郑海鹏, 张瑞丰, 沈家骢   

  1. 吉林大学化学系超分子结构与谱学开放实验室, 长春, 130023
  • 收稿日期:1996-04-25 出版日期:1997-05-24 发布日期:1997-05-24
  • 通讯作者: 郑海鹏. 女. 24岁, 博士研究生.
  • 作者简介:郑海鹏. 女. 24岁, 博士研究生.
  • 基金资助:

    国家自然科学基金

A New Method for the Synthesis of the Conjugated Polymer──Poly (N, N-dimethylaniline)

ZHENG Hai-Peng, ZHANG Rui-Feng, SHEN Jia-Cong   

  1. Key Lab.for Supramolecular Structure and Spectroscopy, Department of Chemistry, Jilin University, Changchun, 130023
  • Received:1996-04-25 Online:1997-05-24 Published:1997-05-24

PDF (PC)

被引次数

10

摘要： 利用一种新的合成方法,首次合成了测链带有强推电子性基团的聚苯衍生物——聚(N,N-二甲基苯胺).初步研究了中间产物的形成及这种固相聚合反应的适宜条件,并通过元素分析、红外、1H NMR及紫外光谱对聚会产物进行了结构表征.

关键词: 固相聚合, CT络合物, 聚(N, N-二甲基苯胺)

Abstract: This paper described a new synthetic method of a novel poly(phenylene) deriva-tive— poly(N, N-dimethylaniline) (PDMA) by forming a CTcomplex with monomer N,N-dimethylaniline and tetrachloro-p-quinone (TCQ).The CTcomplex was further studiedwhich could not only protect the side group (N,N-dimethyl), but also afford relatively lowenergy of activation in polymerization.The resulted polymer PDMAwas characterized by el-ementary analysis, FTIR, 1H NMRand UV-Vis spectra.The relationship between the spec-tra and its structure was also discussed.

Key words: Solid polymerization, CT complex, Poly(N, N-dimethylaniline)

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