高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (9): 1477.

• 论文 • 上一篇    下一篇

侧基上带有C60基团的聚苯乙烯的合成

汪长春, 舒昶, 府寿宽   

  1. 复旦大学高分子科学系, 上海, 200433
  • 收稿日期:1995-09-26 出版日期:1996-09-24 发布日期:1996-09-24
  • 通讯作者: 汪长春,男,31岁,讲师,博士研究生.
  • 作者简介:汪长春,男,31岁,讲师,博士研究生.
  • 基金资助:

    上海市青年教师基金

Synthesis of Polystyrene with C60 in the Side Group

WANG Chang-Chun, SHU Chang, FU Shou-Kuan   

  1. Department of Macromolecular Science, Fudan University, Shanghai, 200433
  • Received:1995-09-26 Online:1996-09-24 Published:1996-09-24

摘要: 采用三步连续反应(氯甲基化,叠氮化,环加成反应),成功地将C60引入聚苯乙烯的侧基上,并对每一步反应进行了较详细的讨论。

关键词: 氯甲基化, 叠氮化, 环加成反应, 聚苯乙烯C60衍生物, C60

Abstract: Three-step reactions,i.e.,chloromethylation,azidization and cycloaddition,were adopted to introduce C60 into the side group of polystyrene successfully, and each step reaction was discussed in detail.The products were proved to be extremely soluble in a variety of organic solvents such as CHCl3, THF, etc..This solubility behavior is simillar to polystyrene itself and totally unlike C60.

Key words: Chloromethylation, Azidization, Cycloaddition reaction, Polystyrene C60 derivatives, C60

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