二茂铁甲氨基烷氧基硅烷的合成与水敏感性研究

高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (11): 1725.

二茂铁甲氨基烷氧基硅烷的合成与水敏感性研究

李保国¹, 阿娟², 边占喜¹, 赵海英¹

1. 内蒙古大学化学系, 呼和浩特, 010021;
2. 内蒙古林学院基础部

收稿日期:1995-11-16 出版日期:1996-11-24 发布日期:1996-11-24
通讯作者: 李保国,男,38岁,讲师
作者简介:李保国,男,38岁,讲师
基金资助:
内蒙古自治区自然科学基金

Studies on Syntheses and Water Sensitivity of Ferrocenylmethylaminoalkoxy Silanes

LI Bao-Guo¹, A Juan², BIAN Zhan-Xi¹, ZHAO Hai-Ying¹

1. Department of Chemistry, Inner Mongolia University, Huhehaote, 010021;
2. Department of General Courses, Inner Mongolia Forestry College

Received:1995-11-16 Online:1996-11-24 Published:1996-11-24

摘要/Abstract

关键词: 二茂铁甲氨基烷氧基硅烷, 二茂铁甲氨基醇, 水敏感性

Abstract: The reaction between ferrocenylmethylaminoalcohols and chlorosilanes gave 12 compounds of ferrocenylmethylaminoalkoxy silanes in one-step method and in relatively good yield.The synthetic method and relationship between the water sensitivity and structures of the compounds were investigated.The experimental results show that both of the aminoalcohols FcCH₂NHCH(R')CH(R″)OH(Fc=C₅H₅FeC₅H₄,R'=H,C₂H₅;R″=H,CH₃)and chlorosilanes R(CH₃)₂SCl(R=CH₃,C₂H₅,n-C₃H₇,n-C₄H₉)have influnce on the reaction.The more bulky R,R'and R″,the smaller the reaction rate.The title compounds FcCH₂NHCH(R')CH(R″)OSi(CH₃)₂R,are relatively sensitive to water.The more bulky R,R'and R″,the more stable the compound to water.The structures were characterized by elementary analysis,IRand ¹H NMR.

Key words: Ferrocenylmethylaminoalkoxy silane, Ferrocenylmethylaminoalcohol, Water sensitivity

TrendMD:

李保国, 阿娟, 边占喜, 赵海英. 二茂铁甲氨基烷氧基硅烷的合成与水敏感性研究. 高等学校化学学报, 1996, 17(11): 1725.

LI Bao-Guo, A Juan, BIAN Zhan-Xi, ZHAO Hai-Ying. Studies on Syntheses and Water Sensitivity of Ferrocenylmethylaminoalkoxy Silanes. Chem. J. Chinese Universities, 1996, 17(11): 1725.