高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (10): 1589.

• 论文 • 上一篇    下一篇

三分子反应在—维介质上的动力学行为

万荣, 胡宏, 李如生   

  1. 清华大学化学系, 北京, 100084
  • 收稿日期:1995-10-09 出版日期:1996-10-24 发布日期:1996-10-24
  • 通讯作者: 万荣,男,23岁,本科五年级学生.
  • 作者简介:万荣,男,23岁,本科五年级学生.
  • 基金资助:

    国家自然科学基金

Dynamic Behavior of Trimolecular Reaction in One Dimension Medium

WAN Rong, HU Hong, LI Ru-Sheng   

  1. Department of Chemistry, Tsinghua University, Beijing, 100084
  • Received:1995-10-09 Online:1996-10-24 Published:1996-10-24

摘要: 提出了一种简明的理论分析方法,求出了三分子反应在一维介质上的动力学行为的解析解,并成功地解决了该反应动力学行为对初始条件的依赖性问题。还通过数值模拟证实了提出的理论方法的正确性。

关键词: 一维介质, 三分子反应, 化学动力学

Abstract: It is well known that the dynamic behavior of chemical reactions in fractional or low dimension medium is greatly different from that ruled by the classical chemical dynamics.In this paper,the anomalous dynamic behavior of trimolecular reaction Xin one dimension medium is studied.Anew theoretical method is developed,by which an analytical solution to the dynamic behavior of this reaction under different initial conditions is obtained.In addition,this new method is verified by the results based on some numerical simulations.

Key words: One dimension medium, Trimolecular reaction, Chemical kinetics

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