高等学校化学学报

高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (1): 97.

• 论文 • 上一篇    下一篇

多相催化剂的MOVS制备方法

何大森1, 许峰1, 赵雷洪1, 李似姣1, E. C. Alyea2   

  1. 1. 浙江师范大学化学系, 金华 321004;
    2. Guelph大学化学和生物化学系, 加拿大
  • 收稿日期:1995-01-28 出版日期:1996-01-24 发布日期:1996-01-24
  • 通讯作者: 何大森,男,51岁,副教授.
  • 作者简介:何大森,男,51岁,副教授.
  • 基金资助:

    国家教育委员会留学回国人员科研基金

MOVS Method for Preparation of Heterogeneous Catalysts

HE Da-Sen1, XU Feng1, ZHAO Lei-Hong1, LI Shi-Jiao1, E. C. Alyea2   

  1. 1. Department of Chemistry, Zhejiang Normal University, Jinhua 321004;
    2. Department of Chemistry & Biochemistry, University of Guelph, Canada NIG 2W1
  • Received:1995-01-28 Online:1996-01-24 Published:1996-01-24

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摘要： 介绍了非均相催化剂的MOVS制备方法。以该法制得的MoO3催化剂在甲醇选择氧化制甲醛、CO加氢制高级醇和喹啉加氢脱氮中均显示出比常规催化剂更为优异的催化性能,并探讨了MOVS催化剂的内在特性与催化性能的关系。

关键词: 催化剂制备, MOVS, 三氧化钼, 高级醇合成, HDN

Abstract: MOVS(Metal oxide vapour synthesis) method for preparation of heterogeneouscatalysts was described.The MoO3 based MOVScatalysts exhibited much higher activitiescompared to the analogous non- MOVScatalysts respectively in partial oxidation of methanolto formaldehyde,synthesis of higher alcohols or quinoline HDN.The relationship betweenthe catalytic behavior and intrinsic properties of MOVScatalysts and some aspects for application of the MOVSmethod were also discussed.

Key words: Preparation of catalysts, MOVS, MoO3, Synthesis of higher alcohols, HDN

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