高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (8): 1157.

• 研究简报 • 上一篇    下一篇

钒促铑基催化剂上合成气反应中的H2/D2同位素效应

汪海有, 刘金波, 傅锦坤, 蔡启瑞   

  1. 厦门大学化学系, 固体表面物理化学国家重点实验室, 厦门 361005
  • 收稿日期:1992-10-13 修回日期:1993-03-23 出版日期:1993-08-24 发布日期:1993-08-24
  • 通讯作者: 汪海有
  • 作者简介:第一作者:男, 29岁, 讲师.
  • 基金资助:

    国家自然科学基金

H2/D2 Isotope Effects in Syngas Conversion Reactions over Vanadium-promoted Rhodium Catalyst

WANG Hai-You, LIU Jin-Po, FU Jin-Kun, TSAI Khi-Rui   

  1. Department of Chemistry, State Key laboratory for Physical Chemistry of the Solid Surface, Xiamen University, Xiamen, 361005
  • Received:1992-10-13 Revised:1993-03-23 Online:1993-08-24 Published:1993-08-24

关键词: 钒助剂, 铑, 合成气, H2/D2同位素效应

Abstract: H2/D2 isotope effects in syngas conversion reactions over V-promoted rhodium catalyst were investigated by performing CO+H2 and CO+D2 reaction alternatively.Noticeable deuterium inverse isotope effects on hydrocarbons (including CH4, C2, C3, and C4) formation and on oxygenatesGncluding CH3OH,CH3CH2OH,CH3CHO) formation were simultaneously observed.

Key words: Vanadium promoter, Rh, Syngas, H2/D2 isotope effects

TrendMD: