高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (5): 636.

• 论文 • 上一篇    下一篇

系列类立方烷型Fe4S4簇合物的XPS分析

魏诠, 徐吉庆, 南玉明, 千吉松, 蔡辉, 闫英卓   

  1. 吉林大学化学系, 长春, 130023
  • 收稿日期:1991-03-29 出版日期:1992-05-24 发布日期:1992-05-24
  • 通讯作者: 魏诠

XPS Analysis of Cabane-like Fe4S4 Clusters

WEI Quan, XU Ji-qing, NAN Yu-ming, QIAN Ji-song, CAI Hui, YAN Ying-zhuo   

  1. Department of Chemistry, Jilin University, Changchun, 130023
  • Received:1991-03-29 Online:1992-05-24 Published:1992-05-24

摘要: 对7种类立方烷型Fe4S4簇合物进行了XPS分析,得到了中心离子Fe的价态,给出了系列Fe4S4中骨架硫的结合能,由峰合成结果给出各种S、N的比例与按结构式计算的结果相同。

关键词: 簇合物, 类立方烷结构, X光电子能谱

Abstract: The XPSof cabane-like Fe4S4 clusters were studied.The valence of Fe was examined, the 2p binding energy of the framework Sin Fe4S4 is first reported.The proportion of all sorts of Sand Nby peak synthesis is in agreement with the values obtained from the calculation on the basis of structure formulas.

Key words: Fe4S4 clusters, Cabane-like structure, X-ray photoelectron spectroscopy

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