高等学校化学学报 ›› 1991, Vol. 12 ›› Issue (6): 774.

• 论文 • 上一篇    下一篇

黄花木化学成分研究

刘自民, 贾忠建   

  1. 兰州大学有机化学研究所, 兰州, 730000
  • 收稿日期:1990-07-13 出版日期:1991-06-24 发布日期:1991-06-24
  • 通讯作者: 贾忠建
  • 基金资助:

    国家自然科学基金

Studies on the Chemical Constituents of Piptanthus Concolor Harrow

Liu Zi-min, Jia Zhong-jian   

  1. Institute of Organic Chemistryy, Lanzhou University, Lanzhou, 730000
  • Received:1990-07-13 Online:1991-06-24 Published:1991-06-24

摘要: 从黄花木中分离得到5种化合物,经化学和光谱方法鉴定它们为:野决明碱、安那吉碱、金雀花碱、β-谷甾醇及1新化合物5-α-羟基-7,17-脱氢异羽扇豆碱。研究结果表明,黄花木属、野决明属和沙冬青属植物在植物化学分类学上具有亲缘关系。

关键词: 黄花木, 豆科, 5-&alpha, -羟基-7, 17-脱氢异羽扇豆碱, 化学分类学

Abstract: From the whole plants of Piptanthus concolor Harrow(Leguminosae), a new alkaloid, 5-α-hydroxyl-7, 17-dehydroisolupanine (Ⅴ), and other four known compounds, thermopsine (Ⅰ), anagyrine (Ⅱ), cytisine (Ⅲ) and β-sitosterol (Ⅳ) were isolated. Their structures were identified on the basis of EIMS,1H NMR,13C NMR,DEPT, IRand UVdata and the comparison with the authentic samples. Meanwhile, the results of this study support the close relation among the genera, piptanthus, thermopsis and ammopiptanthus in chemotaxonomy.

Key words: Piptanthus concolor Harrow, Leguminoseae, 5-α-Hydroxyl-7,17-dehydroisolupanine, Chemotaxonomy

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