高等学校化学学报

高等学校化学学报 ›› 1991, Vol. 12 ›› Issue (4): 545.

• 论文 • 上一篇    下一篇

柏木醇与酚类化合物包合现象的研究

郭文生1, 卢在镐1, 郭长武2, 付兴吉2   

  1. 1. 辽宁师范大学化学系, 116022;
    2. 辽宁师范大学实验中心
  • 收稿日期:1989-09-04 出版日期:1991-04-24 发布日期:1991-04-24
  • 通讯作者: 郭文生
  • 基金资助:

    国家教育委员会优秀青年教师基金

A Study on the Inclusion Phenomena of Cedrol with Phenol Type Compounds

Guo Wen-sheng1, Lu Zhai-gao1, Guo Chang-wu2, Fu Xing-ji2   

  1. 1. Department of Chemistry, Linoning Normal University, Dalian, 116022;
    2. Centre of Experiment, Linoning Normal University, Dalian, 116022
  • Received:1989-09-04 Online:1991-04-24 Published:1991-04-24

PDF (PC)

被引次数

6

摘要： 分子包合物是主体分子和客体分子相互作用组成的复合物(又称为主客体化合物),具有独自的晶形和熔点。利用主体分子形成的空间特点可有效地识别客体分子,用于同分异构体的分离、光学拆分及立体选择性化学反应。

关键词: 包合物, 柏木醇, 酚类化合物

Abstract: It is reported that cedrol(1) complexed with phenol type compounds, such as phenol(2), o-cresol(3), w-cresol (4), p-cresol(5) and formed new clathrate compounds. Melting points of these crystal clathrate compounds, (l)+(2), (l)+(3), (1)+(4) and (1)+(5) are 54-56℃, 43- 44℃, 48-49℃ and 56-58℃, and their molar ratios(cedrol/phenol, in the same sequence) are 1: 1, 1: 1, 1: 0. 79, 1: 0. 77, respectively. The results of X-ray and IRof the inclusion compounds were given.

Key words: Clathrate compounds, Cedrol, Phenol type compound

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