高等学校化学学报

高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (8): 873.

• 研究论文 • 上一篇    下一篇

三烯丙基异氰尿酸酯交联共聚物的研究(Ⅱ)——醇解物的制备、结构及其性能

何炳林, 郭贤权, 杨志欣, 何丹, 史秀萍   

  1. 南开大学高分子化学研究所
  • 收稿日期:1989-04-15 出版日期:1990-08-24 发布日期:1990-08-24
  • 通讯作者: 何炳林
  • 基金资助:

    国家自然科学基金

Studies on Copolymers Crosslinked with Triallyl Isocyanurate ( Ⅱ )——Preparation, Structure and Properties of Saponified Copolymer

He Binglin, Guo Xianquan, Yang Zhixin, He Dan, Shi Xiuping   

  1. Institute of Polymer Chemistry, Nankai University, Tianjin
  • Received:1989-04-15 Online:1990-08-24 Published:1990-08-24

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摘要： 将醋酸乙烯酯与三烯丙基异氰尿酸酯共聚物进行皂化制得含有羟基和羧基盐的共聚物以增强共聚物的亲水性,用作气相色谱固定相,考察了不同交联度对皂化反应的影响,测定了皂化后共聚物的孔结构参数及溶胀性能,并对该固定相的色谱性能进行评价。

关键词: 醇解物, 皂化反应, 气相色谱固定相, 孔结构参数

Abstract: The copolymers possessing hydroxy and carboxyl groups were synthesized by saponifying the copolymers of vinyl acetatg and triallyl isocyanurate, and the effect of different degree of cross-linked copolymers on the saponification was investigated. Pore structure parameters and swelling capacity of these saponified copolymers were also determined. The saponified copolymers were used as the stationary phase in gas chromatography. Their gas chromatographic properties are preliminary evaluated.

Key words: Saponified copolymer, Saponification, Stationary phase in gas chromatography, Pore structure parameter

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