高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (7): 786.

• 研究简报 • 上一篇    下一篇

聚合介质酸度对聚苯胺的结构和性能的影响

苏致兴1, 刘向前1, 盛芬玲2   

  1. 1. 兰州大学化学系;
    2. 兰州大学测试中心
  • 收稿日期:1988-11-09 出版日期:1990-07-24 发布日期:1990-07-24
  • 通讯作者: 苏致兴

The Effect of Acidity of Polymerization Medium on Structures and Properties of Polyaniline

Su Zhixing1, Liu Xiangqian1, Sheng Fenling2   

  1. 1. Department of Chemistry, Lanzhou University, Lanzhou;
    2. Analysis Centre, Lanzhou University, Lanzhou
  • Received:1988-11-09 Online:1990-07-24 Published:1990-07-24

摘要: 不论电化学还是化学聚合,酸度对聚苯胺(PAn)的合成都有很大影响[1],说明只有在酸性条件下才能合成电活性的聚苯胺,鉴于聚合介质的酸度对聚苯胺的影响尚无详细的报道,本文研究了聚合介质酸度对聚苯胺的结构和性能的影响.

关键词: 聚苯胺, 高分子半导体, 共轭高分子

Abstract: In this paper, polyanilines were prepared by the chemical oxidation of aniline on different acidity conditions, their structures and properties and the relationship between them and the polymerization acidity were studied by IR, ESR, X-ray diffraction and so on. Asignificant result was obtained.

Key words: Polyaniline, Polymer semiconductor, Conjugate polymer

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