高等学校化学学报

高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (4): 431.

• 研究简报 • 上一篇    下一篇

电化聚合乙炔的研究

邭正伟, 乔亦男, 杨光, 沈之荃, 胡时昭, 周晓霞   

  1. 浙江大学化学系
  • 收稿日期:1988-07-22 出版日期:1990-04-24 发布日期:1990-04-24
  • 通讯作者: 邭正伟

Studies on Electrochemical Polymerization of Acetylene

Huan Zhengwei, Qiao Yinan, Yang Guang, Shen Zhiquan, Hu Shizhao, Zhou Xiaoxia   

  1. Department of Chemistry, Zhejitmg University, Hangzhou
  • Received:1988-07-22 Online:1990-04-24 Published:1990-04-24

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摘要： 电化学方法聚合乙炔报道甚少,且聚合条件较为苛刻[1],尚无人将Fe催化剂用于该反应。本文主要报道在Fe(NO3)3·9H2O-DMF溶液中,室温下恒以1mA/cm2左右的电流,在不锈钢阴极上聚合乙炔成膜,并经表征证实。

关键词: 聚乙炔, 掺Fe聚乙炔, 恒电流聚合

Abstract: Fe-doped polyacetylene film was prepared successfully on a stainless steel cathode by gal-vanostatic polymerization method at room temperature in Fe(NO3)3·9H2O-DMFsolution. The various factors affecting the polymerization process were investigated. Instrumental analyses show that the configuration of the film is mainly trans-(CH)z doped with Fe ca. 10% and the morphology of the film is polycrystals with a net texture.

Key words: Polyacetylene, Fe-doped polyacetylene, Galvanostatic polymerization

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