高等学校化学学报

高等学校化学学报 ›› 1990, Vol. 11 ›› Issue (11): 1286.

• 研究简报 • 上一篇    下一篇

多目标单纯形法研究催化动力学分析法的最优化设计

江海亮1, 李长风2, 阮大文3   

  1. 1. 江西省分析测试中心, 330029;
    2. 江西大学数学系;
    3. 浙江工学院化工系
  • 收稿日期:1989-06-28 出版日期:1990-11-24 发布日期:1990-11-24
  • 通讯作者: 江海亮

Optimizing Design for Investigation of Catalytic-Kinetic Analysis by Multi-Object Simplex Method

Jiang Hailiang1, Li Changfeng2, Yuan Dawen3   

  1. 1. Jiangxi Analysis and Test Centre, Nanchang, 330029;
    2. Department of Mathematics, Jiangxi University, Nanchang;
    3. Department of Chemistry, ZheJiang Institute of Technology, Hangzhou
  • Received:1989-06-28 Online:1990-11-24 Published:1990-11-24

PDF (PC)

被引次数

10

摘要： 催化动力学分析法灵敏度高、设备简单,近年来发展很快[1],本文提出了多目标单纯形方法,利用罚函数处理约束问题,通过对汞、银催化亚铁氰化钾和硫脲的反应测定汞、银。实验验证,多目标单纯形调优比单因素调优法速度快,表观摩尔吸光系数明显提高。

关键词: 催化动力学分析法, 单纯形法, 罚函数, 汞银

Abstract: An multi-object simplex method has been developed which shows promise as a method for accurate and rapid search of optimum conditions for catalytic kinetic analysis. This method is applied to two catalysed reaction systems in this paper. Compared with the single factor optimization, the number of experiments is reduced and the apparent molar absorptivity is increased by 30%～36%.

Key words: Catalytic-kinetic analysis, Simplex method, Penalty function, Mercury, Silver

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