高等学校化学学报 ›› 1989, Vol. 10 ›› Issue (12): 1257.

• 研究简报 • 上一篇    下一篇

手征性杂氮钛三环化合物的合成

刘汉兴, 尹承烈   

  1. 北京师范大学化学系
  • 收稿日期:1988-07-20 出版日期:1989-12-24 发布日期:1989-12-24
  • 通讯作者: 尹承烈
  • 基金资助:

    国家自然科学基金

Synthesis of Optically Active Titatranes

Liu Hanxing, Yin Chenglie   

  1. Department of Chemistry, Beijing Normal University, Beijing
  • Received:1988-07-20 Online:1989-12-24 Published:1989-12-24

关键词: 钛化合物, 氮杂环化合物, 不对称合成

Abstract: Six pairs of new optically active titatranes (Ⅱ) were synthesized by cyclization of acy-loxytriisopropyl titanate with (+) or (-)N,N-dihydroxyethyl-2-aminobutan-1-ol.Some of their physico-chemical constants, such as IR, 1H NMRand specific rotation were determined.

Key words: Titanium compound, Nitrogen heterocyclics, Asymmetric synthesis

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