高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (7): 735.

• 论文 • 上一篇    下一篇

一些不稳定Cp2TiAr2化合物在温和条件下的固氮研究

刘以寅, 曹晓民   

  1. 南开大学元素有机化学研究所
  • 收稿日期:1987-01-14 出版日期:1988-07-24 发布日期:1988-07-24
  • 通讯作者: 刘以寅
  • 基金资助:

    国家自然科学基金

Study on Nitrogen-Fixation Activity of Some Unstable Cp2TiAr2 Under Mild Conditions

Liu Yiyin, Cao Xiaomin   

  1. Institute of Elemento-Organio Chemistry, Nankai University, Tianjin
  • Received:1987-01-14 Online:1988-07-24 Published:1988-07-24

摘要: Shur等[1]曾对若干金属有机络合物如Cp2TiAr2的固氮作用进行了早朗研究。

关键词: 二芳基二茂钛, 固氮, 分子氮络合物

Abstract: The formation of some unstable Cp2TiAr2 (1) was proved by means of determination of produced X- ions in the reaction process. The nitrogen-fixation activity of Iunder room temperature and normal pressure was studied. Some of 1 show good nitrogen-fixation catalysis. The mechanism of ammonia formation is discussed.

Key words: Diaryl titanocene, Nitrogen-fixation, Molecular nitrogen complexes

TrendMD: