沸石分子筛的生成机理与晶体生长(Ⅻ)——ZSM-5沸石生成过程中液相硅酸根离子聚合态的研究

高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (10): 1071.

沸石分子筛的生成机理与晶体生长(Ⅻ)——ZSM_-5沸石生成过程中液相硅酸根离子聚合态的研究

马淑杰, 赵雪薇, 宋天佑, 丁红

吉林大学化学系

收稿日期:1987-03-20 出版日期:1988-10-24 发布日期:1988-10-24
通讯作者: 马淑杰

Studies on the Polisilicate Anions in the Liquid Phase During the Formation of ZSM-5 Type Zeolite

Ma Shujie, Zhao Xuewei, Song Tianyou, Ding Hong

Department of Chemistry, Jilin University, Changchun

Received:1987-03-20 Online:1988-10-24 Published:1988-10-24

摘要/Abstract

摘要： 自从1964年Lentz等人提出三甲基硅烷化(TMS)方法研究硅酸盐结构后,人们意识到这种方法能够较真按着地反映硅酸盐结构及聚合状态。又由于硅烷化所得的衍生物(硅酯)易溶于有机溶剂,可以采用多种方法进行分析鉴定。本文应用TMS-GLC及TMSGPC二种方法研究了ZSM-5沸石生成过程中液相硅酸根离子聚合状态的变化。

关键词: 三甲基硅烷化, 三甲基硅酯-气相色谱, 三甲硅酯-液相色谱

Abstract: In the system of 15Na₂O·Al₂O₃-50 SiO₂·5TPABr·3000H₂O, in which water glass was put as a source of SiO₂. The changes in concentration of SiO₂, and Al₂O₃ in the liquid phase of gel were investigated by the chemical analysis and ICP. The variations of amounts for various polysilicate anions in the liquid phase during the crystallzation of zeolite ZSM-5 were investigated by TMS-GLCand TMS-GPC. We used the electron micrograph to study particle size of solid phase. According to these results, liquid phase mechanism during the formation of ZSM-5 type zeolite has been proposed.

Key words: Trimethylsilylation, Trimethylsilvlation of gas chromatograph, Thime-thylsilylation of liquid chromatograph

TrendMD:

马淑杰, 赵雪薇, 宋天佑, 丁红. 沸石分子筛的生成机理与晶体生长(Ⅻ)——ZSM_-5沸石生成过程中液相硅酸根离子聚合态的研究. 高等学校化学学报, 1988, 9(10): 1071.

Ma Shujie, Zhao Xuewei, Song Tianyou, Ding Hong . Studies on the Polisilicate Anions in the Liquid Phase During the Formation of ZSM-5 Type Zeolite. Chem. J. Chinese Universities, 1988, 9(10): 1071.