高等学校化学学报

高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (4): 361.

• 论文 • 上一篇    下一篇

智能求解未知多元酸各级离解常数的研究

徐小马, 尤大衡   

  1. 华东化工学院化学系
  • 收稿日期:1985-11-28 出版日期:1987-04-24 发布日期:1987-04-24

A Study of Intelligent Evaluation for Dissociation Constants of Unknown Polybasic Acid

Xu Xiaoma, You Daheng   

  1. Department of Chemistry, East China Institute of Chemica Engineering, Shanghai
  • Received:1985-11-28 Online:1987-04-24 Published:1987-04-24

PDF (PC)

被引次数

8

摘要： 本文介绍了一种新的测定未知多元酸各级离解常数的通用方法。该方法实验上采用苛性碱电势滴定多元酸,计算上采用Gordon数学模型和单纯形最优化方法。并为此编制了一名为"GORDANACID"的计算机程序。

Abstract: A new mathematical model is described for deforming dissociation constants of unknown polybasic acids. The polybasic acids are titrated by caustic alkali potentiomctrically. The calculation is carried out by employing Gordon' s mathematical model and simplex optimization method, with a new computer programme "GORDANACID".

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