高等学校化学学报

高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (4): 359.

• 研究快报 • 上一篇    下一篇

BF3-H3PO4/ZrO2催化异丁烷和丁烯烷基化反应

温陵生, 李忆, 彭茵, 崔圣范, 孙中琦, 邹乐辉, 千载虎   

  1. 吉林大学化学系
  • 收稿日期:1986-11-07 出版日期:1987-04-24 发布日期:1987-04-24

BF3-H3PO4/ZrO2Catalyst for Isobutane-Butene Alkylation

Wen Lingsheng, Li Yi, Peng Yin, Cui Shengfan, Sun Zhongqi, Zhou Lehui, Qian Zaihu   

  1. Chemistry Department, Jilin University, Changchun
  • Received:1986-11-07 Online:1987-04-24 Published:1987-04-24

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摘要： BF3和H3PO4的分子化合物可用于异构烷烃和烯烃烷基化。BF3-H3PO4-SbF5可使异戊烷和乙烯烷基化得高辛烷值燃料,但这些都是液相酸,无现实意义。

Abstract: In this paper, isobutane-butene alkylation has been studied by using BF3-H3PO4/ZrO2 as a catalyst. It was found that the catalyst 404 showed high activity, selectivity and stability at 100℃, 1 atm. and with an isoparaffin to olefin ratio of 6.5:1.

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