双环戊二烯基二芳氧基钛的酸解反应

高等学校化学学报 ›› 1982, Vol. 3 ›› Issue (4): 495.

双环戊二烯基二芳氧基钛的酸解反应

刘以寅, 陈寿山

南开大学元素有机化学研究所

收稿日期:1981-06-19 出版日期:1982-12-24 发布日期:1982-12-24

ACIDOLYSIS REACTIONS OF BIS(CYCLOPEN-TADIENYL)-DI-(ARYLOXY)-TITANIUM

Liu Yiyin, Chen Shoushan

Institute of Elemento-Organic Chemistry, Nankai University, Tianjin

Received:1981-06-19 Online:1982-12-24 Published:1982-12-24

摘要/Abstract

摘要： 本文研究了双环戊二烯基二芳氧基钛于氢卤酸中的酸解反应。证明反应是分步进行的。因反应条件不同可得到二次酸解产物——双环戊二烯基二卤化钛或一次酸解产物——双环戊二烯基芳氧基卤化钛。对影响反应的诸因素进行了讨论。通过上述酸解反应合成了一系列新的双环戊二烯基芳氧基卤化钛,收率较高。由双环戊二烯基芳氧基卤化钛开始,又合成了几个新的Cp₂Ti(OAr)Ar＇及Cp₂Ti(OAr)(OAr＇)类型衍生物。

Abstract: Acidolysis reactions of bis-(cyclopentadienyl)-di-(aryloxy)-titanium were studied. It was proved that acidolysis reactions go step by step. According to the reaction conditions, the second-step acidolysis product, bis-(cyclopentadienyl)-titanium dihalides, and the first-step acidolysis product, bis-(cyclopentadienyl)-(aryloxy)-titanium halides, were obtained. Reaction conditions were discussed.Through above-mentioned reactions, a series of new bis-(cyclopentadi nyl)-(aryloxy)-titanium halides have been synthesized with good yields.Starting from bis-(cyclopentadienyl)-(aryloxy)-titanium halides, a few new derivatives with formulae Cp₂Ti(OAr)Ar and Cp₂Ti(OAr)(OAr') have prepared.

TrendMD:

刘以寅, 陈寿山. 双环戊二烯基二芳氧基钛的酸解反应. 高等学校化学学报, 1982, 3(4): 495.

Liu Yiyin, Chen Shoushan . ACIDOLYSIS REACTIONS OF BIS(CYCLOPEN-TADIENYL)-DI-(ARYLOXY)-TITANIUM. Chem. J. Chinese Universities, 1982, 3(4): 495.