电化学沉积制备光响应聚合物薄膜及其光信息存储应用

doi:10.7503/cjcu20180533

高等学校化学学报 ›› 2019, Vol. 40 ›› Issue (2): 358.doi: 10.7503/cjcu20180533

电化学沉积制备光响应聚合物薄膜及其光信息存储应用

赵瑞阳¹, 于春燕¹, 韩吉姝², 傅云磊¹, 李明¹, 胡德华³, 刘福胜¹()

1. 青岛科技大学化工学院, 青岛 266042
2. 青岛科技大学化学与分子工程学院, 青岛 266042
3. 华南理工大学发光材料与器件国家重点实验室, 广州 510641

收稿日期:2018-07-27 出版日期:2019-02-10 发布日期:2018-12-04
作者简介:
联系人简介: 刘福胜, 男, 博士, 教授, 主要从事精细化学品合成方面的研究. E-mail: liufusheng63@163.com
基金资助:
国家自然科学基金(批准号: 51703112)、山东省自然科学基金(批准号: ZR2017BEM040)和华南理工大学发光材料与器件国家重点实验室开放课题(批准号: 2017-skllmd-10)资助

Preparation of Photo-responsive Film by Electrochemical Deposition Method and the Application in Optical Information Storage^†

ZHAO Ruiyang¹, YU Chunyan¹, HAN Jishu², FU Yunlei¹, LI Ming¹, HU Dehua³, LIU Fusheng^1,^*()

1. College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
2. College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
3. State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510641, China

Received:2018-07-27 Online:2019-02-10 Published:2018-12-04
Contact: LIU Fusheng E-mail:liufusheng63@163.com
Supported by:
† Supported by the National Natural Science Foundation of China(No.51703112), the Shandong Provincial Natural Science Foundation, China(No.ZR2017BEM040) and the Open Fund of the State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, China(No.2017-skllmd-10)

摘要/Abstract

摘要：

设计并合成了一种具有较高电化学活性的偶氮苯类光响应前体小分子, 并用紫外-可见吸收光谱表征其顺反异构性质. 通过电化学沉积方法将小分子前驱体制成表面平整且高度交联的聚合物薄膜, 利用交联薄膜致密的堆积方式增强其稳定性. 以355 nm双干涉激光辐照薄膜, 使其发生光致图案化, 形成周期性强及结构完整的表面起伏光栅结构, 结果表明, 这种在高度交联光响应薄膜基础上形成的光致表面图案化在常用溶剂浸泡和较高温度加热时仍保持清晰的光栅结构, 具有较高的稳定性.

关键词: 偶氮苯, 光响应材料, 电化学沉积, 光致表面图案化

Abstract:

In order to improve the stability of photo-isomerization patterning of photo-responsive film based on azobenzene moiety, a new photo-responsive material based on azobenzene moiety with high electrochemical activity was designed and synthesized, named 1,2-bis(4-{[6-(9H-carbazol-9-yl)hexyl]oxy}phenyl)diazene(BHCzAzo) which exhibited a good photo-isomerization ability between trans-configuration and cis-configuration. BHCzAzo was prepared into a highly crosslinked polymer film without any crack or peeling on the surface using electrochemical deposition(ED) method due to the electrochemical activity of carbazole moiety in BHCzAzo. And the stability of the prepared film was enhanced in the result of the compact stacking mode of ED film. The film was irradiated with 355 nm interfering laser beam, and then a periodic pattern of photo-induced surface relief gratings was formed with good morphological surface. The photo-induced pattern was proved to possess high stability using the experiments of being immersed in different common solvent and heated at different temperature. The stability of photo-induced pattern was greatly enhanced by preparing cross-linked film with photo-responsive ability using ED method.

Key words: Azobenzene, Photo-responsive material, Electrochemical deposition, Photo-induced surface patterning

中图分类号:

O631.5

TrendMD:

赵瑞阳, 于春燕, 韩吉姝, 傅云磊, 李明, 胡德华, 刘福胜. 电化学沉积制备光响应聚合物薄膜及其光信息存储应用. 高等学校化学学报, 2019, 40(2): 358.

ZHAO Ruiyang,YU Chunyan,HAN Jishu,FU Yunlei,LI Ming,HU Dehua,LIU Fusheng. Preparation of Photo-responsive Film by Electrochemical Deposition Method and the Application in Optical Information Storage^†. Chem. J. Chinese Universities, 2019, 40(2): 358.

图/表 10

Scheme 1 Synthesis routes of electrochemical deposition(ED) precursor BHCzAzo

Fig.1 TGA(A) and DSC(B) curves of BHCzAzo recorded at a heating rate of 10 K/min

Fig.2 UV-Vis spectra of BHCzAzo solution irradiated by light in different time(A) Irradiated by 355 nm light. Time/s: a. 0; b. 1; c. 2; d. 5; e. 10. (B) Irradiated time by natural light. a. PSS; b. 1 min; c. 10 min; d. 20 min; e. 40 min; f. 120 min.

Fig.3 Multiple cycles of cis-trans isomerization of BHCzAzo THF solution under 355 nm UV light and natural light

Fig.4 CV curves of BHCzAzo in ED process with 40 cycles

Fig.5 SEM(A) and AFM(B) images of BHCzAzo ED film

Fig.6 FTIR spectra of BHCzAzo powder(a) and ED film(b)

Fig.7 N1s XPS spectra of BHCzAzo spin coated film(a) and ED film(b)

Fig.8 SEM(A) and AFM(B) images of BHCzAzo ED film after being irradiated by 355 nm interfering laser beam for 5 s(C, D) AFM images of erased photo-induced pattern after being irradiated by 480 nm laser beam for 5 min(C) and 10 min(D).

Fig.9 SEM images of photo-induced SRG patterns with different handling methods(A) CH2Cl2(DMF, THF, toluene), 30 min; (B) H2O(pH=3—10), 30 min; (C) 30—80 ℃, 30 min; (D) 90 ℃, 30 min.

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电化学沉积制备光响应聚合物薄膜及其光信息存储应用

Preparation of Photo-responsive Film by Electrochemical Deposition Method and the Application in Optical Information Storage^†

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电化学沉积制备光响应聚合物薄膜及其光信息存储应用

Preparation of Photo-responsive Film by Electrochemical Deposition Method and the Application in Optical Information Storage†

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Preparation of Photo-responsive Film by Electrochemical Deposition Method and the Application in Optical Information Storage^†