金银微纳结构的激光加工

doi:10.7503/cjcu20150109

高等学校化学学报 ›› 2015, Vol. 36 ›› Issue (8): 1472.doi: 10.7503/cjcu20150109

• 研究论文: 无机化学 • 上一篇下一篇

金银微纳结构的激光加工

周颖^1,², 徐颖¹(), 刘连庆², 杨海³, 王继萍⁴()

1. 吉林大学电子科学与工程学院, 集成光电子学国家重点联合实验室, 长春130012
2. 中国科学院沈阳自动化研究所机器人学国家重点实验室, 沈阳110016
3. 北京有色金属研究总院, 北京100088
4. 吉林大学第一附属临床医院, 长春130012

收稿日期:2015-02-02 出版日期:2015-08-10 发布日期:2015-07-17
作者简介:联系人简介: 徐颖, 女, 博士, 副教授, 主要从事飞秒激光微纳加工研究. E-mail:xuying1969@hotmail.com; 王继萍, 女, 博士, 副教授, 主任医师, 主要从事微纳生物学及临床医学研究. E-mail:546223809@qq.com
基金资助:
国家自然科学基金(批准号: 61378053)和机器人学国家重点实验室开放课题(批准号: 51373064)资助

Direct Femtosecond Laser Processing of Gold-silver Alloy Nanostructure by Photoreduction^†

ZHOU Ying^1,², XU Ying^1,^*(), LIU Lianqing², YANG Hai³, WANG Jiping^4,^*()

1. State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, China
2. State Key Laboratory of Robotics, Shenyang Institute of Automation,Chinese Academy of Sciences, Shenyang 110016, China
3. General Research Institute for Nonferrous Metals, Beijing 100088, China
4. The First Affiliated Hospital of Jilin University, Changchun 130012, China

Received:2015-02-02 Online:2015-08-10 Published:2015-07-17
Contact: XU Ying,WANG Jiping E-mail:xuying1969@hotmail.com;546223809@qq.com
Supported by:
† Supported by the National Natural Science Foundation of China(No.61378053) and the Foundation of State Key Laboratory of Robotics of China(No.51373064)

摘要/Abstract

摘要：

将飞秒激光聚焦于双金属甲苯离子前驱体溶液, 在衬底上还原出可任意精细图案化的金银微纳结构. 研究了不同比例离子前驱体溶液对加工的微纳结构中金银比例的影响. 所得双金属微纳结构保留了金属材料的性质, 在定点催化中表现出很好的催化效果.

关键词: 双金属微纳结构, 金银合金, 飞秒激光加工, 图案化

Abstract:

Gold-silver(Au-Ag) alloy nanostructures were fabricated on substrate by the highly intense femtosecond laser pulses through a wet photochemical reduction without introducing additional reducing agent. The nanostructures can not only retain the characteristic of metallic materials, but also realize the assembling pattern of arbitrary subtle shape. The formation of Au-Ag alloy nanostructures was confirmed by energy dispersive X-ray(EDX) diffraction, indicating the fabricated nanostructures were different in the ratio of gold to silver for different molar ratios in the solution. The composite metal material was applied for catalysis of hydrogen pero-xide and an ideal result was achieved.

Key words: Bimetallic nanostrueture, Au-Ag alloy, Femtosecond laser fabrication, Pattern

中图分类号:

O614.12
O644

TrendMD:

周颖, 徐颖, 刘连庆, 杨海, 王继萍. 金银微纳结构的激光加工. 高等学校化学学报, 2015, 36(8): 1472.

ZHOU Ying, XU Ying, LIU Lianqing, YANG Hai, WANG Jiping. Direct Femtosecond Laser Processing of Gold-silver Alloy Nanostructure by Photoreduction^†. Chem. J. Chinese Universities, 2015, 36(8): 1472.

图/表 8

Fig.1 Schematic illustration for femtosecond laser direct writing co-reduced assembly Au-Ag alloy nanostructure

Fig.2 SEM images of Au20 alloy wires of different widths prepared under different laser powerLaser power/mW: (A) 4; (B) 6; (C) 8; (D) 10; (E) 12.

Fig.3 Dependence of wire width on the laser power

Fig.4 SEM images of Au20 alloy nanostructures with different magnifications

Fig.5 EDS characterization of Au20 alloy nanostructures(A) The scanning area of Au20 alloy nanostructures; (B) the whole distribution of all selected elements;(C)—(F) the elemental distribution of C(C), O(D), Ag(E), Au(F).

Fig.6 EDX characterization of Au20(A), Au50(B), Au80(C) and Au/Ag ratio of Au-Ag alloy nanostructures before and after laser processing(D)

Fig.7 SEM images of different laser patterned Au-Ag alloy micropatterns from ionic precursor solution (A) Red cross logo; (B) Santa head; (C) saving water mark; (D) cartoon cow.

Fig.8 Catalytic performance of Au-Ag alloy for H2O2(30%) degraelationOptical microscopy images of bubble motion with the reaction time of 3 s(A), 6 s(B), 9 s(C) and 12 s(D).

参考文献 30

[1]	Li C. C., Sun L., Sun Y. Q., Teranishi T., Chem. Mater., 2013, 25(13), 2580—2590
[2]	Gao B. R., Wang H. Y., Hao Y. W., Fu L. M., Fang H. H., Jiang Y., Wang L., Chen Q. D., Xia H., Pan L. Y., Ma Y. G., Sun H. B., J. Phys. Chem. B, 2010, 114(1), 128—134
[3]	Chen L., Zhu Y., Zang X., Cai B., Li Z., Xie L., Zhuang S., Light Sci. Appl., 2013, 2, e60
[4]	Kim S., Piao L., Han D., Kim B. J., Chung T. D., Adv. Mater., 2013, 25(14), 2056—2061
[5]	Chen L. M., Chabu M. J., Liu Y. N., RSC Adv., 2013, 3(13), 4391—4399
[6]	Xu B. B., Zhang R., Liu X. Q., Wang H., Zhang Y. L., Jiang H. B., Wang L., Ma Z. C., Ku J. F., Xiao F. S., Sun H. B., Chem. Commun., 2012, 48(11), 1680—1682
[7]	Liu D. L., Zhao Q., Lu D. F., Qi Z. M., Chem. J. Chinese Universities, 2014, 35(10), 2207—2213
	(刘德龙, 赵乔, 逯丹凤, 祁志美. 高等学校化学学报, 2014, 35(10), 2207—2213)
[8]	Wang D. S., Li Y. D., Adv. Mater., 2011, 23(9), 1044—1060
[9]	Yu C. L., Li G., Kumar S., Yang K., Jin R. C., Adv. Mater., 2013, 26(6), 892—898
[10]	Li W. Z., Kuai L., Qin Q., Geng B. Y., J. Mater. Chem. A, 2013, 1(24), 7111—7117
[11]	Ge X. B., Chen L. Y., Kang J. L., Fujita T., Hirata A., Zhang W., Jiang J. H., Chen M. W., Adv. Funct. Mater., 2013, 23(33), 4156—4162
[12]	Herbani Y., Nakamura T., Sato S., J. Phys. Chem. C, 2011, 115(44), 21592—21598
[13]	Feng J., Li F., Gao W. B., Liu S. Y., Liu Y., Wang Y., Appl. Phys. Lett., 2001, 78(25), 3947—3949
[14]	Guo L., Zhang Y. L., Shao R. Q., Xie S. Y., Wang J. N., Li X. B., Jiang F., Jiang H. B., Chen Q. D., Zhang T., Sun H. B., Carbon, 2012, 50(4), 1667—1673
[15]	Yang R., Yu Y. S., Xue Y., Chen C., Chen Q. D., Sun H. B., Opt. Lett., 2011, 36(23), 4482—4484
[16]	Wu D., Chen Q. D., Niu L. G., Wang J. N., Wang J., Wang R., Xia H., Sun H. B., Lab Chip, 2009, 9(16), 2391—2394
[17]	Xu B. B., Zhang R., Wang H., Liu X. Q., Wang L., Ma Z. C., Chen Q. D., Xiao X. Z., Han B., Sun H. B., Nanoscale, 2012, 4(22), 6955—6958
[18]	Zhang Y. L., Chen Q. D., Xia H., Sun H. B., Nano Today, 2010, 5(5), 435—448
[19]	Sun Y. L., Dong W. F., Niu L. G., Jiang T., Liu D. X., Zhang L., Wang Y. S., Kim D. P., Chen Q. D., Sun H. B., Light Sci. Appl., 2014, 3, e129
[20]	Wu D., Xu J., Niu L. G., Wu S. Z., Midorikawa K., Sugioka K., Light Sci. Appl., 2015, 4, e228
[21]	Zhang R., Lü C., Xiao X. Z., Luo Y., Xu Y., Chem. J. Chinese Universities, 2014, 35(3), 471—475
	(张然, 吕超, 肖鑫泽, 骆杨, 徐颖. 高等学校化学学报, 2014, 35(3), 471—475)
[22]	Zhang Y. L., Guo L., Wei S., He Y. Y., Xia H., Chen Q. D., Sun H. B., Xiao F. S., Nano Today, 2010, 5(1), 15—20
[23]	Yang J., Sargent E. H., Kelley S. O., Ying J. Y., Nat. Mater., 2009, 8(8), 683—689
[24]	Xu B. B., Zhang Y. L., Xia H., Dong W. F., Ding H., Sun H. B., Lab Chip, 2013, 13(9), 1677—1690
[25]	Xu B. B., Zhang Y. L., Wei S., Ding H., Sun H. B., Chem. Cat. Chem., 2013, 5(8), 2091—2099
[26]	Wu D., Wang J. N., Wu S. Z., Chen Q. D., Zhao S., Zhang H., Sun H. B., Jiang L., Adv. Funct. Mater., 2011, 21(15), 2927—2932
[27]	Zhao G. J., Wang H., Khezri B., Webster R. D., Pumera M., Lab Chip, 2013, 13(15), 2937—2941
[28]	Wang W., Castro L. A., Hoyos M., Mallouk T. E., ACS Nano, 2012, 6(7), 6122—6132
[29]	Wu D., Wu S. Z., Chen Q. D., Zhang Y. L., Yao J., Yao X., Niu L. G., Wang J. N., Jiang L., Sun H. B., Adv. Mater., 2011, 23(4), 545—549
[30]	Xia H., Wang J., Tian Y., Chen Q. D., Du X. B., Zhang Y. L., He Y., Sun H. B., Adv. Mater., 2010, 22(29), 3204—3207

金银微纳结构的激光加工

Direct Femtosecond Laser Processing of Gold-silver Alloy Nanostructure by Photoreduction^†

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金银微纳结构的激光加工

Direct Femtosecond Laser Processing of Gold-silver Alloy Nanostructure by Photoreduction†

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Direct Femtosecond Laser Processing of Gold-silver Alloy Nanostructure by Photoreduction^†