基于连续弯液面构筑的有序阵列模板复制模塑制备图案化聚合物薄膜

doi:10.7503/cjcu20150545

高等学校化学学报 ›› 2016, Vol. 37 ›› Issue (2): 388.doi: 10.7503/cjcu20150545

基于连续弯液面构筑的有序阵列模板复制模塑制备图案化聚合物薄膜

贾若琨¹(), 杨晓航¹, 龙智云², 何蕾茵¹, 王盼新², 张凌云¹, 赵明²

1. 东北电力大学化学工程学院, 吉林 132012
2. 哈尔滨工业大学市政环境工程学院, 哈尔滨 150090

收稿日期:2015-07-14 出版日期:2016-02-10 发布日期:2015-10-19
作者简介:联系人简介: 贾若琨, 男, 博士, 教授, 主要从事材料物理化学方面研究. E-mail:jiaruokun@mail.nedu.edu.cn
基金资助:
国家自然科学基金(批准号: 51003010)和吉林省科技发展计划项目(批准号: 20140101090JC)资助

Fabrication of Patterned Polymer Membrane Through Replica Molding Technology Templated by Ordered Array from Continuous Meniscus^†

JIA Ruokun^1,^*(), YANG Xiaohang¹, LONG Zhiyun², HE Leiyin¹, WANG Panxin², ZHANG Lingyun¹, ZHAO Ming²

1. College of Chemical Engineering, Northeast Dianli University, Jilin 132012, China
2. School of Municipal and Environment Engineering, Harbin Institude of Technology, Harbin 150090, China

Received:2015-07-14 Online:2016-02-10 Published:2015-10-19
Contact: JIA Ruokun E-mail:jiaruokun@mail.nedu.edu.cn
Supported by:
† Supported by the National Natural Science Foundation of China(No.51003010) and the Science and Technology Development Program of Jilin Province, China(No.20140101090JC)

摘要/Abstract

摘要：

基于咖啡环理论, 利用微米尺度限制下的弯液面溶剂散逸过程获得表面微结构可控的有序阵列, 以此为母模板制备聚二甲基硅氧烷(PDMS)弹性印章, 通过复制模塑过程实现阵列结构转移. 利用广义Young-Laplace方程建立的理论模型分析弯液面聚合物沉积黏连过程, 推导出条纹沉积频率与聚合物分子量、基底滑动速率和溶液浓度的关系, 理论计算结果与实验现象一致.

关键词: 弯液面, 有序阵列, 母模板, 复制模塑技术, 图案化聚合物薄膜

Abstract:

Replica molding technology has a reproducible and high-resolution advantage in fabrication of polymer patterns with the feature sizes of sub-micrometer to micrometer. It is critically desirable to develop a low cost and rapid route for building the initialtemplate. In this report, ordered array which could achieve morphological control was continuously supplied from solvent evaporation-driven process in a micron spacing gap by the coffee-stain theory. We use the patterned array as a mother setof the pattern definition of the soft moldpolydimethylsiloxane(PDMS) and obtain transferred patterns through replica molding technology. We also explore the polymer deposition periodically based on the theoretical model of Young-Laplace equation. The results demonstrate that the deposition frequency is influened by molecular weight of polymer, sliding speed of glass plate and concentration of solution. Trends predicted by these calculations agree with experimental behavior.

Key words: Meniscus, Ordered array, Initial template, Replica molding technology, Patterned polymer membrane

中图分类号:

O631

TrendMD:

贾若琨, 杨晓航, 龙智云, 何蕾茵, 王盼新, 张凌云, 赵明. 基于连续弯液面构筑的有序阵列模板复制模塑制备图案化聚合物薄膜. 高等学校化学学报, 2016, 37(2): 388.

JIA Ruokun, YANG Xiaohang, LONG Zhiyun, HE Leiyin, WANG Panxin, ZHANG Lingyun, ZHAO Ming. Fabrication of Patterned Polymer Membrane Through Replica Molding Technology Templated by Ordered Array from Continuous Meniscus^†. Chem. J. Chinese Universities, 2016, 37(2): 388.

图/表 9

Fig.1 Experimental set-up for the polymer solutions in a micron spacing gap

Fig.2 SEM images of dot(A) and stripe(B) PS patterns

Fig.3 SEM images of PS stripe patterns (A) Low sliding speed(20 μm/s); (B) high sliding speed(50 μm/s).

Fig.4 SEM images of PDDT dot paterns (A) Low-magnification; (B) high-magnification.

Fig.5 SEM images of PDDT stripe paterns (A, B) PDDT of chloroform solution(0.1 g/L); (C, D) PDDT of chloroform solution(0.5 g/L); (A, C) Low-magnification; (B, D) high-magnification.

Fig.6 SEM images of PDMS negative mold (A) Shrunken pattern(without press); (B) stripe pattern(with press).

Fig.7 SEM images of PB initial(A) and shrunken(B) patterns

Fig.8 Process of evaporation-driven polymer deposition by the coffee-stain theory

Fig.9 Theoretical model of solvent evaporation-driven polymer deposition

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基于连续弯液面构筑的有序阵列模板复制模塑制备图案化聚合物薄膜

Fabrication of Patterned Polymer Membrane Through Replica Molding Technology Templated by Ordered Array from Continuous Meniscus^†

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基于连续弯液面构筑的有序阵列模板复制模塑制备图案化聚合物薄膜

Fabrication of Patterned Polymer Membrane Through Replica Molding Technology Templated by Ordered Array from Continuous Meniscus†

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Fabrication of Patterned Polymer Membrane Through Replica Molding Technology Templated by Ordered Array from Continuous Meniscus^†