水下超疏油聚(3,4-乙烯基二氧)噻吩薄膜的制备

doi:10.7503/cjcu20130800

高等学校化学学报 ›› 2014, Vol. 35 ›› Issue (1): 98.doi: 10.7503/cjcu20130800

水下超疏油聚(3,4-乙烯基二氧)噻吩薄膜的制备

刘兆元¹, 丁春梅¹, 朱英¹(), 万梅香², 江雷^1,²

1. 北京航空航天大学, 仿生界面科学与技术教育部重点实验室, 化学与环境学院, 北京 100191
2. 中国科学院化学研究所, 北京分子科学国家实验室, 北京 100190

收稿日期:2013-08-19 出版日期:2014-01-10 发布日期:2013-12-04
作者简介:联系人简介: 朱英, 女, 博士, 教授, 博士生导师, 主要从事导电聚合物微纳米材料的研究. E-mail:zhuying@buaa.edu.cn
基金资助:
国家“八六三”计划(批准号: 2012AA030305)、国家“九七三” 计划(批准号: 2012CB933200)、国家自然科学基金(批准号: 51273008, 20974006)和中央高校基本科研业务费专项资金(批准号: YWF-10-01-B16))资助

Electrochemical Synthesis of Micro/nanostructured Poly(3,4-ethylenedioxythiophene) Films with Underwater Superoleophobicity^†

LIU Zhaoyuan¹, DING Chunmei¹, ZHU Ying^1,^*(), WAN Meixiang², JIANG Lei^1,²

1. Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education,School of Chemistry and Environment, Beihang University, Beijing 100191, China
2. Beijing National Laboratory for Molecular Sciences, Institute of Chemistry,Chinese Academy of Sciences, Beijing 100190, China

Received:2013-08-19 Online:2014-01-10 Published:2013-12-04
Contact: ZHU Ying E-mail:zhuying@buaa.edu.cn
Supported by:
† Supported by the National High Technology Research and Development Program of China(No.2012AA030305), the National Program on Key Basic Research Project of China (No.2012CB933200), the National Natural Science Foundation of China(No.51273008) and the Fundamental Research Funds for the Central Universities of China(No.YWF-10-01-B16)

摘要/Abstract

摘要：

以离子液体溴化(1-己基-3-甲基咪唑盐)作为电解质和掺杂剂采用电化学一步法制备了微纳米复合结构的聚(3,4-乙烯基二氧噻吩)薄膜, 薄膜由槽内排布着纳米珠链的棒状结构组成. 研究表明, 通过控制电流密度的大小, 可以调节棒状结构和珠状结构的平均直径. 离子液体中的咪唑阳离子和对阴离子均掺杂到聚合物中, 该薄膜具有可逆的电化学活性及水下超疏油特性.

关键词: 聚(3, 4-乙烯基二氧噻吩)薄膜, 离子液体, 微/纳米结构, 水下超疏油

Abstract:

Micro/nanostructured poly(3,4-ethylenedioxythiophene)(PEDOT) films were fabricated by an electrochemical polymerization in the presence of ionic liquid(1-hexyl-3methyllimidazolium bromide) as the electrolyte and dopants. The PEDOT films consist of micro-rod structures that encompass the micro-groove structure, and the nano-chain structure arranged inside of the micro-groove structure. The width of micro-grooves and the beads on the nano-chains can be adjusted by changing the current density of polymerization. The results showed that PEDOT chain backbone was doped by both the anion(Br^-) and cation(imidazolium) of ionic liquids. In addition, PEDOT film exhibited reversible electrochemical activity and underwater superoleophobic properties, which could be used for the application of the underwater anti-fouling coating and controlled oil-water separation materials.

Key words: Poly(3, 4-ethylenedioxythiophene) film, Ionic liquid, Micro/nanostructure, Underwater superoleophobicity

中图分类号:

O647
O631

TrendMD:

刘兆元, 丁春梅, 朱英, 万梅香, 江雷. 水下超疏油聚(3,4-乙烯基二氧)噻吩薄膜的制备. 高等学校化学学报, 2014, 35(1): 98.

LIU Zhaoyuan, DING Chunmei, ZHU Ying, WAN Meixiang, JIANG Lei. Electrochemical Synthesis of Micro/nanostructured Poly(3,4-ethylenedioxythiophene) Films with Underwater Superoleophobicity^†. Chem. J. Chinese Universities, 2014, 35(1): 98.

图/表 7

Fig.1 SEM images of the PEDOT micro/nanostructures prepared at different current densitiesCurrent density/(mA·cm-2): (A)—(C) 0.5; (D)—(F) 0.6; (G)—(I) 0.7; (J)—(L) 0.8.

Fig.2 XPS spectra of PEDOT(A) Full spectrum; (B) C1s spectrum; (C) S2p spectrum.

Fig.3 UV-Vis spectrum of the PEDOT dissolved in DMSO

Fig.4 XRD pattern of PEDOT

Fig.5 SEM images of the micro/nanostructured PEDOT films prepared at different polymerization timePolymerization time/h: (A), (B) 0.5; (C) 1; (D) 2. Current density: 0.5 mA/cm2.

Fig.6 Proposed mechanism for the formation of PEDOT micro/nanostructures

Fig.7 Cyclic voltammogram of PEDOT film with a scanning rate of 50 mV/s(A), photographs of a water droplet on the PEDOT film in air(B, CA=48.3°) and an oil droplet on the PEDOT film under water(C, CA=151.6°)

参考文献 31

[1]	King A. Z., Shaw C. M., Spanning A. S., Martin D. C., Polymer, 2011, 52(5), 1302—1308
[2]	Zheng H. J., Jiang Y. D., Xu J. H., Yang Y. J., Chem. J. Chinese Universities, 2010, 31(8), 1665—1670
	(郑华靖, 蒋亚东, 徐建华, 杨亚杰.高等学校化学学报, 2010,31(8), 1665—1670)
[3]	Kim Y. H., Sachse C., Machala M. L., May C., Meskamp M. L., Leo K., Adv. Funct. Mater., 2011, 21(6), 1076—1081
[4]	Patra S., Munichandraia N., J. Appl. Polym. Sci., 2007, 106(2), 1160—1171
[5]	Jeong Y. S., Akagi K., Macromolecules, 2011, 44(8), 2418—2426
[6]	Radhakrishnan S., Sumathi C., Umar A., Jae K. S., Wilson J., Dharuman V., Biosens. Bioelectron., 2013, 47, 133—140
[7]	Kateb M., Ahmadi V., Mohseni M., Sol. Energy Mater. Sol. Cell, 2013, 112, 57—64
[8]	Chen S. Y., Pei W. H., Gui Q., Tang R. Y., Chen Y. F., Zhao S. S., Wang H., Chen H. D., Sens. Actuators. A: Physical, 2013, 193, 141—148
[9]	Zhou C. F., Liu Z. W., Yan Y. S., Du X. S., Mai Y. W., Ringer S., Nanoscale Res. Lett., 2011, 6, 364
[10]	Jin L., Wang T., Feng Z. Q., Leach M. K., Wu J. H., Mo S. J., Jiang Q., J. Mater. Chem. B, 2013, 1(13), 1818—1825
[11]	Zheng H. J., Jiang Y. D., Xu J. H., Yang Y. J., Chem. J. Chinese Universities, 2008, 29(10), 2040—2043
	(郑华靖, 蒋亚东, 徐建华, 杨亚杰.高等学校化学学报, 2008,29(10), 2040—2043)
[12]	Poverenov E., Li M., Bitler A., Bendikov M., Chem. Mater., 2010, 22(13), 4019—4025
[13]	Charlotte A. C., Mohamed B., Tae-Sik K., Reynolds J. R., Macromolecules, 2005, 38(8), 3068—3074
[14]	Kumar A., Reynolds J. R., Macromolecules, 1996, 29( 23), 7629—7630
[15]	Spain E., Keyes T. E., Forster R. J., Biosens. Bioelectron., 2013, 41, 65—70
[16]	Lu B. Y., Lu Y., Wen Y. P., Duan X. M., Xu J. K., Chen S. A., Zhang L., Int. J. Electrochem. Sci., 2013, 8(2), 2826—2841
[17]	Pozo G., Marcilla R., Salsamendi M., Mecerreyes D., Pomposo J. A., Rodriguez J., Bolink H. J., J. Polym. Sci. Part A, Polym. Chem., 2008, 46, 3150—3154
18	[18] Liu K. K., Hu Z. G., Xue R., Zhang J. R., Zhu J. J., J. Power Sources, 2008, 179(2), 858—862
[19]	Ahmad S., Deepa M., Singh S., Langmuir, 2007, 23(23), 11430—11433
[20]	Xue Z.X., Jiang L., Acta Polymerica Sinica, 2012,(10), 1091—1101
	(薛众鑫, 江雷. 高分子学报, 2012,(10), 1091—1101)
[21]	Liu M. J., Wang S. T., Wei Z. X., Song Y. L., Jiang L., Adv. Mater., 2009, 21(6), 665—669
[22]	Ding C. M., Zhu Y., Liu M. J., Feng L., Wan M. X., Jiang L., Soft Matter, 2012, 8(35), 9064—9068
[23]	Döbbelin M., Tena-Zaera R., Marcilla R., Iturri J., Adv. Funct. Mater., 2009, 19(20), 3326—3333
[24]	Patil A. O., Heeger A. J., Wudlf F., Chem. Rev., 1988, 88(1), 183—200
[25]	Cornil J., Bredas J. L., Adv. Mater, 1995, 7(3), 295—297
[26]	Aasmundtveit K. E., Samuelsent E. J., Pettersson L. A. A., Inganas O., Johansson T., Feidenhans R., Synth. Met., 1999, 101(1—3), 561—564
[27]	Han M. G., Foulger S. H., Small, 2006, 10(2), 1164—1169
[28]	Zotti G., Zecchin S., Macromolecules, 2003, 36( 9 ), 3337—3344
[29]	Kiya Y., Iwata A., Sarukawa T., Henderson J. C., Abruna H. D., J. Power Sources, 2007, 173(1), 522—530
[30]	Lide D.R., CRC Handbook of Chemistry and Physics, 73rd, CRC Press, Boca Raton, FL, USA, 1992—1993, 364—369
[31]	Popov A., Borisova A., J. Colloid Interface Sci., 2001, 236(1), 20—27

水下超疏油聚(3,4-乙烯基二氧)噻吩薄膜的制备

Electrochemical Synthesis of Micro/nanostructured Poly(3,4-ethylenedioxythiophene) Films with Underwater Superoleophobicity^†

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水下超疏油聚(3,4-乙烯基二氧)噻吩薄膜的制备

Electrochemical Synthesis of Micro/nanostructured Poly(3,4-ethylenedioxythiophene) Films with Underwater Superoleophobicity†

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Electrochemical Synthesis of Micro/nanostructured Poly(3,4-ethylenedioxythiophene) Films with Underwater Superoleophobicity^†