Loading...
Toggle navigation
CJCU
Home
About Journal
Editorial Board
Editorial Board
Youth Executive Editorial Board
Editorial Introduction
Guide for Author
Journal
Forthcoming Articles
Asap
Current Issue
Archive
Most Download Articles
Most Read Articles
Most Cited Articles
Email Alert
RSS
Subscription
Contact Us
中文
Table of Content
24 May 1985, Volume 6 Issue 5
Previous Issue
Next Issue
Articles
Synthesis and Structure or Organo-Phosphido-Bridged Tri-and Tetracobalt Carbonyl Cluster Co
5
(CO)
3
(μ
3
- PR), Co
4
(μ-CO)
2
(CO)
8
(μ
5
-PR)
3
(R = NEt
3
, OBu-n, NMe
2
) and Heteronuclear Cluster Compounds Co
2
Fe(CO)
9
(μ
3
-PR) (R = NEt
2
,Ph)
Liu Shutang, Honrath, U.
1985, 6(5): 377-382.
Asbtract
(
)
PDF
(462KB) (
)
Related Articles
|
Metrics
The Tri- and Tctracobalt Cluster compounds Co
3
(CO)
9
,(μ
3
-PR) and Co
4
(μ-CO)
2
(CO)
8
(μ
4
-PR)
2
(R = NEt
2
,OBu-n, NMc
2
) have been prepared simultaneously from the same initial material RPCl
2
and Co
2
(CO)
8
. The trigonal pyramidal structure for the molecule-frameworks Co
5
Pof Co
3
(CO)
5
(μ
3
-PR)and octahedral structure for the molecul-frameworks Co
4
P
2
of Co
4
(μ-CO)
2
(CO)
8
(μ
4
PR)
2
have been deduced from their IR,
1
HNMRspcctroscopic data and clement-analysis.The hcteronuclcar cluster compounds Co
2
Fc(CO)
9
(μ
3
-PR)(R = NEt
2
, Ph) have been synthesized via a metal-exchange reaction from Co
5
(CO)
9
(μ
3
-PR) and Na
2
[Fe (C
0
)
4
]. The molecule-frameworks Co
2
FePof Co
2
Fe(CO)
9
(μ
3
-PR) also arc trigonal pyramidal structure.
The Influence of Alkali Metal Cations on Formation of Silicalite in NH
4
OH-TBAOH System
Tu Kungang, Xu Ruren
1985, 6(5): 383-388.
Asbtract
(
)
PDF
(853KB) (
)
Related Articles
|
Metrics
In contrast with the results previously reported, we have found that Silicalite-2 can be prepared when in the presence of certain amount of alkali metal cations (as chlorides)from NH
4
OH-TBAOHsystem. Further, our work demonstrated the essential role played by various alkali metal cations during the crystallization of the Silicalite-2 in crystal transformation, the composition per unit cell, the particle size and morphology of the crystallites.
The Effect of Steam Treatment on the Properties of the Zeolite HZSM-5
Li Hexuan, Zang Yaru, Tao Keyi, Zhao Yingxian
1985, 6(5): 389-393.
Asbtract
(
)
PDF
(394KB) (
)
Related Articles
|
Metrics
The methods of X-ray diffraction, infrared spectrum and temperature-programmed desorption were used to investigate the properties of the zeolite HZSM-5, which was treated with super-heated steam. The effects of treatment temperature, time and content of water on the acidities of the samples were discussed emphatically.
Studies on Lanthanoids-Antimony-Chalcogenides(Ⅵ) --Synthesis and Crystal Data of CeSbOS
2
Gao Jinzhang, Izumi Nakai, Kozo Nagashima
1985, 6(5): 394-396.
Asbtract
(
)
PDF
(220KB) (
)
Related Articles
|
Metrics
Asingle crystal of CeSbOS
2
was prepared by the evacuated silica-tube method at 900-1000℃ and its crystal data were determined. CcSbOS
2
is a blackish-red plate crystal with orthorhombic; space group: P2
1
2
1
2
1
; lattice parameters. a=14.43(9), b=15.09(2), c = 8.62(1)Å. The crystal is stable in air at room temperature and dissolved in diluted HNO
3
solution.
Study on the Color Reaction of Trichloroarsenazo with Rare Earth (Ⅰ) --Direct Determination of Trace Rare Earth in Tap Water
Chen Danhua, Cai Ruxiu, Yu Ximao, Zeng Yun'e
1985, 6(5): 397-402.
Asbtract
(
)
PDF
(439KB) (
)
Related Articles
|
Metrics
The color reaction of trichloroarscnazo (TCA) (2-(2-arsonophcnylazo)-7-(2, 4,6-trichlorophcnylazo)-1,8-dihydroxy-3,6-disulfonaphthalcne) with rare earth has been studied in this paper.TCAwas found to have high sensitivity to Cerium group rare earth ε = 1.079-1.308×10
5
and to the amount of rare earths ε = 0.937-1.329×10
5
), big comparison degree (Δλ = 93-104nm), and good selectivity. Large amounts of Ca (10mg), Mg(8mg), Al (60mg) do not interfere with the determination. It is one of the best selective reagents for rare earths up to now.
Investigation of Second Derivative Oscillo Polarography with Linearly Changing Potential
Zhang Zuxun, Tu Yifeng
1985, 6(5): 403-408.
Asbtract
(
)
PDF
(432KB) (
)
Related Articles
|
Metrics
The theory of reversible wave and adsorption-complex wave in second derivative oscillopolarography are discussed.
Polarographic Study of Metal-4-(2-Pyridinylazo)-Resocinol (PAR) Complex ( Ⅱ ) -Polarographic Catalytic Wave in Molybdenum(Ⅵ) -PAR-NaClO
3
System
Song Junfeng, Liu Longbin, Hu Yinhua
1985, 6(5): 409-411.
Asbtract
(
)
PDF
(236KB) (
)
Related Articles
|
Metrics
The complex of molybdenum(VI)with PAR at pH 1.7 H
2
S0
4
medium in the presence of NaClO
3
produces a sensitive catalytic wave.
Studies on Organoactinide Compounds (Ⅰ) --Synthesis and Structural Characterization of Two New Substituted Uranocenes
Wang Xukun, Streitwieser, A. Jr., Lyttle, M. H., Solar, J. P.
1985, 6(5): 412-416.
Asbtract
(
)
PDF
(404KB) (
)
Related Articles
|
Metrics
Two new substituted uranocenes--1, 1-dimesityluranocene and 1, 1-di-o-tolylurano-cene were prepared and characterized. Detailed investigation of 1, 1 -di-mesityluranocene by partial decoupled and variable temperature
1
H NMRshowed that the mesityl and the cyclooctatetraenyl groups were not in the same plane and the two mesityl rings had different conformation at different temperatures,
Study on the Components of Saussurea Involucrata Kar. et Kin. (Ⅱ)
Li Yu, Jia Zhongjian, Du Mei, Chu Tse-tsin
1985, 6(5): 417-420.
Asbtract
(
)
PDF
(396KB) (
)
Related Articles
|
Metrics
Anew sesquiterpenoid glycoside was isolated from aerial parts of Saussurea involucrata. et Kin. Cellulase hydrolysis of this compound gave a new guaia-nolide, named as involucratolactone, G
15
H
20
O
3
, m,p.
Investigation of a New Gas Solid Chromatographic Stationary Phase
Yu Zhongjian, Zhang Zunxun, Yun Xiqin, Kou Dengmin, Li Yanhong, Wang Busen
1985, 6(5): 421-426.
Asbtract
(
)
PDF
(423KB) (
)
Related Articles
|
Metrics
Under specified conditions, the cross-linked copolymcr beads of styrene-divinyl-bcnzene were pyrolyzed into carbonaceous adsorbent which may be used as stationary phase in gas solid chromatography. The chromatographic separation efficiency of some spherical carbonaceous adsorbents for various gases were studied. It has been proved that the separation power for inert gases, permanent gases and C
1
-C
3
light hydrocarbons is excellent.This kind of adsorbent is similar to carbon molecular sieves (CMS) in separating property, but it shows some good advantage over them.
Studies on Reflux Liquid Column Chromatography for Analysis of Natural Products
Wu Feng'e
1985, 6(5): 427-429.
Asbtract
(
)
PDF
(241KB) (
)
Related Articles
|
Metrics
Reflux liquid column chromatography is a new method of separation. The set up is composed of combining chromatographic column with Soxhlet extractor. The column was packed with adsorbent, and the sample components were eluted by cyclic eluant, which was vaporized in a recipient vessel.
Calculation of Total π-Electronic Energy of Conjugated Molecules
Zhang Mingchun, Wang Jiangann
1985, 6(5): 430-432.
Asbtract
(
)
PDF
(288KB) (
)
Related Articles
|
Metrics
This paper reports on the new calculating method of the totalπ-electronic energy.From the relationship between the coefficients of characteristic polynomail and roots of polynomail, the authors have derived the formulae of total π-clectronic energy as following.
Mechanistic Studies on Catalytic Dehydrogenation of Ethylbenzene Over Iron-Oxide-Based Catalyst Systems --Role of Lattice Oxygen
Chen Huizhen, He Danyuen, Xiao Zhangling, K. R. Tsai
1985, 6(5): 433-440.
Asbtract
(
)
PDF
(648KB) (
)
Related Articles
|
Metrics
The role of lattice oxygen in catalytic dehydrogcnation of ethylbenzene over industrial iron-oxide-based catalysts, 11
#
(Cr-consaining) and 210
#
(Cr-free), has been investigated by means of the following experiments: (1) Determination of amounts of H
2
Oproduced due to removal of lattice oxygen by reaction with ethyl-benzene used as the feed without addition of steam, and observation of gradual decay of catalytic activities, and changes in the X-ray powder-diffraction patterns of the used catalysts; (2) with elhylbcnzcne plus D
2
Oas the feed, determination of the change in D
2
/H
2
ratio in the exit gas for very high and very low space velocities; and (3) vvith ethylbenzene plus D
2
18
Oas the feed, observation of isotopic exchange of lattice
16
Owith steam
18
Ofrom the red shifts in the IRspectra of the used catalyst. The results indicate that direct heterolytic dehydrogenalion of ethylbenzene appcared to be the major rcction pathway, but a minor reaction pathway of cthyl-benzcne dehydiogenation by oxygen-transfer mechanism also appeared to make an appreciable contribution (about 20%) to the overall conversion. Mechanisms of these two reaction pathways are discussed. For the oxygen-transfer dehydrogenation mechanism, the importance of electron transport between neighboring active-sites operating cooperatively in opposite phases of their redox cycles is pointed out.
A Study on the Texture of Zinc Electrodeposits by Means of X-Ray Diffraction
Xu Shukai, Huang Taishan, Zhou Shaomin
1985, 6(5): 441-446.
Asbtract
(
)
PDF
(465KB) (
)
Related Articles
|
Metrics
The texture of zinc electrodeposils prepared under controlled polarized potential and current density was studied by means of X-ray diffraction. It was observed that the crystal orientation of zinc ekectrodeposits strongly depends upon the polarized potential and duration of electrodeposition. The obtained results were discussed on the basis of geometrical selection theory and outward mode of growth, and also with the crystallographic and electrochemical factors.
Studies on Internal Rotation of Methyl in Substituted Benzene by Using
13
C NMR Spin-lattice Relaxation Time
Xie Dilin, Wang Jinslian, Chen Liang, Hu Yu xian
1985, 6(5): 447-450.
Asbtract
(
)
PDF
(316KB) (
)
Related Articles
|
Metrics
Amethod for determinating the spin-internal rotation relaxation rate of methyl by ortho-subslituting and meta-substituting the sample ( toluene ) is suggested. Spin-lattice relaxation times ( T
1
) and nuclear Overhauser effect ( NOE ) of
13
Cin the methyl of ο-xylene and m-xylene between 28℃ and 90℃ are measured. The spin-whole rotation relaxation rate and spin-internal rotation relaxation rate of
15
Cin the methyl of m-xylene are separated, with the internal rotation rate of the methyl calculated.
On the Influence of pH on Kinetics and Rate of Oxygen Evolution at Ti Electrode Covered with Film of RuO
2
and TiO
2
Quan Zongxue, Yin Hengzhen
1985, 6(5): 451-455.
Asbtract
(
)
PDF
(373KB) (
)
Related Articles
|
Metrics
The chlorine and oxygen content in anode gas has been determined by gsa absorption method. The result shows that the oxygen evolution rale changes with pHs (the pHvalue of anode chamber electrolyte): when pHs<2, the rale of oxygen evolution increascs rapidly with increasing pHs; between 2-4.2, the rate of it changed slowly, and, when pHs>4.2 it increases again quite rapidly. The rule stated above are independent of the density of current and the constitution of the oxide film of the electrodes within the current density range 150-550mA/cm
2
.
Coordination Activation and Hydrogenation of Chemisorbed N
2
on Iron Catalysts for Ammonia Synthesis
Liao Daiwei
1985, 6(5): 456-458.
Asbtract
(
)
PDF
(212KB) (
)
Related Articles
|
Metrics
The results of EHMOcalculation indicated that the μ
7
(η
2
, ω
2
, ω
2
') symmetrical double-end-on plus multiple-side-on flat-lying mode appeared to be more favorable to the coordination activation and hydrogenation of chemisorbed N
2
on iron catalysts for ammonia synthesis than other modes, and supported the associative reaction mechanism suggested by professor,K.R. Tsai.
Investigations on the Properties and Catalytic Behavior of Rare Earth Heteropoly Acids
Wu Zhiyun, Zhao Zhongqing, Li Kai, Zhang Qiang
1985, 6(5): 459-460.
Asbtract
(
)
PDF
(166KB) (
)
Related Articles
|
Metrics
In this paper, we studied some properties and the catalytic behavior of the rare earth hcteropoly acids in MeOH Conversion reaction.
Studies on Polymerization Processes of Bis[4-(4-Ethynyl-Phenoxy)-Phenyl]Sulfone and Polymer's Dynamic Mechanical Properties
Zeng Hanrain, Mai Kancheng, Ye Lanxin
1985, 6(5): 461-466.
Asbtract
(
)
PDF
(462KB) (
)
Related Articles
|
Metrics
The polymerization processes of bis[4-(4-ethynylphenoxy)phenyl] sulfone and its polymer's dynamic mechanical properties were investigated by torsional braid ana-lysis(TBA) and infrared spectroscopy. Results showed that the multiple transitions including the melting, low-and high-temperature reaction of oligomer, glass transition and decomposition reaction of its polymer could be characterized in the TBAspectra. The glass transition temperatures of its polymers depend upon the conditions of polymerization.
Study on the Electrical Property of Polyeletrolytes
Chen Zhusheng, Mao Xiaoguan, He Yuankang, Wang Chaoying, Chen Liquan
1985, 6(5): 467-471.
Asbtract
(
)
PDF
(439KB) (
)
Related Articles
|
Metrics
In this paper, first of all, the conductivity of sodium polymethacrylate of different molecular weight has been investigated at different temperatures. Secondly, the conductivity of lithium, sodium and potassium polymethacrylate has been determined at different temperatures, and the effects of ionic radius on conductivity have been compared. Finally, the effects of side chain length of polyelectrolytes on the conductivity have been studied.Conductivity has been determined by means of direct current method. The complex relations between conductivity of polyelectrolyte and molecular weight are showed. Conductivity depends on the number of ion, which disassociate from the chain, and molecular weight. The results of experiment indicate that the relation between conductivity and ionic radius change as the shape of V. Among salts of lithium, sodium and potassium, the sodium is in the lowest. Linear lgo vs. 1/Tplots are obtained for polyelectrolytes.
Author Login
Peer Review
Editor Work
Office Work
Special Issues
More...
Download
More...
Links
More...