CJCU

Chem. J. Chinese Universities ›› 1985, Vol. 6 ›› Issue (5): 412.

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Studies on Organoactinide Compounds (Ⅰ) --Synthesis and Structural Characterization of Two New Substituted Uranocenes

Wang Xukun1, Streitwieser2, A. Jr.2, Lyttle2   

  1. 1. Institute of Elementoorganic Chemistry, Nankai University, Tianjin;
    2. Department of Chemistry, University of California, Berkeley, U. S. A.
  • Received:1984-03-05 Online:1985-05-24 Published:1985-05-24

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Abstract: Two new substituted uranocenes--1, 1-dimesityluranocene and 1, 1-di-o-tolylurano-cene were prepared and characterized. Detailed investigation of 1, 1 -di-mesityluranocene by partial decoupled and variable temperature 1H NMRshowed that the mesityl and the cyclooctatetraenyl groups were not in the same plane and the two mesityl rings had different conformation at different temperatures,

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