Hydrothermal Synthesis and Characterization of MZr2(AsO4)3,(M=Na, K, Rb, Cs)

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (5): 598.

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Hydrothermal Synthesis and Characterization of MZr₂(AsO₄)₃,(M=Na, K, Rb, Cs)

WANG Hai-Zeng, PANG Wen-Qin

Deportment of Chemistry, Jilin University, Changclatn, 130023

Received:1992-05-05 Revised:1992-11-21 Online:1993-05-24 Published:1993-05-24

Abstract

Abstract: MZr₂(AsO₄)₃(M = Na, K, Rb, Cs) compounds were synthesized under hydrothermal conditions:As₂O₅/ZrO₂ = 6.4, M⁺/As=0.333 (molar ratio), pH≤2.0, 250℃, 5 days.The influence of the concentration and source of reactants on the product phases was investigated.The products were characterized by means of X-ray powder diffraction, Raman and IRspectroscopies.The effect of M⁺ on the vibrational spectrum of anionic skeleton was preliminarily analyzed.

Key words: Hydrothermal synthesis, Characterization of structure, Arsenate, MZr₂(AsO₄)₃

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WANG Hai-Zeng, PANG Wen-Qin . Hydrothermal Synthesis and Characterization of MZr₂(AsO₄)₃,(M=Na, K, Rb, Cs)[J]. Chem. J. Chinese Universities, 1993, 14(5): 598.

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Hydrothermal Synthesis and Characterization of MZr₂(AsO₄)₃,(M=Na, K, Rb, Cs)

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