Preparation and Properties of Cermets Inert Anode with Adding MnO2

Chem. J. Chinese Universities

• 研究论文 • Previous Articles Next Articles

Preparation and Properties of Cermets Inert Anode with Adding MnO₂

ZHANG Li-Peng^1,2, YU Xian-Jin²*, DONG Yun-Hui², LI De-Gang²

1. School of Material Science and Metallurgical Engineering, Northeast University, Shenyang 110004, China;
2. School of Chemical Engineering, Shandong University of Technology, Zibo 255049, China

Received:2007-02-24 Revised:1900-01-01 Online:2008-01-10 Published:2008-01-10
Contact: YU Xian-Jin

Abstract

Abstract: Cermets with adding MnO₂, used as the inert anode in aluminum electrolysis, were prepared. The effects of MnO₂ on the properties of inert anode were researched. The inert anode on corrosion resistance properties were also studied, and determination of the conductivity of the sample in the temperature change range of 500—1000 ℃ was made. The effects of MnO₂ on sintering properties of inert anode were investigated. The results indicate that MnO₂ improved sintering properties, crystal of cermets with adding MnO₂ grew ideally, the cermets inter anode had a high density, high anti-oxidation, corrosion resistance and high conductivity. The annual corrosion rate of cermets with adding MnO₂ was 12.32 mm/a. The electric conductivity was stable and good, which belongs to the electric conductivity property of the semiconductor. The conductivity increased with temperature increasing. The conductivities of cermets with adding MnO₂ was 67 S/cm at 850 ℃.

Key words: MnO2, Metal cermet, Doping, Inert anode

CLC Number:

TrendMD:

ZHANG Li-Peng^1,2, YU Xian-Jin²*, DONG Yun-Hui², LI De-Gang². Preparation and Properties of Cermets Inert Anode with Adding MnO₂[J]. Chem. J. Chinese Universities, doi: .

[1]	CHENG Qian, YANG Bolong, WU Wenyi, XIANG Zhonghua. S-doped Fe-N-C as Catalysts for Highly Reactive Oxygen Reduction Reactions [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220341.
[2]	SONG Youwei, AN Jiangwei, WANG Zheng, WANG Xuhui, QUAN Yanhong, REN Jun, ZHAO Jinxian. Effects of Ag，Zn，Pd-doping on Catalytic Performance of Copper Catalyst for Selective Hydrogenation of Dimethyl Oxalate [J]. Chem. J. Chinese Universities, 2022, 43(6): 20210842.
[3]	SUN Xuefeng, RENAGUL Abdurahman, YANG Tongsheng, YANG Qianting. Synthesis and Luminescence Properties of Cr，In Co-doped Small Size MgGa₂O₄ Near-infrared Persistent Luminescence Nanoparticles [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210850.
[4]	WANG Zumin, MENG Cheng, YU Ranbo. Doping Regulation in Transition Metal Phosphides for Hydrogen Evolution Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220544.
[5]	HONG Yangyu, XING Hongzhu, BING Qiming, GAO Xuwen, QI Bin, CHEN Yakun, SU Tan, ZOU Bo. Synthesis and Fluorescence Properties of Novel Ce³⁺-doped Manganese Phosphite Open-framework Materials [J]. Chem. J. Chinese Universities, 2021, 42(9): 2725.
[6]	CHEN Mingsu, ZHANG Huiru, ZHANG Qi, LIU Jiaqin, WU Yucheng. First-principles Study on the Catalytic Effect of Co，P co-Doped MoS₂ in Lithium-sulfur Batteries [J]. Chem. J. Chinese Universities, 2021, 42(8): 2540.
[7]	WU Yaqiang, LIU Siming, JIN Shunjin, YAN Yongqing, WANG Zhao, CHEN Lihua, SU Baolian. Synthesis of Zn-Doped NiCoP Catalyst with Porous Double-layer Nanoarray Structure and Its Electrocatalytic Properties for Hydrogen Evolution [J]. Chem. J. Chinese Universities, 2021, 42(8): 2483.
[8]	CHEN Xiaoyu, YU Ranbo. Research Progress on Doping of Molybdenum Disulfide and Hydrogen Evolution Reaction [J]. Chem. J. Chinese Universities, 2021, 42(2): 475.
[9]	MA Jun, ZHONG Yang, ZHANG Shanshan, HUANG Yijun, ZHANG Lipeng, LI Yaping, SUN Xiaoming, XIA Zhenhai. Design and Theoretical Calculation of Heteroatoms Doped Graphdiyne Towards Efficiently Catalyzing Oxygen Reduction and Evolution Reactions [J]. Chem. J. Chinese Universities, 2021, 42(2): 624.
[10]	YAO Mingcai, YANG Qiang, MENG Jian, LIU Xiaojuan. Effect of Zn²⁺ Substituting Ga³⁺ on Structure and Photocatalytic Properties of Wurtzite β-CuGa_1-_xZn_xO₂with Unequal Doping [J]. Chem. J. Chinese Universities, 2021, 42(12): 3561.
[11]	ZHU Yuxin, OUYANG Jie, SONG Yanhua, TANG Sheng, CUI Yanjuan. Preparation of Boron and Iodine co-Doped Carbon Nitride and Its Performance in Photocatalytic Hydrogen Evolution from Water^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1645.
[12]	ZHAO Guoqing, YUAN Zhao, WANG Lian, GUO Zhuo. Preparation of Ni₂P/N, S co-Doped Reduced Graphene Oxide Composites and Their Electrocatalytic Properties for Hydrogen Evolution^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1575.
[13]	HUANG Jialing,LIU Fengjiao,WANG Tingting,LIU Cuie,ZHENG Fengying,WANG Zhenhong,LI Shunxing. Nitrogen and Sulfur co-Doped Carbon Quantum Dots for Accurate Detection of pH in Gastric Juice^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1513.
[14]	CHENG Shifu,HU Hao,CHEN Bihua,WU Haihong,GAO Guohua,HE Mingyuan. Preparation and Electrochemical Performance of Porous Carbons Prepared from Binary Ionic Liquids ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 1048.
[15]	WANG Xia, LIU Yanji, JIA Yongfeng, JI Lei, HU Quanli, DUAN Limei, LIU Jinghai. Preparative Chemistry of N-containing Porous Carbon Nanofibers for Capacity Improvement in Lithium-sulfur Battery ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 829.

Preparation and Properties of Cermets Inert Anode with Adding MnO₂

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments