Synthesis and Characterization of Phthaloyl Bridged Iron-Sulfur Complexes [(μ-RS)Fe2(CO)6]2(μ-OCC6H4CO-μ)

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (6): 905.

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Synthesis and Characterization of Phthaloyl Bridged Iron-Sulfur Complexes [(μ-RS)Fe₂(CO)₆]₂(μ-OCC₆H₄CO-μ)

SONG Li-Cheng, HU Qing-Mei, SU Zheng-Yuan, CAO Xi-Chuan, ZHU Jin

Department of Chemistry, Nankai University, Tianjin, 300071

Received:1994-06-26 Revised:1995-02-23 Online:1995-06-24 Published:1995-06-24

Abstract

Abstract: The in situ reaction of the complex salts [(μ-CO)(μ-RS)Fe₂(CO)₆]Et₃NH derived from Fe₃(CO)₁₂,RSH and Et₃N with p-,or m-phthaloyl chloride in THFat room temperature afforded six novel phthaloyl bridged iron-sulfur complexes [(μ-RS)Fe₂(CO)₆]₂(μ-pOCC₆H₄CO-p-μ)(R=Et,n-Bu, t-Bu) and [(μ-RS)Fe₂(CO)₆]₂(μ-m-OCC₆H₄CO-m-μ)(R=n-Pr,n-Bu,t-Bu).These new complexes were characterized by elemental analysis,IR and ¹HNMR spectroscopies and the reaction course was discussed.In addition,a new synthetic route to p-phthaloyl chloride has been developed.

Key words: Synthesis, Characterization, Bridged phthaloyl ligand, Iron-sulfur complexes

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SONG Li-Cheng, HU Qing-Mei, SU Zheng-Yuan, CAO Xi-Chuan, ZHU Jin. Synthesis and Characterization of Phthaloyl Bridged Iron-Sulfur Complexes [(μ-RS)Fe₂(CO)₆]₂(μ-OCC₆H₄CO-μ)[J]. Chem. J. Chinese Universities, 1995, 16(6): 905.

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Synthesis and Characterization of Phthaloyl Bridged Iron-Sulfur Complexes [(μ-RS)Fe₂(CO)₆]₂(μ-OCC₆H₄CO-μ)

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