Preparation of Azobenzene Substituted Pyrazoline Derivatives and Studies on their Electronic Spectroscopy

Abstract

Abstract: Bifunctional pyrazoline derivatives 5 and 6 containing azobenzene group were prepared. The difference between them was the length of the flexible chain connecting the two chromophores. Compound 6 had four more methylenes than compound 5. UV-Vis spectra of compounds 5 and 6 were the simple superposition of the absorbance of the azobenzene and pyrazoling and showed that pyrazoline had no effect on the isomerization of azobenzene. When there were two methylenes between azobenzene and pyrazoline, the fluorescent intensity of compound 5 decreased greatly compared with that of compound 6. It means that the intramolecular Electronic Energy Transfer has taken place in compound 5. In compound 6, this process could not occur because of the longer flexible chain between the two chromophores.

Key words: Pyrazoline, Azobenzene, Photochromism, Electronic energy transfer

CLC Number:

O636

TrendMD:

JIN Ming, LU Ran, CHUAI Xiao-Hong, ZHANG Yi-Hua, ZHAO Ying-Ying . Preparation of Azobenzene Substituted Pyrazoline Derivatives and Studies on their Electronic Spectroscopy[J]. Chem. J. Chinese Universities, 2002, 23(3): 466.

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Preparation of Azobenzene Substituted Pyrazoline Derivatives and Studies on their Electronic Spectroscopy

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