Chem. J. Chinese Universities
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XIONG Xiao-Yun, LI Cai-Jin, DING Hong, HUANG Shi-Ying, LIANG De-Sheng, XIAO Feng-Shou, LI Shou-Gui*
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Abstract: This work describes a novel method to synthesize NaY zeolite at high temperature(100—140 ℃) by using NaY seeds solution as a silica source, which is also a method for the activation of silica source in the synthesis of NaY zeolite. Conventionally, the synthesis temperature of NaY zeolite from water glass is about 100 ℃, and higher temperature(>100 ℃) leads to the formation of impurity. However, this work shows that high-temperature synthesis(100—140 ℃) still exhibits a pure phase NaY. It is very interesting that, compared with conventional temperature, high-temperature in the synthesis of NaY zeolite has obvious advantages such as short crystallization time and high n(Si)/n(Al) ratio in the product. More importantly, this method is possible to extend to the synthesis of NaA, NaX, Ω, ECR-1and MOR.
Key words: NaY zeolite, Activation of silica source, Guidance agent of crystallization
CLC Number:
O614
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XIONG Xiao-Yun, LI Cai-Jin, DING Hong, HUANG Shi-Ying, LIANG De-Sheng, XIAO Feng-Shou, LI Shou-Gui*. High Temperature Synthesis of NaY Zeolite[J]. Chem. J. Chinese Universities, doi: .
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URL: http://www.cjcu.jlu.edu.cn/EN/
http://www.cjcu.jlu.edu.cn/EN/Y2007/V28/I9/1634