Mercury Selective Sensor Based on C3v Symmetric Calix[6]arene Tripod

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (9): 2139.

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Mercury Selective Sensor Based on C3v Symmetric Calix[6]arene Tripod

HE Song, LU Yang, LI Yuan-Yuan, LU Yan*, ZENG Xian-Shun*

Key Laboratory of Display Materials and Photoelectric Devices, Ministry of Education, School of Materials Science & Engineering, Tianjin University of Technology, Tianjin 300384, China

Received:2011-03-29 Revised:2011-06-09 Online:2011-09-10 Published:2011-08-11
Contact: ZENG Xian-Shun;LU Yan E-mail:xshzeng@tjut.edu.cn;luyan@tjut.edu.cn
Supported by:
国家自然科学基金(批准号: 20972111, 21074093, 21004044)和天津市高等学校科技发展基金(批准号: 20080308)资助.

Abstract

Abstract: Three new fluorescent probes based on C3v symmetric calix[6]arene functionalized with three anthracylselenoalkoxy (1), anthracyltelluroalkoxy (2) or anthracylthiaalkoxy (3) groups were synthesized, respectively. The photophysical behavior and the binding ability of 1-3 with some alkaline metal ions and transition metal ions were investigated by fluorescence spectrometry. Receptor 1 exhibited highly selective fluorescence quenching behavior towards Hg2+ in CH2Cl2 with Ka = (1.12 ? 0.08) ? 105 M-1. In addition, the color change of 1-Hg2+ from colorless to light yellow allows naked-eye detection of mercury (Ⅱ)

Key words: Calix[6]arene, Mercury ion, Chemosensor, Selenium

CLC Number:

0626

TrendMD:

HE Song, LU Yang, LI Yuan-Yuan, LU Yan*, ZENG Xian-Shun*. Mercury Selective Sensor Based on C3v Symmetric Calix[6]arene Tripod[J]. Chem. J. Chinese Universities, 2011, 32(9): 2139.

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Mercury Selective Sensor Based on C3v Symmetric Calix[6]arene Tripod

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