Synthesis and Characterization of Hydrotalcite-like[CdxMg6-xAl2(OH)16]2+)[S·2H2O]2-

Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (3): 355.

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Synthesis and Characterization of Hydrotalcite-like[Cd_xMg_6-xAl₂(OH)₁₆]²⁺)[S·2H₂O]^2-

BAO Yu-Min, LI Lian-Sheng, MA Shu-Jie, XIONG De-Cheng, FU Ge-Yan, FENG Shou-Hua, XU Ru-Ren

Key Laboratory of Inorganic Hydrothermal Synthesis, Jilin Uniuersity, Changchun 130023

Received:1995-06-21 Online:1996-03-24 Published:1996-03-24

Abstract

Abstract: Hydrotalcite-like [Cd_xMg_6-xAl₂(OH)₁₆]²⁺[S·2H₂O]^2- was synthesized hydrothermally and characterized by means of XRD,FT-IR,DTA-TGetc.,The influence of pH,Cd²⁺ ionic concentration and sulphuration time on the synthesis was studied.The synthetic optimal conditions are pH=9～10,[Cd²⁺]/[Mg²⁺]=1:5～1:9 and sulphuration time 5 min.It is suggested that Mg²⁺ ions can be only partially substituted by Cd ²⁺ ions in the hydrotalcite-like.

Key words: Hydrotalcite, Sulphuration, Layered compound, Synthesis

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BAO Yu-Min, LI Lian-Sheng, MA Shu-Jie, XIONG De-Cheng, FU Ge-Yan, FENG Shou-Hua, XU Ru-Ren. Synthesis and Characterization of Hydrotalcite-like[Cd_xMg_6-xAl₂(OH)₁₆]²⁺)[S·2H₂O]^2-[J]. Chem. J. Chinese Universities, 1996, 17(3): 355.

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Synthesis and Characterization of Hydrotalcite-like[Cd_xMg_6-xAl₂(OH)₁₆]²⁺)[S·2H₂O]^2-

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