Interrelation of Carbon Numbers in Microemulsion with Nonionic Surfactant

Abstract

Abstract: The interrelation of carbon numbers was studied in microemulsions containing nonionic surfactant, n-alcohol, n-hydrocarbon and water by construction of pseduo ternary phase diagrams. Mixtures of the surfactant, alcohol and hydrocarbon were titrated at 30 ℃ with water to the points of turbidity and clarity to determine the microemulsion area. The total area of the microemulsion of different types for AEO₉, n-alcohol, n hydrocarbon and water reached a maximum value when N_O, carbon number of the oil, N_O, carbon number plus that of the alcohol, N_A, was equal to that of the AEO₉, N_S(N_S= N_O+ N_A). The results are discussed theoretically.

Key words: Microemulsion, Nonionic surfactant, Interrelation of carbon numbers, Phase diagram

CLC Number:

O648.1

TrendMD:

TENG Hong-Ni, SUN Yong, HUANG Bin, KONG Bin, CHEN Zong-Qi  . Interrelation of Carbon Numbers in Microemulsion with Nonionic Surfactant[J]. Chem. J. Chinese Universities, 1999, 20(5): 772.

[1]	WANG Xingfan, ZHOU Huan, ZHOU Kuo, JIN Fenli, YANG Junfang. Comprehensive Thermodynamic Model and Polythermal Phase Diagram Prediction of Nitrate Type Brine Systems [J]. Chem. J. Chinese Universities, 2021, 42(10): 3175.
[2]	LIU Zihao,XIAO Han,YAO Yuan,WANG Ting,WU Liguang,ZHANG Xueyang. Fabrication of PVDF Hybrid Blending Membrane via Microemulsion Polymerization Coupling with Blending Method ^† [J]. Chem. J. Chinese Universities, 2019, 40(10): 2248.
[3]	KANG Changyong,DING Xiaoli,ZHAO Hongyong,WANG Xinlan,ZHANG Yuzhong,WANG Lina. Construction of Nanocavity in Membranes Based on Hollow Polymer Microspheres and Effects on Gas Permeation Performance^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2820.
[4]	LIU Shujing, LI Jiangtao, GU Fang, WANG Haijun. Phase Structure of A_a Type of Patchy Colloids^† [J]. Chem. J. Chinese Universities, 2017, 38(10): 1888.
[5]	LIU Xuewu,CHEN Shuhua,ZHAN Shiping. Experimental Study and Theoretical Phase Diagram Calculation for Polystyrene Membranes Prepared by Supercritical CO₂-induced Phase Inversion^† [J]. Chem. J. Chinese Universities, 2016, 37(8): 1573.
[6]	LI Zhaowan, QIAO Zhanping, CHEN Xin, DANG Yuanlin, YANG Qichao. Equilibria for the CsBr-TmBr₃-H₂O and CsBr-TmBr₃-HBr(~13%)-H₂O Systems at 298.15 K and Thermodynamic and Fluorescent Properties of New Solid-phase Compound [J]. Chem. J. Chinese Universities, 2015, 36(9): 1759.
[7]	HU Biao, ZHOU Peng, PAN Chengling, DU Yong, LIU Shuhong, LI Yiwei, HAN Jiangjun. Theoretical Study on the Binary Phase Diagrams of the Zr-X (X=Li, Na, K, Sc, Hf) Systems^† [J]. Chem. J. Chinese Universities, 2015, 36(10): 1939.
[8]	YIN Huiqin, WANG Kun, LIU Wenguan, XIE Leidong, HAN Han, WANG Wenfeng. Thermodynamic Modeling of the LiF-CrF₃ Binary System^† [J]. Chem. J. Chinese Universities, 2014, 35(12): 2668.
[9]	ZHU Yan, YAO Wei-Qin, CHEN Shao-Jie, TIAN Long-Zhao, YUAN Shuai. Phase Diagram and Temperature Influence of SDS/n-pentanol-cyclohexane-water Pseudo Ternary Systems [J]. Chem. J. Chinese Universities, 2013, 34(5): 1254.
[10]	SONG Hua, SHI Yang, SONG Hua-Lin. Preparation of Pt-S₂O₈^2-/ZrO₂-Al₂O₃ Catalyst by Microemulsion Method and Its Performance for Isomerization [J]. Chem. J. Chinese Universities, 2012, 33(09): 2061.
[11]	MA Yu-Jie, FAN Gao-Chao, CHEN Jie, HUANG Zai-Yin. In situ Thermokinetic Investigation on the Growth of MnMoO₄稨₂O Nanorods [J]. Chem. J. Chinese Universities, 2012, 33(08): 1813.
[12]	YAN Dong-Dong, DU Na, HOU Wan-Guo. Removal of Crude Oil from Oily Sludge by Microemulsion [J]. Chem. J. Chinese Universities, 2012, 33(08): 1777.
[13]	ZHU Wen-Qing, XING Xi-Ping, ZHANG Chao, YUAN Yu-Kun, CHEN Ya-Shao. Controlled Synthesis of Nd₂(CO₃)₃?8H₂O Particles in the Media of Reverse Microemulsions [J]. Chem. J. Chinese Universities, 2012, 33(05): 1036.
[14]	ZHANG Zhi-Wei, DING Wei, LI Zhong, DONG Zhi-Long, YU Tao, QU Guang-Miao, WANG Hui-Min, LUO Shi-Qiong. Properties of Microemulsion Formed by Different Alkyl Aryl Sulfonates [J]. Chem. J. Chinese Universities, 2012, 33(02): 395.
[15]	MA Li*, JIA Chun-Yue, GAN Meng-Yu, HAO Shao-Na, LIU Xing-Min, LI Zhi-Chun. Synthesis and Electrochemical Behavior of Polyainiline by Composite Emulsifier Microemulision Polymerization [J]. Chem. J. Chinese Universities, 2011, 32(7): 1656.

Interrelation of Carbon Numbers in Microemulsion with Nonionic Surfactant

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments