Synthesis and Characterization of Ordered Mesoporous Aluminosilicates Molecular Sieves with Highly Hydrothermal Stability

Chem. J. Chinese Universities

• 研究论文 • Previous Articles Next Articles

Synthesis and Characterization of Ordered Mesoporous Aluminosilicates Molecular Sieves with Highly Hydrothermal Stability

LUO Yong-Ming^1,2, HOU Zhao-Yin¹, ZHENG Xiao-Ming¹*

1. Institute of Catalysis, Department of Chemistry, Xixi Campus, Zhejiang University, Hangzhou 310028, China;
2. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China

Received:2006-11-04 Revised:1900-01-01 Online:2007-05-10 Published:2007-05-10
Contact: ZHENG Xiao-Ming

Abstract

Abstract: Highly ordered mesoporous aluminosilicate molecular sieve MSAMS-4 was synthesized via multistage recrystallization. The reaction product was characterized by XRD, N₂ adsorption-desorption, FTIR spectroscopy and ²⁷Al MAS NMR. The hydrothermal stability tests exhibit that MSAMS-4 retained a well-ordered hexagonal symmetry mesostructure both after being treated with 100 ℃ water for 120 h and streamed at 800 ℃ for 6 h.

Key words: SBA-15, Aluminosilicate molecular sieve, Hydrothermal stability, Multistage recrystallization, Synthesis and characterization

CLC Number:

O611

TrendMD:

LUO Yong-Ming^1,2, HOU Zhao-Yin¹, ZHENG Xiao-Ming¹*. Synthesis and Characterization of Ordered Mesoporous Aluminosilicates Molecular Sieves with Highly Hydrothermal Stability[J]. Chem. J. Chinese Universities, doi: .

[1]	CHENG Biaoping, LI Laisheng, ZHOU Rendan, LI Liang, ZHANG Hongfu. Enantioseparations of Triazole Chiral Pesticides on Two β-Cyclodextrin-bonded Stationary Phases with Different Linkages by HPLC^† [J]. Chem. J. Chinese Universities, 2015, 36(5): 872.
[2]	XU Qian, DONG Zhaoyang, SHI Guoliang, PAN Dahai, YU Feng, CHEN Shuwei, LI Ruifeng. Optimized Synthesis and Characterization of Highly Ordered Mesoporous Al-SBA-15 with High Hydrothermal Stability^† [J]. Chem. J. Chinese Universities, 2015, 36(12): 2355.
[3]	ZHOU Rendan, LI Laisheng, CHENG Biaoping, NIE Guizhen, ZHANG Hongfu. Preparation and Evaluation of a Novel 6-mono-Nitrophenylamino-β-cyclodextrin Bonded SBA-15 Chiral Stationary Phase for HPLC^† [J]. Chem. J. Chinese Universities, 2014, 35(6): 1152.
[4]	LI Zhixiong, NA Wei, WANG Hua, GAO Wengui. Direct Syntheses of Cu-Zn-Zr/SBA-15 Mesoporous Catalysts for CO₂ Hydrogenation to Methanol^† [J]. Chem. J. Chinese Universities, 2014, 35(12): 2616.
[5]	WANG Min, LI Dong, CAI Wenjing, JIANG Nanzhe. Synthesis of Length Controllable Ordered Mesoporous Rodslike SBA-15 by Co-surfactant Method^† [J]. Chem. J. Chinese Universities, 2014, 35(1): 26.
[6]	DENG Ying, YUAN Pei, YUAN Xia, WU Jian, LUO He-An. Preparation of Hydrophobic Cosalen/SBA-15 and Its Application in the Selective Oxidation of Toluene [J]. Chem. J. Chinese Universities, 2013, 34(11): 2617.
[7]	DU Ming-Xia, QIAN Xian-Hua, WANG Li-Ping, SHAO Xin, LI Wen-Zhi. Enantioseparation of Chiral Alcohols on Acellulose Derivative Immobilized onto Spherical Mesoporous SBA-15 by High Performance Liquid Chromatography [J]. Chem. J. Chinese Universities, 2012, 33(05): 902.
[8]	XU Shuai, ZHANG Xin, DUAN Shuo, XU Xiao-Meng, ZHOU Chang-Li*. Preparation of Selective Modified Electrode Based on β-CD Functionalized Ordered Mesoporous Materials [J]. Chem. J. Chinese Universities, 2011, 32(9): 2210.
[9]	NIE Xin, QU Feng-Yu, LI Xiao-Feng, LIN Hui-Ming. Synthesis of Spherical Mesoporous SBA-15 with Abundant Carboxyl and Drug Release Profile [J]. Chem. J. Chinese Universities, 2011, 32(7): 1478.
[10]	TANG Tao, LI Xiao-An, ZHAO Yan-Ling, XU Yao, WU Dong*, SUN Yu-Han. Synthesis of Amine/methyl Bifunctionalized SBA-15 with Hexagonal Platelet Morphology and Its Application in Bilirubin Adsorption [J]. Chem. J. Chinese Universities, 2011, 32(3): 772.
[11]	CAO Yu, CHEN Biao-Hua, ZHANG Run-Duo*. Selectively Catalytic Combustion of Acetonitrile by Transition\\|metal Supported Mesoporous Molecular Sieve SBA-15 [J]. Chem. J. Chinese Universities, 2011, 32(12): 2849.
[12]	ZHAO Jun-Hua, LI Hong-Liang, LIN Qing, LI Ke-Xun, PENG Zhi, ZHAO Xiu-Song. Mesoporous Carbon Preparation by in-situ* Carbonization via a Reaction Under Autogenic Pressure at Elevated Temperature [J]. Chem. J. Chinese Universities, 2010, 31(6): 1088.
[13]	MA Jin-Yan, QU Feng-Yu*, XU Ying-Pu, LI Xiao-Feng. Highly-Ordered Hierarchical Composite Pore Materials Using Natural Plants as Templates [J]. Chem. J. Chinese Universities, 2010, 31(6): 1103.
[14]	TIAN Dong, YONG Guo-Ping, LIU Shao-Min. In situ* Formation of Silver Nanoparticles Hosted in Mesoporous SBA-15 [J]. Chem. J. Chinese Universities, 2009, 30(12): 2367.
[15]	BI Ya-Dong, ZHANG Wei, XU Heng-Yong*, LI Wen-Zhao. Interaction at Pt-CeO₂ Contact Interface over Pt/CeO₂/SBA-15 Catalyst [J]. Chem. J. Chinese Universities, 2009, 30(10): 2032.

Synthesis and Characterization of Ordered Mesoporous Aluminosilicates Molecular Sieves with Highly Hydrothermal Stability

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments