Molecular Recognition and "on-off" Switching of Calix[4]arenes to Monosaccharides and Pyrimidine Derivatives

Abstract

Abstract: The AM1 and INDO/SCI method were used to study supra-molecular complexes composed of octahydroxy calixarenes and monosaccharides and pyrimidine derivatives. It was shown that the host performs a better molecular recognition to mono-saccharides especially to the erythrose by the CH-π interaction but there is almost no π-π interaction between the host and the pyrimidine which exists in the pyrimidine derivative when H is substituted by-COOH, and the "on-off" molecular switching can be designed by this. The reason of red-shift for UV absorption peaks of the complexes compared to that of the host was discussed.

Key words: Calix[4]arenes, Monosaccharides, Pyrimidine, "On-off", molecular switching

CLC Number:

O641

TrendMD:

WU Shi, TENG Qi-Wen, CHEN Xiao-Fei, ZHOU Rong-Hui . Molecular Recognition and "on-off" Switching of Calix[4]arenes to Monosaccharides and Pyrimidine Derivatives[J]. Chem. J. Chinese Universities, 2003, 24(7): 1271.

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Molecular Recognition and "on-off" Switching of Calix[4]arenes to Monosaccharides and Pyrimidine Derivatives

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