Synthesis and Self-aggregation Behavior of Novel Amphiphilic Polyelectrolytes Containing Gemini Surfactant Units

Chem. J. Chinese Universities ›› 2010, Vol. 31 ›› Issue (10): 2024.

• Articles • Previous Articles Next Articles

Synthesis and Self-aggregation Behavior of Novel Amphiphilic Polyelectrolytes Containing Gemini Surfactant Units

LI Rong-Qiang1,2, XU Cheng-Feng2, WEI Lu-Bin1, WANG Jin-Ben2*

1. School of Chemical and Environmental Engineering, China University of Mining and Technology(Beijing), Beijing 100083, China;
2. Key Laboratory of Colloid, Interface and Chemical Termodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Received:2010-03-01 Online:2010-10-10 Published:2010-10-10
Contact: WANG Jin-Ben. E-mail: jbwang@iccas.ac.cn
Supported by:
国家“八六三”计划项目(批准号: 2007AA090701-2)和国家科技重大专项基金(批准号: 2008ZX05024-02)资助.

Abstract

Abstract: A novel class of amphiphilic polyelectrolytes bearing Gemini surfactant units were synthesized using the copolymerization of acryloyloxyethyltrimethylammonium chloride(D) and Gemini surfactant type monomer 1,3-bis(N,N-dimethyl-N-alkylammonium)-2-proplylacrylate dibromide(G)(alkyl=tetradecyl or cetyl). The self-aggregation properties of these polyelectrolytes in aqueous solution were investigated by steady fluorescence, conductivity, dynamic light scattering(DLS) and Transmission electron microscopy(TEM) techniques as the function of the molar fraction of Gemini surfactant units in the polyelectrolyte. It was found that the cri-tical aggregation concentration(CAC) decreases with the increase of molar fraction of Gemini surfactant segments and the length of alkyl chain on the Gemini surfactant units. Two kinds of aggregates coexist in the solution, one of which is suggested to be intrapolymer aggregate and the other is interpolymer aggregate. With the increase of alkyl chain length, the polyelectrolytes exhibit a strong preference for intrapolymer hydrophobe self-aggregation. With the increase of molar fraction of Gemini segments, the hydrodynamic radius(Rh) increases in the case of D14G and oppositely decreases slightly in the case of D16G.

Key words: Polyelectrolyte, Amphiphilicity, Gemini surfactant-type monomer, Aggregation behavior

TrendMD:

LI Rong-Qiang, XU Cheng-Feng, WEI Lu-Bin, WANG Jin-Ben*. Synthesis and Self-aggregation Behavior of Novel Amphiphilic Polyelectrolytes Containing Gemini Surfactant Units[J]. Chem. J. Chinese Universities, 2010, 31(10): 2024.

References

[1]Ren H. J., Chen W., Zheng Y. F., Luan Z. K.. React. Funct. Polym.[J], 2007, 67(7): 601—608 [2]Antunes E., Garcia F., Ferreira P., Blanco A., Negro C., Rasteiro M. G.. Ind. Eng. Chem. Res.[J], 2008, 47(23): 9370—9375 [3]Wang Y., Ke C. Y., Beh C. W., Liu S. Q., Goh S. H., Yang Y. Y.. Biomaterials[J], 2007, 28(35): 5358—5368 [4]Gruber J. V.. J. Cosmet. Sci.[J], 2009, 60(3): 385—386 [5]BAI Ying(白莹), PAN Chun-Hua(潘春花), WU Feng(吴锋), WU Chuan(吴川), YE Lin(叶霖), FENG Zeng-Guo(冯增国). Chem. J. Chinese Universities(高等学校化学学报)[J], 2007, 28(9): 1796—1800 [6]Sabhapondit A., Borthakur A., Haque I.. Energy Fuels[J], 2003, 17(3): 683—688 [7]Kotz J., Kosmella S., Beitz T.. Prog. Polym. Sci.[J], 2001, 26(8): 1199—1232 [8]Nichifor M., Bastos M., Lopes S., Lopes A.. J. Phys. Chem. B[J], 2008, 112(49): 15554—15561 [9]Nichifor M., Lopes S., Bastos M., Lopes A.. J. Phys. Chem. B[J], 2004, 108(42): 16463—16472 [10]Bai G. Y., Nichifor M., Lopes A., Bastos M.. J. Phys. Chem. B[J], 2005, 109(46): 21681—21689 [11]Pawlowski D., Tieke B.. Langmuir[J], 2003, 19(16): 6498—6504 [12]Bokias G., Hourdet D.. Polymer[J], 2001, 42(15): 6329—6337 [13]Sun G., Zhang M., He J., Ni P.. J. Polym. Sci., Part A: Polym. Chem.[J], 2009, 47: 4670—4684 [14]Zhao Y., Zhou J., Xu X., Liu W., Zhang J., Fan M., Wang J.. Colloid Polym. Sci.[J], 2009, 287(2): 237—241 [15]Losada R., Wandrey C.. Macromolecules[J], 2009, 42(9): 3285—3293 [16]Losada R., Wandrey C.. Macromol. Rapid Commun.[J], 2008, 29(3): 252—257 [17]Pindzola B. A., Jin J., Gin D. L.. J. Am. Chem. Soc.[J], 2003, 125(10): 2940—2949 [18]Abe M., Tsubone K., Koike T., Tsuchiya K., Ohkubo T., Sakai H.. Langmuir[J], 2006, 22(20): 8293—8297 [19]Kim T., Hirao T., Ikeda I.. J. Am. Oil Chem. Soc.[J], 1996, 73(7): 61—71 [20]Kalyanasundaram K., Thomas J. K.. J. Phys. Chem.[J], 1977, 81(23): 2176—2180 [21]Li Y., Li P., Wang J., Wang Y., Yan H., Thomas R. K.. Langmuir[J], 2005, 21(15): 6703—6706 [22]Suwa M., Hashidzume A., Morishima Y., Nakato T., Tomida M.. Macromolecules[J], 2000, 33(21): 7884—7892 [23]Yamamoto H., Tomatsu I., Hashidzume A., Morishima Y.. Macromolecules[J], 2000, 33(21): 7852—7861

Synthesis and Self-aggregation Behavior of Novel Amphiphilic Polyelectrolytes Containing Gemini Surfactant Units

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	YE Hui, LIU Yabo, JIA Yuxi. Numerical Simulation of Swelling and Drug Release Processes for Weak Polyelectrolyte Hydrogels^† [J]. Chem. J. Chinese Universities, 2018, 39(4): 817.
[2]	SONG Rongguang, ZHOU Yihan, LI Fan, WANG Haiyan, SHI Tongfei, ZHANG Guo. pH-Dependent Specific Protein Recognition Ability of Glycopolymers^† [J]. Chem. J. Chinese Universities, 2015, 36(12): 2604.
[3]	DONG Yunhong, CHEN Anpu, ZHAO Nanrong. Diffusion Coefficient of Nanoparticles in Semidilute Polyelectrolyte Solutions Based on Mode Coupling Theory^† [J]. Chem. J. Chinese Universities, 2015, 36(11): 2251.
[4]	MAO Jun, BO Shu-Qin, JI Xiang-Ling. Enzymatic Degradation of Biocompatible Block Polyelectrolyte Micelles in Aqueous Solutions [J]. Chem. J. Chinese Universities, 2012, 33(09): 2099.
[5]	WANG Ya-Li, NIE Yan-Yan, JIANG Yu-Cheng, HU Man-Cheng, LI Shu-Ni, ZHAI Quan-Guo. Synthesis, Structure and Performance of Soluble Polyaniline by CPO-catalyzed Oxidation Using Small Molecule as Dopant or Polyelectrolyte as Template [J]. Chem. J. Chinese Universities, 2012, 33(06): 1344.
[6]	FAN Hong-Liang, ZHANG Tao, LI Zu-Hong, WU Li-Yuan, JIN Qin-Han. Specific Assay of Amino Acids Based on a Fluorescent Conjugated Polyelectrolyte with Multi-carboxylates [J]. Chem. J. Chinese Universities, 2012, 33(01): 54.
[7]	LI Fan, PEI Dan-Feng, SHI Tong-Fei, ZHANG Guo. Synthesis and Characterization of Novel Multi\\|temperature Responsive Glycopolymers [J]. Chem. J. Chinese Universities, 2011, 32(8): 1667.
[8]	LI Fan, PEI DanFeng, SHI Tong-Fei, ZHANG Guo. Synthesis of New pH-responsive Glycopolymers by Atom Transfer Radical Polymerization [J]. Chem. J. Chinese Universities, 2011, 32(10): 2243.
[9]	AN Hui-Yong, SONG Chun-Lei, XU Kun, LI Wen-Bo, LIU Chang, WANG Pi-Xin*. Preparation, Characterization and Solution Properties of Poly(AM/DMC/C11AM) [J]. Chem. J. Chinese Universities, 2010, 31(11): 2308.
[10]	TONG Wei-Yi, LIU Zhi-Cheng, KONG De-Jin, QI Xiao-Lan, GUO Yang-Long. Synthesis and Characterization of ZSM-5/Nano-β Core-Shell Composite-Zeolites [J]. Chem. J. Chinese Universities, 2009, 30(5): 959.
[11]	ZHANG Guang-Wei^1,2, FAN Qu-Li², HUANG Wei^2*. Synthesis and Quenching Behavior of a Novel Cationic Poly(p-phenylenevinylene) Related Copolymer [J]. Chem. J. Chinese Universities, 2009, 30(2): 413.
[12]	PENG Cai-Yu, TONG Wei-Jun, HAN Bao-San, WANG Zhao-Hai, GAO Chang-You*, ....... Preparation, Protein Adsorption and Blood Compatibility of Polyelectrolyte Multilayers with Different Surface Properties [J]. Chem. J. Chinese Universities, 2009, 30(11): 2311.
[13]	ZHANG Peng, QIAN Jin-Wen^*, XUAN Li-Jing, AN Quan-Fu. Pervaporation Performance of Polyelectrolyte PDDA/PSS Layer-by-layer Self-assembly Multilayer Membranes [J]. Chem. J. Chinese Universities, 2008, 29(9): 1885.
[14]	YANG Xiao-Feng¹, LI Xiao-Dong^1,2*, SHEN Jia-Cong². Preparation of “Micelles Enhanced” Polyelectrolyte Capsules [J]. Chem. J. Chinese Universities, 2007, 28(5): 974.
[15]	LI Xiao-Dong^1,2*, SHEN Jia-Cong². Encapsulation and Release of the Micelles-enhanced PE Capsules Filled with Rhodamine B [J]. Chem. J. Chinese Universities, 2007, 28(10): 2000.