Admicelles and Adsolubilization of Extended Surfactants on Alumina

doi:10.7503/cjcu20200433

Abstract

Abstract:

A series of sodium linear alkyl polyoxypropylene ether sulfates（C_cP_pS， c=8 or 16， p=9； c=12， p=3， 6 or 9） was synthesized and structurally identified to investigate the formation of admicelles of extended surfactants on alumina and the related adsolubilization. The formation of bilayer admicelles of C₁₂P₉S on alumina was identified by the adsolubilization result of cationic dye methylence blue（MB） in comparison with sodium dodecyl ether sulfate（SDS）， but the adsorption capacity of C₁₂P₉S and adsolubilization capacity of MB were both less than SDS for its rugby-shaped molecule caused by polyoxypropylene（PPO） spacer. On the contrary， C₁₂P₉S@Al₂O₃ showed stronger adsolubilization capacities of weak polar PA molecules and water-insoluble ST molecules than those of SDS evidently. Moreover， the adsolubilization capacity of PA by C₁₂P₉S@Al₂O₃ was 8.5 times of SDS@Al₂O₃， which means that PA molecules were adsolubilized as expected in the swollen PPO domains in bilayer admicelles of C₁₂P₉S on alumina， and makes extended surfactant modified alumina potential application prospects in some fields such as wastewater treatment and drug delivery systems.

Key words: Extended surfactant, Alumina, Adsorption, Bilayer admicelle, Adsolubilization

CLC Number:

O647.2

TrendMD:

HU Xueyi, HAN Lulu, FANG Yun, XIA Yongmei. Admicelles and Adsolubilization of Extended Surfactants on Alumina[J]. Chem. J. Chinese Universities, 2021, 42(3): 843.

Figures/Tables 8

References 24

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Surfactant	Linear regression equation	R²
C₁₂P₃S	y=0.166x+0.1050	0.998
C₁₂P₆S	y=0.171x+0.1115	0.999
C₁₂P₉S	y=0.204x+0.06197	0.997
C₈P₉S	y=0.194x+0.06848	0.997
C₁₆P₉S	y=0.120x+0.1426	0.998
SDS	y=0.202x+0.1415	0.999

Surfactant	Linear regression equation	R²
C₁₂P₃S	y=0.166x+0.1050	0.998
C₁₂P₆S	y=0.171x+0.1115	0.999
C₁₂P₉S	y=0.204x+0.06197	0.997
C₈P₉S	y=0.194x+0.06848	0.997
C₁₆P₉S	y=0.120x+0.1426	0.998
SDS	y=0.202x+0.1415	0.999

Absorbent	Γ_MB/(mmol·mol^-1)	Γ_ST/(mmol·mol^-1)	Γ_PA/(mmol·mol^-1)
SDS@Al₂O₃	380	1700	240
C₁₂P₉S@Al₂O₃	220	3020	2030
Al₂O₃	ca. 0	ca. 0	ca. 0

Absorbent	Γ_MB/(mmol·mol^-1)	Γ_ST/(mmol·mol^-1)	Γ_PA/(mmol·mol^-1)
SDS@Al₂O₃	380	1700	240
C₁₂P₉S@Al₂O₃	220	3020	2030
Al₂O₃	ca. 0	ca. 0	ca. 0

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