Chem. J. Chinese Universities ›› 2020, Vol. 41 ›› Issue (9): 2032.doi: 10.7503/cjcu20200311

• Physical Chemistry • Previous Articles     Next Articles

Preparation and Electrical Properties of Germanium Telluride Field Effect Transistor

ZHANG Xin1, ZHAO Fulai1, WANG Yu1, LIANG Xuejing1, FENG Yiyu1,2, FENG Wei1,2()   

  1. 1.School of Materials Science and Engineering, 2. Key Laboratory of Advanced Ceramics and Machining Technology, Ministry of Education, Tianjin University, Tianjin 300072, China
    3.Key Laboratory of Materials Processing and Mold, Ministry of Education, Zhengzhou University, Zhengzhou 450002, China
  • Received:2020-06-01 Online:2020-09-10 Published:2020-09-02
  • Contact: FENG Wei E-mail:weifeng@tju.edu.cn
  • Supported by:
    Supported by the State Key Program of National Natural Science Foundation of China(51633007);the National Natural Science Foundation of China(51573125)

Abstract:

Compared with three-dimensional(3D) materials, two-dimensional(2D) materials have excellent photoelectric properties, and can be used in many fields such as electronics and photocatalysis, etc. Two-dimensional germanium telluride(2D-GeTe) belongs to a narrow-band gap semiconductor, and its carrier mobility has a theoretical value of up to 1066.33 cm2·V-1·s-1, but its crystal structure limits its application in the field of optoelectronics. In this work, a GeTe alloy was synthesized by a high-temperature sintering method in a tube furnace, and then a GeTe nanosheet with a lateral dimension about 10 μm successfully was prepared by micromechanical exfoliation. After heat-treating the material, through the method of electron beam exposure and vacuum sputtering coating, using titanium(10 nm)/gold(60 nm) alloy as the contact electrode, the 2D-GeTe based field effect transistor(FET) was prepared, and the electrical properties were measured at room temperature. The results show that the GeTe nanomaterials obtained by exfoliating have good crystallinity, a wide optical absorption range, and an optical band gap of 1.98 eV, which belongs to p-type semiconductors. At the same time, the FET devices prepared based on 2D-GeTe exhibits favorable electrical properties, with a channel length of 7 μm, a channel width of 3 μm, and a carrier mobility of 6.4 cm2·V-1·s-1, the switching current ratio is 670. And the output curve is non-linear, which indicates that due to the preparation process and the environment, there is a clear Schottky barrier between the material and the contact electrode. In short, the study of 2D-GeTe electrical properties and the successful preparation of FET devices have enriched the types of two-dimensional materials in the field of semiconductor optoelectronic devices, and provide some reference and guidance for the research of high optoelectronic devices.

Key words: Germanium telluride, Two-dimensional material, Micromechanical stripping method, Field effect transistor

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