Synthesis and Enzymatic Activity of Ni, Ru Co-doped CePO4 Nanomaterials †

doi:10.7503/cjcu20200119

Abstract

Abstract:

NiRu-CePO₄ nanoparticles with high specific surface area were synthesized by a simple hydrothermal method, which could avoid the separate nucleation process of the precious metal. The X-ray diffraction(XRD) pattern of NiRu-CePO₄ is consistent with hexagonal cerium phosphate. The transmission eletron microscopy(TEM) and energy dispersive X-ray(EDX) characterization indicated that the nanoparticles have a length of ca. 20 nm along the longitude and the doped metals Ni and Ru are uniformly dispersed. The BET area is determined as 178.4 m²/g, and the zeta potential as -18.2 mV. NiRu-CePO₄ exhibits good peroxidase-like and oxidase-like activities in wide pH range. 3,3',5,5'-tetramethylbenzidine(TMB) was used as the electron donor and the chromogenic reagent, and the activities were evaluated by monitoring the absorbance at 652 nm. The morphology, dispersion of the elements and valence state of Ce had no significant change when characterizing the used catalyst, confirming the good stability of NiRu-CePO₄.

Key words: Cerium phosphate, Ruthenium, Bimetal, Peroxidase mimic, Oxidase mimic

CLC Number:

O614

TrendMD:

WANG Qishun, ZHANG Zeshu, WANG Huan, LIU Yu, SONG Shuyan, ZHANG Hongjie. Synthesis and Enzymatic Activity of Ni, Ru Co-doped CePO₄ Nanomaterials ^†[J]. Chem. J. Chinese Universities, 2020, 41(5): 947.

Figures/Tables 7

References 32

[1]	Guo Y., Mei S., Yuan K., Wang D. J., Liu H. C., Yan C. H., Zhang Y. W., ACS Catal., 2018,8, 6203—6215
[2]	Tang Y., Wei Y. C., Wang Z. Y., Zhang S. R., Li Y. T., Nguyen L., Li Y. X., Zhou Y., Shen W. J., Tao F. F., Hu P. J., J. Am. Chem. Soc., 2019,141, 7283—7293 doi: 10.1021/jacs.8b10910 URL pmid: 31021087
[3]	Wang D. Y., Kang Y. J., Doan-Nguyen V., Chen J., Küngas R., Wieder N. L., Bakhmutsky K., Gorte R. J., Murray C. B., Angew. Chem. Int. Ed., 2011,50, 4378—4381 doi: 10.1002/anie.201101043 URL pmid: 21480452
[4]	Wang F., He S., Chen H., Wang B., Zheng L. R., Wei M., Evans D. G., Duan X., J. Am. Chem. Soc., 2016,138, 6298—6305 doi: 10.1021/jacs.6b02762 URL pmid: 27135417
[5]	Kanai S., Nagahara I., Kita Y., Kamata K., Hara M., Chem. Sci, 2017,8, 3146—3153 doi: 10.1039/c6sc05642c URL pmid: 28507690
[6]	Tang C., Bando Y., Golberg D., Ma R., Angew. Chem. Int. Ed., 2005,44, 576—579 doi: 10.1002/anie.200461171 URL pmid: 15612077
[7]	Sato A., Ogo S., Kamata K., Takeno Y., Yabe T., Yamamoto T., Matsumura S., Hara M., Sekine Y., Chem. Commun, 2019,55, 4019—4022 doi: 10.1039/c9cc00174c URL pmid: 30806415
[8]	Liu C., Li F., Wu J., Hou X., Huang W., Zhang Y., Yang X. G., J. Hazard. Mater., 2019,363, 439—446 doi: 10.1016/j.jhazmat.2018.09.054 URL pmid: 30340173
[9]	Li F., Xiao D. H., Zhang Y. B., Wang D. Q., Pan X. Q., Yang X. G., Chin. J. Catal., 2010,31, 938—942
[10]	Zhao X., Huang L., Li H. R., Hu H., Hu X. N., Shi L. Y., Zhang D. S., Appl. Catal. B Environ., 2016,183, 269—281
[11]	Tian L., Long Y., Song S. S., Wang C., Chem. J. Chinese Universities, 2019,40, 2549—2555
	( 田龙, 龙艳, 宋术岩, 王成 . 高等学校化学学报, 2019,40, 2549—2555)
[12]	Cored J., García-Ortiz A., Iborra S., Climent M. J., Liu L. C., Chuang C. H., Chan T. S., Escudero C., Concepción P., Corma A., J. Am. Chem. Soc., 2019,141, 19304—19311 doi: 10.1021/jacs.9b07088 URL pmid: 31774282
[13]	Song S. S., Li K., Pan J., Wang F., Li J. Q., Feng J., Yao S., Ge X., Wang X., Zhang H. J., Adv. Mater., 2017,29, 1605332
[14]	Li J., Song S. S., Long Y., Wu L. L., Wang X., Xing Y., Jin R. C., Liu X. G., Zhang H. J., Adv. Mater., 2018,30, 1704416
[15]	Dong C. Y., Lian C., Hu S. C., Deng Z. S., Gong J. Q., Li M. D, Liu H. L., Xing M. Y., Zhang J. L., Nat. Commun., 2018,9, 1252 doi: 10.1038/s41467-018-03666-2 URL pmid: 29593250
[16]	Sun C. W., Li H., Chen L. Q., Energy Environ. Sci., 2012,5, 8475
[17]	Yang W. T., Wang X., Song S. S., Zhang H. J., Chem., 2019,5, 1743—1774
[18]	Chen G. B., Gao R., Zhao Y. F., Li Z. H., Waterhouse G. I. N., Shi R., Zhao J. Q., Zhang M. T., Shang L., Sheng G. Y., Zhang X. P., Wen X. D., Wu L. Z., Tung C. H., Zhang T. R., Adv. Mater., 2018,30, 1704663
[19]	Zhao Y. F., Zhou H., Chen W. X., Tong Y. J., Zhao C., Lin Y., Jiang Z., Zhang Q. W., Xue Z. G., Cheong W. C., Jin B. J., Zhou F. Y., Wang W. Y., Chen M., Hong X., Dong J. C., Wei S. Q., Li Y. D., Wu Y. E., J. Am. Chem. Soc., 2019,141, 10590—10594 doi: 10.1021/jacs.9b03182 URL pmid: 31188590
[20]	Lin L., Li H. B., Yan C. C., Li H. F., Si R., Li M. R., Xiao J. P., Wang G. X., Bao X. H., Adv. Mater., 2019,31, 1903470
[21]	Zhao X. X., Yu R. B., Tang H. J., Mao D., Qi J., Wang B., Zhang Y., Zhao H. J., Hu W. P., Wang D., Adv. Mater., 2017,29, 1700550
[22]	Lv C. X., Yang X. F., Umar A., Xia Y. Z., Jia Y., Shang L., Zhang T. R., Yang D. J., J. Mater. Chem. A, 2015,3, 22708—22715
[23]	Wei S. J., Li A., Liu J. C., Li Z., Chen W. X., Gong Y., Zhang Q. H., Cheong W. C., Wang Y., Zheng L. R., Xiao H., Chen C., Wang D. S., Peng Q., Gu L., Han X. D., Li J., Li Y. D., Nat. Nanotechnol., 2018,13, 856—861 doi: 10.1038/s41565-018-0197-9 URL pmid: 30013217
[24]	Liu T. K, Hong X. L, Liu G. L, ACS Catal., 2019,10, 93—102
[25]	Wang F., Song S. Y, Li K., Li J. Q., Pan J., Yao S., Ge X., Feng J., Wang X., Zhang H. J., Adv. Mater., 2016,28, 10679—10683 doi: 10.1002/adma.201603608 URL pmid: 27748988
[26]	Metelitza D. I., Naumchik I. V., Karasyova E. I., Polozov G. I., Shadyro O. I., Appl. Biochem. Microbiol., 2003,39, 352—362
[27]	Liu X. W., Byrne R. H., Geochim. Cosmochim. Acta, 1997,61, 1625—1633
[28]	Wang H., Liu C. Q., Liu Z., Ren J. S., Qu X. G., Small, 2018,14, 1703710
[29]	Wang H., Li P. H., Yu D. Q., Zhang Y., Wang Z. Z., Liu C. Q., Qiu H., Liu Z., Ren J. S., Qu X. G., Nano Lett., 2018,18, 3344—3351 doi: 10.1021/acs.nanolett.7b05095 URL pmid: 29763562
[30]	Wang L. N., Yuan F. L., Niu X. Y., Kang C. H., Li P. Y., Li Z. B., Zhu Y. J., RSC Adv., 2016,6, 40175—40184
[31]	Takita Y., Qing X., Takami A., Nishiguchi H., Nagaoka K., Appl. Catal. Gen, 2005,296, 63—69
[32]	Larese C., Galisteo F. C., Granados M. L., Mariscal R., Fierro J. L. G., Lambrou P. S., Efstathiou A. M., J. Catal., 2004,226, 443—456

Synthesis and Enzymatic Activity of Ni, Ru Co-doped CePO₄ Nanomaterials ^†

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 7

References 32

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	HE Beibei, YANG Kuihua, LYU Rui. Construction of Mn-Cu Bimetal Containing Phyllosilicate Nanozyme and Evaluation of the Enzyme-like Properties [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220150.
[2]	DUAN Jun, ZHOU Pingping, ZHANG Liqian, MA Lin, YU Wen, ZHU Meiqi, ZHUANG Minyan, YANG Fenglei, CAO Changsheng, ZHANG Peng, SHI Yanhui. Syntheses of Imidazole-coordinated Ru（II） Half-sandwich Macrocyclic Complexes and Their Anti-cancer Activity [J]. Chem. J. Chinese Universities, 2021, 42(12): 3589.
[3]	HUANG Yunshuai, YANG Ni, WU Zehong, WU Si. Ruthenium Complexes with Photoresponsive Coordination Bonds for Light-controlled Surface Functions ^† [J]. Chem. J. Chinese Universities, 2020, 41(6): 1174.
[4]	WANG Jinyu, LIU Chunli, CHEN Yanhui. Synthesis of Aminophosphine Ruthenium Carbene Complex and Its Application in Olefins Metathesis Reaction [J]. Chem. J. Chinese Universities, 2020, 41(12): 2766.
[5]	CHEN Danyi, ZHANG Fumei, HE Dan, ZHANG Zimei, ZHONG Fen, WEN Simiaomiao, LIU Qixing, ZHOU Haifeng. Synthesis of Chiral Phenylbenzothiazole Methanol via Transfer Hydrogenation Catalyzed by Ruthenium Complexes^† [J]. Chem. J. Chinese Universities, 2020, 41(10): 2264.
[6]	YANG Xiaotian,GENG Zhibin,KUANG Siliang,FENG Shouhua. FeNi(OH)_x Thin Films Prepared by Electrospray Ionization for Electrocatalytic Water Oxidation ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 56.
[7]	LI Xiaoli, HUANG Liang, DUAN Hongjuan, ZHANG Li, ZHANG Haijun. Preparation and Catalytic Activity of Graphene Supported Pt/Co Nanoparticles for Hydrogen Generation from KBH₄ [J]. Chem. J. Chinese Universities, 2019, 40(8): 1662.
[8]	ZHAO Yachen,LI Ji,ZHANG Peipei,LIU Shuxian,WEI Daina,SU Zhi,QIAN Yong,WANG Feili,Peter John Sadler,LIU Hongke. Synthesis, Characterization and DNA, BSA Interactions of Mononuclear Ruthenium Complexes with Modified 1,10-Phenanthrolines Ligands^† [J]. Chem. J. Chinese Universities, 2019, 40(1): 30.
[9]	WANG Dongmei,LIU Zihua,LI Guanghua,LIU Yunling,LI Chunxia. Synthesis, Structure and Fluorescent Property of Indium-based Bimetallic Metal-organic Frameworks^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1886.
[10]	LU Lilin,SHU Hongfei,RUAN Zhuhua,NI Jiaqi,ZHANG Haijun. Preparation of Graphene-supported Pt-Pd Catalyst and Its Catalytic Activity and Mechanism for Hydrogen Generation Reaction^† [J]. Chem. J. Chinese Universities, 2018, 39(5): 949.
[11]	WANG Tieshi, CHEN Jianjun, YE Lin, ZHANG Aiying, FENG Zengguo. Synthesis of Oxygen-bridged Binuclear Titanium and Nickel Complexes and Application in Catalysis of Bimodal Polyethylene^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2586.
[12]	LI Xiang,WANG Huiying,WANG Hongqiang,YE Jinting,QIU Yongqing. Theoretical Studies on the Second-order Nonlinear Optical Properties of Ru^Ⅱ/Ⅲ Complexes of Bipyridyl^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2221.
[13]	CHENG Wei, CHEN Cailing, YU Ying, LI Chunguang, GAO Lu, SHI Zhan. Facile Synthesis of ZIFs-derived Hollow Bimetal (Zn,Co)S Nanocrystals for Supercapacitors [J]. Chem. J. Chinese Universities, 2017, 38(8): 1303.
[14]	LI Xiao, GAO Liguo, GONG Ying, MA Yajun, MA Xiangrong. Direct Asymmetric Aldol Reaction of Acetophenones and Aromatic Aldehydes Catalyzed by Chiral Al/Zn Heterobimetallic Compounds ZABDP^† [J]. Chem. J. Chinese Universities, 2017, 38(5): 778.
[15]	HAN Tianhao, LIANG Fuxin, YANG Zhenzhong. Synthesis of Au-Ni Bimetallic Nanoparticles with Tunable Aspect Ratio^† [J]. Chem. J. Chinese Universities, 2017, 38(11): 1921.