Preparation of Ni-Al2O3 Catalysts Derived from Hydrotalcite and Its Catalytic Performance for Hydrogenation of Levulinic Acid

doi:10.7503/cjcu20190068

Abstract

Abstract: A series of Ni-Al₂O₃ catalysts with different Ni/Al molar ratios was prepared using NiAl-NO₃-LDH as precursors and characterized by means of N₂-physical adsorption, ICP-OES, TG/DTG, XRD, XPS, H₂-TPR/TPD and NH₃-TPD techniques. The catalytic performance of these catalysts for liquid phase hydrogenation of levulinic acid was valuated. The results demonstrated that with the increasing of Ni/Al molar ratio, isolated γ-AlOOH species evolved dissociative Ni(OH)₂ which existed in the hydrotalcite-like laminate structure, the interaction between metal-support in catalyst become weaker, the dispersion of Ni species decreased, surface acidic sites increased first and then decreased. When Ni/Al molar ratio is 3, the catalyst had the most abundant acidic and hydrogenation sites and exhibited the high performance for the hydrogenation of levulinic acid to γ-valerolactone. 92.7% yield of γ-valerolactone was obtained under the condition of 160℃, 4 MPa H₂ pressure.

Key words: Levulinic acid, Ni-Al₂O₃ catalyst, γ-Valerolactone, Catalytic hydrogeation

CLC Number:

O643

TrendMD:

ZHANG Yin, GUO Jianjian, WANG Jie, LI Haitao, ZHAO Yongxiang. Preparation of Ni-Al₂O₃ Catalysts Derived from Hydrotalcite and Its Catalytic Performance for Hydrogenation of Levulinic Acid[J]. Chem. J. Chinese Universities, 2019, 40(8): 1686.

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Preparation of Ni-Al₂O₃ Catalysts Derived from Hydrotalcite and Its Catalytic Performance for Hydrogenation of Levulinic Acid

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