Investigation on Thickening Property of the Hydrophobically Associating Polyacrylamides†

doi:10.7503/cjcu20140179

Abstract

Abstract:

Hydrophobically associating polymers are distinctive water-soluble polymers with a few hydrophobic groups in the hydrophilic macromolecular chain. Because of its unique amphiphilic molecule structure, it has special rheological properties. Six hydrophobically associating polyacrylamide derivatives with different modification monomers were synthesized. Their intramolecular and intermolecular association behavior by internal factors such as the degree of polymerization, the block copolymer content as well as the size of hydrophobic groups and the external factors of the resistance to shear, salt tolerance were investigated. The hydrophobic chain can improved the viscosity and salt resistance of polymers.

Key words: Hydrophobic association, Polyacrylamide, Associating mechanism, Thickening property

CLC Number:

O632.63

TrendMD:

CAO Xulong, HU Yue, SONG Xinwang, ZHU Yangwen, HAN Yugui, WANG Kunpeng, GUO Dongsheng, LIU Yu. Investigation on Thickening Property of the Hydrophobically Associating Polyacrylamides^†[J]. Chem. J. Chinese Universities, 2014, 35(9): 2037.

Figures/Tables 7

Fig.1 Structures of polymers PAM1—PAM6

Fig.2 Critical associating concentration(CAC) of PAM1(a), PAM2(b) and PAM3(c)

Fig.3 Effect of shear rate on the apparent viscosity of polymer aqueous solutions at 45 ℃ a. PAM1; b. PAM2; c. PAM3.

Fig.4 CAC of PAM4(a), PAM5(b) and PAM6(c) (45 ℃, 7.34 s-1)

Fig.5 Effects of shear rate on the apparent viscosity of polymer aqueous solutions at 45 ℃ (A) PAM4; (B) PAM5; (C) PAM6.

Fig.6 Recoveries of viscosity of PAM4(a), PAM5(b) and PAM6(c) after shearing for 2 min at 45 ℃ Shear rate: 200 s-1.

Fig.7 Relationship between the apparent viscosity of polymer and NaCl a. PAM4; b. PAM4+10 g/L NaCl; c. PAM5; d. PAM5+10 g/L NaCl; e. PAM6; f. PAM6+10 g/L NaCl.

References 24

[1]	Song C. L., Yang Q. B., An H. Y., Chin. J. Appl. Chem., 2010, 39(5), 735—746
	(宋春雷, 杨青波, 安会勇. 应用化学, 2010, 39(5), 735—746)
[2]	Li L. H., Guo Y. J., Luo P. Y., Chin. J. Appl. Chem., 2003, 20(11), 1045—1051
	(李林辉, 郭拥军, 罗平亚. 应用化学, 2003, 20(11), 1045—1051)
[3]	Evani S., Rose G. D., Polymer Material Science Engineering,1987, 57, 477—481
[4]	Hiroshi Y., Itsuro T., Akihito H., Macromolecules,2000, 33, 7852—7861
[5]	Iliopoulos T. C., Guylaine D., Macromolecules,2000, 33, 2936—2943
[6]	Li J., Yang Y., Cao X. L., Zhang J. C., Zhang L., Zhang L., Zhao S., Chem. J. Chinese Universities,2014, 35(4), 791—797
	(李静, 杨勇, 曹绪龙, 张继超, 张磊, 张路, 赵濉. 高等学校化学学报, 2014, 35(4), 791—797)
[7]	Klucker R., Munch J. P., Schosseler F., Macromolecules,1997, 30, 3839—3848
[8]	Feng Y. J., Luo P. Y., Dong Z. X., The Second Oil and Gas Reservoir Engineering International Symposium,1999, 10, 20—21
	(冯玉军, 罗平亚, 董兆雄. 第二届油气藏开发工程国际学术研讨会, 1999, 10, 20—21)
[9]	Guo Y. J., Feng R. S., Xue X. S., Journal of Southwest Petroleum University,2007, 29(4), 164—166
	(郭拥军, 冯茹森, 薛新生. 西南石油大学学报, 2007, 29(4), 164—166)
[10]	Li A. H., Guo Y. J., Feng R. S., Journal of Southwest Petroleum University,2007, 29(5), 168—171
	(李爱辉, 郭拥军, 冯茹森. 西南石油大学学报, 2007, 29(5), 168—171)
[11]	Zhong C. R., Huang R. H., Liu Q., Petrochemical Technology,2003, 32(12), 1037—1041
	(钟传蓉, 黄荣华, 刘强. 石油化工, 2003, 32(12), 1037—1041)
[12]	Zhong C. R., Huang R. H., Zhang X., Polymer Materials Science & Engineering,2003, 19(6), 126—130
	(钟传蓉, 黄荣华, 张熙. 高分子材料科学与工程, 2003, 19(6), 126—130)
[13]	Zhou C., Yang W., Yu Z., Polym. Bull., 2010, 12(4), 1045—1051
[14]	Valint J. P. L., Bock J., Macromolecules,1988, 21, 175—179
[15]	Cui P., Ma J. T., Huang R. H., Oil Field Chemistry,2001, 2, 159—162
	(崔平, 马俊涛, 黄荣华. 油田化学, 2001, 2, 159—162)
[16]	Lantman C. W., MacKnight W. J., Peiffer D. G., Macromolecules,1987, 20(5), 1096—1101
[17]	Iliopoulos I., Wang T. K., Audebert R., Langmuir,1991, 7(4), 617—619
[18]	Li Z. Q., Hu C. X., Cheng Y. Q., Xu H., Cao X. L., Song X. W., Zhang H. Y., Liu Y., Chem. J. Chinese Universities,2013, 34(4), 853—857
	(李振泉, 胡春秀, 程玉桥, 徐辉, 曹绪龙, 宋新旺, 张衡益, 刘育. 高等学校化学学报, 2013, 34(4), 853—857)
[19]	Cao B. G., Li H. B., Luo P. Y., Oil Field Chemistry,2005, 22, 168—172
	(曹宝格, 李华斌, 罗平亚. 油田化学, 2005, 22, 168—172)
[20]	Wang K. P., Guo D. S., Zhao H. X., Liu Y., Chem. Eur. J., 2014, 20, 4023—4031
[21]	Jia Z. F., Li Z. Y., Zhong J. X., Drilling Fluid & Completion Fluid,2007, 24, 53—57
	(贾振福, 李早元, 钟静霞. 钻井液, 2007, 24, 53—57)
[22]	Li S. S., Liao M. Y., Jin M. H., Chem. Res. Chinese Universities,2014, 30(3), 518—520
[23]	Li M. R., Liu Z., Cao X. L., Acta Petrolei Sinica,2012, 28, 1037—1042
	(李美蓉, 柳智, 曹绪龙. 石油学报, 2012, 28, 1037—1042)
[24]	Su R., Wang X. H., Zhao T. Q., Yu W. Z., Feng X. D., Zhang H. Q., Yu A. M., Chem. Res. Chinese Universities,2012, 28(1), 14—18