Reinforcement and Tougheness of Quartz Fiber/Silicon-containing Arylacetylene with Heat-resistant Polyetherimide Macromolecular Coupling Agent†

doi:10.7503/cjcu20170149

Abstract

Abstract:

A novel acetylene-terminated polyetherimide macromolecular coupling agent(BDA-K) was designed and synthesized, and its effects on the interfacial reinforcement and toughness of the quartz fiber(QF) reinforced silicon-containing aryl-alkyne(PSA) matrix composites were investigated. The interlaminar shear strength(ILSS), flexural strength and notched impact strength increased by 54.1%, 59.0% and 23.8% compared with those of untreated at room temperature. The retention of ILSS and flexural strength reached 89.0% and 89.6% at 250 ℃ and 63.3% and 67.9% at 500 ℃, respectively. The FTIR and XPS spectra indicate that BDA-K takes part in PSA curing and effective chemical bonds form between BDA-K and QF. Owing to the introduction of heat-proof groups i.e. the imide rings to BDA-K backbone, TGA results reveal that the value of T_d5 is up to 489 ℃. The interphase morphologies by SEM show that soft and moderate macromolecule layers constructed between the matrix and the fiber treated with BDA-K, which improves the mechanical strength and toughness of the QF/PSA composites.

Key words: School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China)

CLC Number:

O631.1⁺1

TrendMD:

GU Yuanbo, HU Yanhong, DU Lei, DENG Shifeng, ZHOU Yan, RU Lingao. Reinforcement and Tougheness of Quartz Fiber/Silicon-containing Arylacetylene with Heat-resistant Polyetherimide Macromolecular Coupling Agent^†[J]. Chem. J. Chinese Universities, 2017, 38(9): 1670.

Figures/Tables 10

References 26

[1]	Itoh M., Inoue K., Hirayama N., Sugimoto N., Seguchi T., Material Science, 2002, 37, 3795—3801
[2]	Jiang Z. Y., Zhou Y., Huang F. R., Du L., Chinese Journal of Polymer Science,2011, 29(6), 726—731
[3]	Li F., Wang C., Shen X., Huang F. R., Du L., Polymer Journal, 2011, 43(7), 594—599
[4]	Yan H., Qi H. M., Huang F. R., Petrochemical Technology, 2004, 33(9), 880—883
	(严浩, 齐会民, 黄发荣.石油化工,2004, 33(9), 880—883)
[5]	Li Q., Zhou Y., Hang X., Deng S. F., Huang F. R., Du L., Li Z., European Polymer Journal, 2008, 44(8), 2538—2544
[6]	Foley M. E., Obaid A. A., Huang X., Tanoglu M., Bogetti T. A., McKnight S. H., Gillespie J. W., Composites Part A: Applied Science and Manufacturing,2002, 33(10), 1345—1348
[7]	Auad M. L., Frontini P. M., Borrajo J., Aranguren M. I., Polymer,2001, 42(8), 3723—3730
[8]	Saidpour S. H., Richardson M. O. W., Composites Part A: Applied Science and Manufacturing,1997, 28(11), 971—975
[9]	Ying S. N., Zhou X. D., Plastics Science and Technology,2012, 40(5) 39—43
	(应淑妮, 周晓东.塑料科技,2012, 40(5), 39—43)
[10]	Park R., Jang J., Composites Science and Technology,1998, 58(6), 979—985
[11]	Zhang B., Lu S. R., Wang M., Liu T., Polymer Materials Science and Engineering,2010, 26(3), 35—38
	(张波, 陆绍荣, 王敏, 刘婷.高分子材料科学与工程,2010, 26(3), 35—38)
[12]	Tang Q. H., Ai Q. S., Yang R. J., He J. Y., Chem. J. Chinese Universities, 2013, 34(1), 199—204
	(唐启恒, 艾青松, 杨荣杰, 何吉宇.高等学校化学学报,2013, 34(1), 199—204)
[13]	Pei X., Zhai W., Zheng W., Langmuir,2014, 30(44), 13375—13383
[14]	Fan W. F., Liu X. J., Yan J. L., Meng X. S., Liu J. F., Wang Z., Chem. J. Chinese Universities, 2016, 37(10), 1926—1931
	(范卫锋, 刘秀菊, 阎敬灵, 孟祥胜, 刘敬峰, 王震.高等学校化学学报,2016, 37(10), 1926—1931)
[15]	National Technical Committee on Plastics of Standardization, JC/T773—1996, Fiber-reinforced Plastics Composites-Determination of Apparent Interlaminar Shear Strength by Short-beam Method, Standards Press of China,Beijing, 1996
	(全国塑料标准化技术委员会, JC/T773-1996, 纤维增强塑料短梁法测定层间剪切强度, 北京:中国标准出版社, 1996)
[16]	National Technical Committee on Plastics of Standardization, GB/T9341-2000, Plastic-Determination of Flexural Properties, Standards Press of China, Beijing, 2000
	(中国塑料标准化技术委员会, GB/T9341-2000, 塑料弯曲性能试验方法, 北京: 中国标准出版社, 2000)
[17]	International Organization for Standardization,ISO 180:2000, Plastic-Determination of Izod Impact Strength, Switzerland, 2000
[18]	Wang D. M., Dang G. D., Zhao X. G., Zhou H. W., Wang Y. L., Chen C. H., Chem. J. Chinese Universities, 2010, 31(5), 1051—1055
	(王大明, 党国栋, 赵晓刚, 周宏伟, 王运良, 陈春海.高等学校化学学报,2010, 31(5), 1051—1055)
[19]	Qi H.M., Wang C. L., Gao J. M.,Fiber Reinforced Plastics/Composites, 2009, (6), 62—66
	(齐会民, 王春兰, 高金淼.玻璃钢/复合材料, 2009, (6), 62—66)
[20]	Jiang Z. X., Cheng X. Q., Li J., Qiu W. J., Guan S. A., Dong W., Ma Z. Y., Huang Y. D., Applied Surface Science, 2012, 258(6), 2038—2042
[21]	Yang H.H., Hu Y. H., Du L., Gu Y. B.,Fiber Reinforced Plastics/Composites, 2016, (8), 13—21
	(杨海荟, 扈艳红, 杜磊, 顾渊博.玻璃钢/复合材料, 2016, (8), 13—21)
[22]	Wu S., Liu L., Ding S. N., Li F. P., Lan L., Liu A. H., Journal of Functional Materials, 2016, 47(4), 60—63
	(吴双, 刘玲, 丁绍楠, 李风萍, 兰琳, 刘安华.功能材料,2016, 47(4), 60—63)
[23]	Zhang H. W., Zhang Y., Jiang Y., Ren Y. R., Yu Q., Journal of Chemical Engineering of Chinese Universities,2016, 30(2),459—465
	(张洪文, 张杨, 姜彦, 任玉荣, 俞强. 高校化学工程学报, 2016, 30(2), 459—465)
[24]	Rhee H. W., Bell J. P., Polymer Composites, 1991, 12(4), 213—225
[25]	Xie Y., Hill C. A. S., Xiao Z., Militz H., Mai C., Composites Part A: Applied Science and Manufacturing,2010, 41(7), 806—819
[26]	Itoh M., Inoue K., Iwata K., Ishikawa J., Takenaka Y., Advanced Materials, 1997, 9(15), 1187—1190

Temperature/℃	ILSS/MPa		Retention rate of ILSS		Flexural strength/MPa		Retention rate of flexural strength
Temperature/℃	Untreated	3.5%BDA-K	Untreated	3.5%BDA-K	Untreated	3.5%BDA-K	Untreated	3.5%BDA-K
r. t.	15.9	24.5			197.9	314.6
250	14.1	21.8	88.7	89.0	181.6	281.8	91.8	89.6
500	8.6	15.5	54.1	63.3	121.7	213.5	61.5	67.9

Temperature/℃	ILSS/MPa		Retention rate of ILSS		Flexural strength/MPa		Retention rate of flexural strength
Temperature/℃	Untreated	3.5%BDA-K	Untreated	3.5%BDA-K	Untreated	3.5%BDA-K	Untreated	3.5%BDA-K
r. t.	15.9	24.5			197.9	314.6
250	14.1	21.8	88.7	89.0	181.6	281.8	91.8	89.6
500	8.6	15.5	54.1	63.3	121.7	213.5	61.5	67.9

Sample	Element distribution(%)
Sample	C_1s	N_1s	O_1s	Si_2p
QF	56.26	9.31	21.83	12.60
QF-BDA-K	69.22	6.30	16.87	7.61

Sample	Element distribution(%)
Sample	C_1s	N_1s	O_1s	Si_2p
QF	56.26	9.31	21.83	12.60
QF-BDA-K	69.22	6.30	16.87	7.61

Binding energy/eV	Functional group	QF content(%)	QF-BDA-K content(%)
284.6	—C—C—(C₁_s peak)	56.12	64.81
286.1	—C—N—(C₁_s peak)	15.33	18.13
286.5	—C—OH(C₁_s peak)	21.56	13.23
288.2	—C=O(C₁_s peak)	6.99	3.83
398.3	—N= in a cyclic structure(N₁_s peak)	20.66	5.11
399.7	—NH—CO—(N₁_s peak)	79.34	62.85
400.4	Imide ring(N₁_s peak)		32.04
531.6	—C=O(O₁_s peak)	16.61	14.32
531.9	—Si—O—(O₁_s peak)	35.46	46.90
532.6	—C—OH(O₁_s peak)	5.13	3.79
532.7	SiO₂(O₁_s peak)	42.80	29.13
533.6	C—O—C(O₁_s peak)		5.86
101.5	—Si—O—Si—(Si₂_p peak)		21.46
102.3	—Si—OH(Si₂_p peak)	31.35	27.80
103.3	SiO₂(Si₂_p peak)	68.65	50.74