Preparation and Electrochemical Performance of Na+-stabilized Layered LiNi0.6Co0.2Mn0.2O2 Cathode Material for Lithium-ion Batteries

doi:10.7503/cjcu20160781

Abstract

Abstract:

Na-doped Li_0.98Na_0.02Ni_0.6Co_0.2Mn_0.2O₂ cathode material was synthesized through a simple oxalate co-precipitation. Powder X-ray diffraction(XRD), scanning electron microscopy(SEM), transmission electron microscopy(TEM), energy dispersive X-ray spectroscopy(EDS), inductively coupled plasma-atomic emission spectrometry(ICP-AES), electrochemical impedance spectroscopy(EIS) and galvanostatic charge-discharge tests were employed to analyze the particle morphology, crystal structure and electrochemical properties of the as-prepared materials. Results indicate that the Na-stabilized sample has a more ordered α-NaFeO₂ structure(space group R3m), reduced Li⁺/Ni²⁺ cation mixing and enlarged Li layer spacing, which facilitates the fast insertion and extraction of Li⁺ ions in the bulk structure. Electrochemical results confirm that the Na-stabilized sample has excellent cycling stability and high rate performance. After 100 cycles at 1C between 2.7 V and 4.3 V, the cathode delivers a discharge capacity of 146 mA·h/g with capacity retention of 95.4%. At 0.1C, 0.2C, 0.5C, 1C, 3C, 5C, 10C and 20C, the specific capacities of the material are 181, 168, 162, 155, 143, 136, 126 and 113 mA·h/g, respectively. The Na-doping method is facile and feasible, which can provide some valuable reference for synthesizing other high rate and high capacity layered anode/cathode oxides.

Key words: Na-doped cathode material, Li⁺ diffusion path, Electrochemical performance, Lithium-ion battery

CLC Number:

O646

TrendMD:

ZHENG Zhuo, WU Zhenguo, XIANG Wei, HUA Weibo, GUO Xiaodong. Preparation and Electrochemical Performance of Na⁺-stabilized Layered LiNi_0.6Co_0.2Mn_0.2O₂ Cathode Material for Lithium-ion Batteries[J]. Chem. J. Chinese Universities, doi: 10.7503/cjcu20160781.

References

[1] Manthiram A., Murugan A. V., Sarkar A., Muraliganth T., Energy Environ. Sci., 2008, 1(6), 621-638
[2] Dunn B., Kamath H., Tarascon J. M., Science, 2011, 334(6058), 928-935
[3] Tarascon J. M., Armand M., Nature, 2001, 414(6861), 359-367
[4] Zhang Y., Pan Y., Liu J., Wang G. L., Cao D. X., Chem. Res. Chinese Universities, 2015, 31(1), 117-122
[5] Meng Y. J., Liu X. Y., Liu L., Li B. X., Zhao X. D., Feng L. K., Wang Y. X., Wang X. F., Chem. Res. Chinese Universities, 2015, 31(5), 820-824
[6] Zhang B., He J., Hua Z. S., Wang X., Peng H. F., Chem. J. Chinese Universities, 2017, 38(1), 108-114(张勃, 何珺, 华正伸, 王新, 彭会芬. 高等学校化学学报, 2017, 38(1), 108-114)
[7] Wang X., Yang L. L., Wang C. Z., Chen G., Wei Y. J., Chem. J. Chinese Universities, 2015, 36(4), 733-738(王雪, 杨丽丽, 王春忠, 陈岗, 魏英进. 高等学校化学学报, 2015, 36(4), 733-738)
[8] Kim Y., ACS Appl. Mater. Interfaces, 2012, 4(5), 2329-2333
[9] Bi Y., Yang W., Du R., Zhou J., Liu M., Liu Y., Wang D., J. Power Sources, 2015, 283(9), 211-218
[10] Cho J., Jung H., Park Y., Kim G., Lim H. S., J. Electrochem. Soc., 2000, 147(1), 15-20
[11] Abraham D. P., Twesten R. D., Balasubramanian M., Petrov I., McBreen J., Amine K., Electrochem. Commun., 2002, 4(8), 620-625
[12] He W., Yuan D., Qian J., Ai X., Yang H., Cao Y., J. Mater. Chem. A, 2013, 1(37), 11397-11403
[13] Yang Z. G., Guo X. D., Xiang W., Hua W. B., Zhang J., He F. R., Wang K., Xiao Y., Zhong B. H., J. Alloys Compd., 2017, 699, 358-365
[14] Jia M. Z., Wang H. Y., Chen Y. Z., Ma C. L., Acta Phys. Sin., 2016, 65(5), 252-259(嘉明珍, 王红艳, 陈元正, 马存良. 物理学报, 2016, 65(5), 252-259)
[15] Qing R. P., Shi J. L., Xiao D. D., Zhang X. D., Yin Y. X., Zhai Y. B., Gu L., Guo Y. G., Adv. Energy Mater., 2016, 6(6), 1501914
[16] Zhao F., Xue P., Ge H. H., Li L., Wang B. F., J. Electrochem. Soc., 2016, 163(5), A690-A695
[17] Li J., Xiong S., Liu Y., Ju Z., Qian Y., Nano Energy, 2013, 2(6), 1249-1260
[18] Kang K., Meng Y. S., Bréger J., Grey C. P., Ceder G., Science, 2006, 311(5763), 977-980
[19] Wang D., Belharouak I., Zhou G., Amine K., Adv. Funct. Mater., 2013, 23(8), 1070-1075
[20] Kim S., Ma X., Ong S. P., Ceder G., Phys. Chem. Chem. Phys., 2012, 14(44), 15571-15578
[21] Ates M. N., Jia Q., Shah A., Busnaina A., Mukerjee S., Abraham K. M., J. Electrochem. Soc., 2013, 161(3), A290-A301
[22] Zheng Z., Guo X. D., Chou S. L., Hua W. B., Liu H. K., Dou S. X., Yang X. S., Electrochim. Acta, 2016, 191, 401-410
[23] Wu F., Li N., Su Y., Shou H., Bao L., Yang W., Zhang L., An R., Chen S., Adv. Mater., 2013, 25(27), 3722-3726
[24] Striebel K. A., Sakai E., Cairns E. J., J. Electrochem. Soc., 2002, 149(1), A61-A68
[25] Aurbach D., Levi M. D., Gamulski K., Markovsky B., Salitra G., Levi E., Heider U., Heider L., Oesten R., J. Power Sources, 1999, 81/82(9), 472-479

Preparation and Electrochemical Performance of Na⁺-stabilized Layered LiNi_0.6Co_0.2Mn_0.2O₂ Cathode Material for Lithium-ion Batteries

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	JIA Yanggang, SHAO Xia, CHENG Jie, WANG Pengpeng, MAO Aiqin. Preparation and Lithium Storage Performance of Pseudocapacitance-controlled Perovskite High-entropy Oxide La（Co_0.2Cr_0.2Fe_0.2Mn_0.2Ni_0.2）O₃ Anode Materials [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220157.
[2]	HOU Congcong, WANG Huiying, LI Tingting, ZHANG Zhiming, CHANG Chunrui, AN Libao. Preparation and Electrochemical Properties of N-CNTs/NiCo-LDH Composite [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220351.
[3]	BAO Junquan, ZHENG Shibing, YUAN Xuming, SHI Jinqiang, SUN Tianjiang, LIANG Jing. An Organic Salt PTO（KPD）₂ with Enhanced Performance as a Cathode Material in Lithium-ion Batteries [J]. Chem. J. Chinese Universities, 2021, 42(9): 2911.
[4]	WU Zhuoyan, LI Zhi, ZHAO Xudong, WANG Qian, CHEN Shunpeng, CHANG Xinghua, LIU Zhiliang. A Highly Efficient One-step Preparation Method of Nano-silicon and Carbon Composite for High-performance Lithium Ion Batteries [J]. Chem. J. Chinese Universities, 2021, 42(8): 2500.
[5]	YI Conghua, SU Huajian, QIAN Yong, LI Qiong, YANG Dongjie. Preparation of Lignin Nanocarbon and Its Performance as a Negative Electrode for Lithium-ion Batteries [J]. Chem. J. Chinese Universities, 2021, 42(6): 1807.
[6]	WANG Yimeng, LIU Kai, WANG Baoguo. Coating Strategies of Ni-rich Layered Cathode in LIBs [J]. Chem. J. Chinese Universities, 2021, 42(5): 1514.
[7]	MAO Eryang, WANG Li, SUN Yongming. Advances in Alloy-based High-capacity Li-containing Anodes for Lithium-ion Batteries [J]. Chem. J. Chinese Universities, 2021, 42(5): 1552.
[8]	SUN Quanhu, LU Tiantian, HE Jianjiang, HUANG Changshui. Advances in the Study of Heteratomic Graphdiyne Electrode Materials [J]. Chem. J. Chinese Universities, 2021, 42(2): 366.
[9]	ZHOU Zhan, MA Lufang, TAN Chaoliang. Preparation of Layered （NH₄）₂V₆O₁₆·H₂O Nanosheets as an Anode for Li-ion Batteries [J]. Chem. J. Chinese Universities, 2021, 42(2): 662.
[10]	GONG Shanshan, WU Tong, WANG Guange, HUANG Qing, SU Yuefeng, WU Feng. Screening of Deep Eutectic Solvent Based on Efficient Recovery of Spent Lithium⁃ion Battery Cathode Materials [J]. Chem. J. Chinese Universities, 2021, 42(10): 3151.
[11]	XIANG Houzheng, XIE Hongxiang, LI Wenchao, LIU Xiaolei, MAO Aiqin, YU Haiyun. Synthesis and Electrochemical Performance of Spinel-type High-entropy Oxides [J]. Chem. J. Chinese Universities, 2020, 41(8): 1801.
[12]	LU Di,ZHENG Chunman,CHEN Yufang,LI Yujie,ZHANG Hongmei. Synthesis of Li-rich Layers/Spinel/Carbon Composite Cathode Materials with Phenol Formaldehyde Resin and Its Electrochemical Performance^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1684.
[13]	CHEN Liangdan,ZOU Wei,WU Liang,XIA Fanjie,HU Zhiyi,LI Yu,SU Baolian. Nano-Al₂O₃ Coated Li-rich Cathode Material Li_{1. 2}Ni_0.13Co_0.13Mn_0.54O₂ for Highly Improved Lithium-ion Batteries ^† [J]. Chem. J. Chinese Universities, 2020, 41(6): 1329.
[14]	LI Xiangnan, WANG Qiuxian, FAN Yong, YU Mingming, ZHANG Huishuang, YANG Shuting. Deposition Method Synthesis of Nano-phosphorus/Biomass Carbon Composites and Their High- and Low-temperature Electrochemical Performances as Anode Material in Lithium-ion Batteries ^† [J]. Chem. J. Chinese Universities, 2019, 40(9): 1949.
[15]	YANG Jinge, LI Yujie, LU Di, CHEN Yufang, SUN Weiwei, ZHENG Chunman. Morphology Control and Lithium Storage Performance of Micro/nano Li-rich Cathode Material^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1495.