Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization†

doi:10.7503/cjcu20160196

Chem. J. Chinese Universities ›› 2016, Vol. 37 ›› Issue (9): 1740.doi: 10.7503/cjcu20160196

• Polymer Chemistry • Previous Articles Next Articles

Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization^†

YU Tian¹, XU Chengnan¹, YU Yuan¹, ZHAO Feifei¹, PAN Yiting¹, LIU Cai¹, HUANG Yongdong², ZHANG Rongyue^1,^*()

1. Department of Chemical Engineering, Beijing Institute of Petro-chemical Technology, Beijing 102617, China
2. National Key Lab of Biochemical Engineering, Institute of Process Engineering,Chinese Academy of Sciences, Beijing 100190, China

Received:2016-03-30 Online:2016-09-10 Published:2016-08-26
Contact: ZHANG Rongyue E-mail:ryzhang@iccas.ac.cn
Supported by:
† Supported by the Beijing Natural Science Foundation, China(No.2162013), the National Natural Science Foundation of China(No.51103158), the Breeding Project of Outstanding Young Teachers and Management Backbones, China(No.080318620081/037), the Cross Training Programme for High Level Graduate in Beijing Universities, China(Nos.201507, 201506) and the 2016 Undergraduate Research Training Program, China(No.2016J00079)

Abstract

Abstract:

The gigaporous microspheres based on a copolymer of glycidyl methacrylate and ethylene dimethacrylate were prepared by atom transfer radical polymerization(ATRP). The microspheres were characterized by Fourier transform infrared spectrometer, scanning electronic microscopy and mercury intrusion porosimetry. The results indicated that the microspheres by ATRP showed larger size pore and surface than those by conventional free radical polymerization(CFRP). It was observed from the morphology of the microspheres that the smaller size of particles(100—400 nm) formed the skeleton of microspheres by ATRP than CFRP method(1000 nm). Meanwhile the size of these particles by ATRP was well-distributed in comparison with CFRP. These microspheres by ATRP showed good potential in rapid separation of proteins.

Key words: High through-put, Separation support, Atom transfer radical polymerization, Gigaporous polymer microsphere

CLC Number:

O632
O658.7

TrendMD:

YU Tian, XU Chengnan, YU Yuan, ZHAO Feifei, PAN Yiting, LIU Cai, HUANG Yongdong, ZHANG Rongyue. Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization^†[J]. Chem. J. Chinese Universities, 2016, 37(9): 1740.

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References 20

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Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization^†

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