Preparation and Surface Photovoltage of Four Cu(Ⅱ/Ⅰ) Complexes

Chem. J. Chinese Universities

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Preparation and Surface Photovoltage of Four Cu(Ⅱ/Ⅰ) Complexes

ZHANG Li¹, NIU Shu-Yun^1*, JIN Jing¹, SUN Li-Ping¹, YANG Guang-Di², YE Ling²

1. School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, China;
2. Key Laboratory of Supramolecular Structure and Materials of Ministry of Education, Jilin University, Changchun 130021, China

Received:2008-07-07 Revised:1900-01-01 Online:2009-02-10 Published:2009-02-10
Contact: NIU Shu-Yun

Abstract

Abstract: Four copper coordination complexes {[Cu(phen)(H₂O)(o-tpha)]·H₂O}_n(1), [Cu₂Cl₄(phen)₂](2), [Cu₄Cl₄(bipy)₂](3) and [Cu₂Cl₂(phen)]_n(4)(bipy=2,2'-bipyridyl, phen=1,10-phenanthroline, o-H₂tpha=o-phthalic acid), were hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. Complexes 1 and 4 both possess 1D infinite structure, complex 2 is a binuclear supramolecule connected by hydrogen bonds and complex 3 is a tetranuclear cluster. The surface photovoltage spectra(SPS) of four complexes all exhibit surface photovoltage responses(SPV) in the range 300—800 nm, however, the intensity, position and numbers of response bands are different obviously. The diffe-rences are mainly attributed to their different structures, valences and coordination environments of copper ions in the four complexes.

Key words: Cu(Ⅱ)/ Cu(Ⅰ), Crystal structure, Surface photovoltage spectrum, Field-induced surface photovoltage spectrum, Electronic transtion

CLC Number:

O614.121

TrendMD:

ZHANG Li¹, NIU Shu-Yun^1*, JIN Jing¹, SUN Li-Ping¹, YANG Guang-Di², YE Ling². Preparation and Surface Photovoltage of Four Cu(Ⅱ/Ⅰ) Complexes[J]. Chem. J. Chinese Universities, doi: .

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Preparation and Surface Photovoltage of Four Cu(Ⅱ/Ⅰ) Complexes

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