Synthesis and Characterization of a New Organic-inorganic Hybrid Mesoporous Basic Catalyst

Chem. J. Chinese Universities

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Synthesis and Characterization of a New Organic-inorganic Hybrid Mesoporous Basic Catalyst

WANG Hong-Su¹, WU Shu-Jie¹, SHAO Yan-Qiu^1,2, XU Ling¹, SONG Ke¹, XU Hai-Yan¹, KAN Qiu-Bin¹*

1. Department of Physical Chemistry, College of Chemistry, Jilin University, Changchun 130021, China;
2. Department of Chemistry, Mudanjiang Normal Colledge, Mudanjiang 157012, China

Received:2007-01-23 Revised:1900-01-01 Online:2007-08-10 Published:2007-08-10
Contact: KAN Qiu-Bin

Abstract

Abstract: A hybrid mesoporous HMS silica materials were synthesized via co-condensation between tetraethylorthosilicate(TEOS) and bis[3-(trimethoxysilyl)propyl]amine(BTMSPA) by using octadecylamine as the template through the “S⁰I⁰” route. The sequential addition of TEOS and BTMSPA resulted in well-ordered porous hybrid silicates. The synthesized materials were characterized by means of X-ray diffraction, N₂ gas adsorption-desorption experiments, ²⁹Si MAS NMR and condensation reaction of benzaldehyde with 2'-hydroxyacetopheone.

Key words: Mesopore, Hybrid material, HMS mesopore material, Basic catalysis

CLC Number:

O643

TrendMD:

WANG Hong-Su¹, WU Shu-Jie¹, SHAO Yan-Qiu^1,2, XU Ling¹, SONG Ke¹, XU Hai-Yan¹, KAN Qiu-Bin¹*. Synthesis and Characterization of a New Organic-inorganic Hybrid Mesoporous Basic Catalyst[J]. Chem. J. Chinese Universities, doi: .

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Synthesis and Characterization of a New Organic-inorganic Hybrid Mesoporous Basic Catalyst

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