Electroreduction Behavior of Coumarin in an Ionic Liquid(BMIMBF4)

Chem. J. Chinese Universities

• 研究简报 • Previous Articles Next Articles

Electroreduction Behavior of Coumarin in an Ionic Liquid(BMIMBF₄)

WANG Huan; XUE Teng; ZHANG Ai-Jian; ZHANG Li; LU Jia-Xing*

Shanghai Key Laboratory of Green Chemistry and Chemical Process. East China Normal University, Shanghai 200062, China

Received:2005-05-27 Revised:1900-01-01 Online:2006-06-10 Published:2006-06-10
Contact: LU Jia-Xing

Abstract

Abstract: The electrochemical reduction of coumarin at GC electrode in 1-n-butyl-3-methylimidazolium tetrafluoroborate(BMIMBF₄) room temperature ionic liquid is reported. Coumarin exhibits a one-electron, irreversible reduction to caroanion radical, and the latter species undergoes fast dimerization to dihydrodimer. The influences of scan rate, concentration and temperature were studied by cyclic voltammetry. The results show that the reaction is diffusion controlled. The diffusion coefficient D of coumarin in BMIMBF₄ from Chronocoulometry is 5.066×10^-7 cm²/s. Furthermore, the influences of water and substituting group during the electroreduction are discussed. These preliminary electrochemical experiments show encouraging results for the use of ionic liquids in a "green" electrochemistry.

Key words: Ionic liquid, Electroreduction, Coumairn

CLC Number:

O646

TrendMD:

WANG Huan; XUE Teng; ZHANG Ai-Jian; ZHANG Li; LU Jia-Xing*. Electroreduction Behavior of Coumarin in an Ionic Liquid(BMIMBF₄)[J]. Chem. J. Chinese Universities, doi: .

[1]	CUI Wei, ZHAO Deyin, BAI Wenxuan, ZHANG Xiaodong, YU Jiang. CO₂ Absorption in Composite of Aprotic Solvent and Iron-based Ionic Liquid [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220120.
[2]	YANG Dan, LIU Xu, DAI Yihu, ZHU Yan, YANG Yanhui. Research Progress in Electrocatalytic CO₂ Reduction Reaction over Gold Clusters [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220198.
[3]	PENG Kuilin, LI Guilin, JIANG Chongyang, ZENG Shaojuan, ZHANG Xiangping. Research Progress for the Role of Electrolytes in the CO₂ Electrochemical Reduction [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220238.
[4]	SONG Dewen, WANG Mingwang, WANG Yani, JIAO Zhenmei, NING Hui, WU Mingbo. Progress of CO₂ Electroreduction to Oxalic Acid [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220248.
[5]	JI Shuangqi, JIN Zhao, GUAN Wenna, PAN Xiangyu, GUAN Tong. Preparation and Chromatographic Performance of Mixed-mode Silica Stationary Phase Modified by Double Cationic Ionic Liquid and Octadecyl Group [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220008.
[6]	CHANG Sihui, CHEN Tao, ZHAO Liming, QIU Yongjun. Thermal Degradation Mechanism of Bio-based Polybutylactam Plasticized by Ionic Liquids [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220353.
[7]	WAN Ren, SONG Fan, PENG Changjun, LIU Honglai. Group Contribution Method for Infinite Dilution Molar Conductivity of Unconventional Ions in Water [J]. Chem. J. Chinese Universities, 2021, 42(12): 3672.
[8]	WANG Man, WANG Xin, ZHOU Jing, GAO Guohua. Efficient Synthesis of Dimethyl Carbonate via Transesterification of Methanol and Ethylene Carbonate Catalyzed by Poly（ionic liquid）s [J]. Chem. J. Chinese Universities, 2021, 42(12): 3701.
[9]	ZHOU Molin, JIANG Xin, YI Ting, YANG Xiangguang, ZHANG Yibo. Improvement of Interface Stability Between Sulfide Solid Electrolyte Li₁₀GeP₂S₁₂ and Lithium Metal [J]. Chem. J. Chinese Universities, 2020, 41(8): 1810.
[10]	GAO Chong,YU Fengli,XIE Congxia,YU Shitao. Baeyer-Villiger Oxidation of Cyclic Ketones Catalyzed by Amino Alcohol Heteropoly Acid Ionic Liquid ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 1101.
[11]	GAO Naiwei, MA Qiang, HE Yonglin, WANG Yapei. Green Electronic Devices Based on Ionic Liquids ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 901.
[12]	CHENG Shifu,HU Hao,CHEN Bihua,WU Haihong,GAO Guohua,HE Mingyuan. Preparation and Electrochemical Performance of Porous Carbons Prepared from Binary Ionic Liquids ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 1048.
[13]	PIAO Huilan,MA Pinyi,QIN Zucheng,JIANG Yanxiao,SUN Ying,WANG Xinghua,SONG Daqian. Determination of Triazine Herbicides from Fruit Juice Samples Using Effervescence Assisted Microextraction Method Based on Acidic Ionic Liquid Packed Syringe [J]. Chem. J. Chinese Universities, 2020, 41(2): 228.
[14]	ZHANG Li,QIAN Mingchao,LIU Xueke,Gao Shuaitao,YU Jiang,XIE Haishen,WANG Hongbin,SUN Fengjiang,SU Xianghong. Dynamic Study of Oxidative Desulfurization by Iron-based Ionic Liquids/NHD ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 317.
[15]	WANG Nan,YAO Kaisheng,ZHAO Chenchen,LI Tianjin,LU Weiwei. Ionic Liquid-assisted Synthesis of AuPd Nanosponges and Their Catalytic Performance ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 62.

Electroreduction Behavior of Coumarin in an Ionic Liquid(BMIMBF₄)

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments