Improvement of Interface Stability Between Sulfide Solid Electrolyte Li10GeP2S12 and Lithium Metal

doi:10.7503/cjcu20200252

Abstract

Abstract: Sulfide solid electrolyte Li₁₀GeP₂S₁₂ exhibits extremely high ionic conductivity but relatively poor stability to lithium metal. After being modified by N-butyl-N-methylpiperidinium bis(fluorosulfonyl)imide together with lithium bis(fluorosulfonyl)imide, a thin and dense solid electrolyte interphase(SEI) was formed in situ at the Li|Li₁₀GeP₂S₁₂ interface. Besides, the ionic liquid with certain liquidity is able to penetrate into the interior grains of Li₁₀GeP₂S₁₂ to construct abundant lithium ion diffusion channels, which could alleviate the high impedance problem caused by the thermodynamically unstable interface. The modified Li|Li₁₀GeP₂S₁₂|Li symmetric cell attains a stable cycle life of over 1500 h with the polarization voltage of 30 mV at 0.1 mA/cm². In addition, the interface modified Li|Li₁₀GeP₂S₁₂|LiFePO₄ cell delivers an initial discharge capacity of 148.1 mA·h/g at 0.2C with the voltage range of 2.5-3.6 V and the first cycle Coulombic efficiency of 95.8%. The capacity retention is still 90.1% after 30 cycles, showing an improved cycling stability.

Key words: Sulfide solid electrolyte, Electrolyte/electrode interface, Ionic liquid

CLC Number:

O646

TrendMD:

ZHOU Molin, JIANG Xin, YI Ting, YANG Xiangguang, ZHANG Yibo. Improvement of Interface Stability Between Sulfide Solid Electrolyte Li₁₀GeP₂S₁₂ and Lithium Metal[J]. Chem. J. Chinese Universities, 2020, 41(8): 1810.

References 33

[1]	Lin D. C., Cui Y., Liu Y. Y., Nat. Nanotechnol., 2017, 12(3), 194-206
[2]	Sahu G., Lin Z., Li J., Liu Z., Dudney N., Liang C., Energy Environ. Sci., 2014, 7, 1053-1058
[3]	Evarts E. E., Nature, 2015, 526, 93-95
[4]	Goodenough J. B., Kim Y., Chem. Mater., 2010, 22, 587-603
[5]	Liu J., Xu J. Y., Lin Y., Li J., Lai Y. Q., Yuan C. F., Zhang J., Zhu K., Acta Chim. Sinica, 2014, 71(6), 869-878(刘晋, 徐俊毅, 林月, 李劼, 赖延清, 袁长福, 张锦, 朱凯. 化学学报, 2014, 71(6), 869-878)
[6]	Long L., Wang S. J., Xiao M., Meng Y. Z., J. Mater. Chem. A, 2016, 4(26), 10038-10069
[7]	Chen X., Vereecken P. M., Adv. Mater. Interfaces, 2019, 6(1), 1800899
[8]	Lu Q. W., He Y. B., Yu Q. P., Li B. H., Kaneti Y. V., Yao Y. W., Kang F. Y., Yang Q. H., Adv. Mater., 2017, 29(13), 1604460
[9]	Zhao Q., Liu X. T., Stalin S., Khan K., Archer L. A., Nature Energy, 2019, 4(5), 365-373
[10]	Buschmann H., Dölle J., Berendts S., Kuhn A., Bottke P., Wilkening M., Heitjans P., Senyshyn A., Ehrenberg H., lotnyk A., Duppel V., Kienle L., Janek J., Phys. Chem. Chem. Phys., 2011, 13(43), 19378-19392
[11]	Park M., Zhang X. C., Chung M., Less G. B., Sastry A. M., J. Power. Sources, 2010, 195(24), 7904-7929
[12]	Xu L., Tang S., Cheng Y., Wang K. Y., Liang J. Y., Liu C., Cao Y. C., Wei F., Mai L. Q., Joule, 2018, 2(10), 1991-2015
[13]	Gao Z. H., Sun H. B., Fu L., Ye F. L., Zhang Y., Luo W., Huang Y. H., Adv. Mater., 2018, 30(17), 1705702
[14]	Murayama M., Kanno R., Irie M., Ito S., Hata T., Sonoyama N., Kawamoto Y., J. Solid State Chem., 2002, 168(1), 140-148
[15]	Manthiram A., Yu X. W., Wang S. F., Nat. Rev. Mater., 2017, 2(4), 16103
[16]	Emly A., Kioupakis E., Van der ven A., Chem. Mater., 2013, 25(23), 4663-4670
[17]	Wang S., Bai Q., Nolan A. M., Liu Y. S., Gong S., Sun Q., Mo Y. F., Angew. Chem. Int. Ed., 2019, 58(24), 8039-8043
[18]	Suzuki N., Inaba T., Shiga T., Thin Solid Films, 2012, 520(6), 1821-1825
[19]	Park K. H., Bai Q., Kim D. H., Oh D. Y., Zhu Y. Z., Mo Y. F., Jung Y. S., Adv. Energy. Mater., 2018, 8(18), 1800035
[20]	Bachman J. C., Muy S., Grimaud A., Chang H., Pour N., Lux S. F., Paschos O., Maglia F., Lupart S., Lamp P., Giordano L., Shaohorn Y., Chem. Rev., 2016, 116(1), 140-162
[21]	Kanno R., Hata T., Kawamoto Y., Irie M., Solid State Ionics, 2000, 130(1/2), 97-104
[22]	Kamaya N., Homma K., Yamakawa Y., Hirayama M., Kanno R., Yonemura M., Kamiyama T., Kato Y., Hama S., Kawamoto K., Mitsui A., Nature Materials, 2011, 10(9), 682-686
[23]	Ong S. P., Mo Y. F., Richards W. D., Miara L., Lee H. S., Ceder G., Energy Environ. Sci., 2013, 6(1), 148-156
[24]	Sun Y., Yan W., An L., Wu B. B., Zhong K. F., Yang R. Z., Solid State Ionics, 2018, 44(14), 17425-17433
[25]	Zhang Z. H., Chen S. J., Yang J., Wang J. Y., Yao L. L., Yao X. Y., Cui P., Xu X. X., ACS Appl. Mater. Interfaces, 2018, 10(3), 2556-2565
[26]	Guerfi D., Dontigny P., Petitclerc C. P., Lagacé M.,Vijh A., Zaghib K., J. Power. Sources, 2010, 195(3), 845-852
[27]	Wang F. C., Zhou W. L., Chem. J. Chinese Universities, 2018, 39(11), 2529-2533(王凤春, 周万里. 高等学校化学学报, 2018, 39(11), 2529-2533)
[28]	Xiong S. Z., Xie K., Hong X. B., Chem. J. Chinese Universities, 2011, 32(11), 2645-2649(熊仕昭, 谢凯, 洪晓斌. 高等学校化学学报, 2011, 32(11), 2645-2649)
[29]	Liu X. Z., Guan X. Y., Fang Q. R., Jin Y. R., Chem. J. Chinese Universities, 2019, 40(7), 1341-1344(刘小舟, 管新宇, 方千荣, 金永日. 高等学校化学学报, 2019, 40(7), 1341-1344)
[30]	Zhang T., Yang Z., Li H. L., Zhuang Q. C., Cui Y. H., Acta Chim. Sinica, 2019, 77(6), 525-532(张桐, 杨梓, 李红亮, 庄全超, 崔艳华. 化学学报, 2019, 77(6), 525-532)
[31]	Zheng B. Z., Zhu J. P., Wang H. C., Feng M., Umeshbabu E., Li Y. X., Wu Q. H., Yang Y., ACS Appl. Mater. Interfaces, 2018, 10(30), 25473-25482
[32]	Tong B., Zhang Z. X., Liu Z. J., Peng Z. Q., Zhou Z. B., Chem. J. Chinese Universities, 2018, 39(7), 1518-1523(仝博, 张仲祥, 刘圳杰, 彭章泉, 周志彬. 高等学校化学学报, 2018, 39(7), 1518-1523)
[33]	Kobayashi Y., Miyashiro H., Yamazaki A., Mita Y., J. Power. Sources, 2020, 449, 227502

Improvement of Interface Stability Between Sulfide Solid Electrolyte Li₁₀GeP₂S₁₂ and Lithium Metal

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References 33

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	CUI Wei, ZHAO Deyin, BAI Wenxuan, ZHANG Xiaodong, YU Jiang. CO₂ Absorption in Composite of Aprotic Solvent and Iron-based Ionic Liquid [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220120.
[2]	PENG Kuilin, LI Guilin, JIANG Chongyang, ZENG Shaojuan, ZHANG Xiangping. Research Progress for the Role of Electrolytes in the CO₂ Electrochemical Reduction [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220238.
[3]	JI Shuangqi, JIN Zhao, GUAN Wenna, PAN Xiangyu, GUAN Tong. Preparation and Chromatographic Performance of Mixed-mode Silica Stationary Phase Modified by Double Cationic Ionic Liquid and Octadecyl Group [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220008.
[4]	CHANG Sihui, CHEN Tao, ZHAO Liming, QIU Yongjun. Thermal Degradation Mechanism of Bio-based Polybutylactam Plasticized by Ionic Liquids [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220353.
[5]	WAN Ren, SONG Fan, PENG Changjun, LIU Honglai. Group Contribution Method for Infinite Dilution Molar Conductivity of Unconventional Ions in Water [J]. Chem. J. Chinese Universities, 2021, 42(12): 3672.
[6]	WANG Man, WANG Xin, ZHOU Jing, GAO Guohua. Efficient Synthesis of Dimethyl Carbonate via Transesterification of Methanol and Ethylene Carbonate Catalyzed by Poly（ionic liquid）s [J]. Chem. J. Chinese Universities, 2021, 42(12): 3701.
[7]	CHENG Shifu,HU Hao,CHEN Bihua,WU Haihong,GAO Guohua,HE Mingyuan. Preparation and Electrochemical Performance of Porous Carbons Prepared from Binary Ionic Liquids ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 1048.
[8]	GAO Chong,YU Fengli,XIE Congxia,YU Shitao. Baeyer-Villiger Oxidation of Cyclic Ketones Catalyzed by Amino Alcohol Heteropoly Acid Ionic Liquid ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 1101.
[9]	GAO Naiwei, MA Qiang, HE Yonglin, WANG Yapei. Green Electronic Devices Based on Ionic Liquids ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 901.
[10]	PIAO Huilan,MA Pinyi,QIN Zucheng,JIANG Yanxiao,SUN Ying,WANG Xinghua,SONG Daqian. Determination of Triazine Herbicides from Fruit Juice Samples Using Effervescence Assisted Microextraction Method Based on Acidic Ionic Liquid Packed Syringe [J]. Chem. J. Chinese Universities, 2020, 41(2): 228.
[11]	ZHANG Li,QIAN Mingchao,LIU Xueke,Gao Shuaitao,YU Jiang,XIE Haishen,WANG Hongbin,SUN Fengjiang,SU Xianghong. Dynamic Study of Oxidative Desulfurization by Iron-based Ionic Liquids/NHD ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 317.
[12]	WANG Nan,YAO Kaisheng,ZHAO Chenchen,LI Tianjin,LU Weiwei. Ionic Liquid-assisted Synthesis of AuPd Nanosponges and Their Catalytic Performance ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 62.
[13]	LI Chenguang, HUA Er, LIU Tianxia. Tribological Behaviour of Protic Ionic Liquid Composed of 2-Ethylhexylethylenediaminium Cation and Trifluoromethanesulfonate Anion as Liquid Paraffin Additive^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1411.
[14]	LIU Xiaozhou, GUAN Xinyu, FANG Qianrong, JIN Yongri. Three-dimensional Covalent Organic Frameworks Synthesized by Room Temperature Ionic Liquid Method^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1341.
[15]	DING Zhongxie,LIANG Jinhua,LIU Zhen,SHEN Jiecan,ZHANG Feng,REN Xiaoqian,JIANG Min. Functional Specific Heteropoly Acid Ionic Liquid Catalyzed Direct Esterification of Aqueous Succinate Solution^† [J]. Chem. J. Chinese Universities, 2019, 40(5): 1029.