Co-templates Synthesis and Characterization of a New Two-dimensional Co-containing Aluminophosphate [C4H11N]0.77[C4H12N]0.23[C3H12N2]2[H3O]2[Co0.23Al5.77P8O34]†

doi:10.7503/cjcu20140206

Abstract

Abstract:

In the presence of diethylamine and 1,2-diaminopropane, a new microporous cobalt-containing aluminophosphate compound [C₄H₁₁N]_0.77[C₄H₁₂N]_0.23[C₃H₁₂N₂]₂[H₃O]₂[C $o 0.2 3$ Al_5.77P₈ $O 3 2$ ](1) was synthesized. The structure of compound 1 was determined by single-crystal X-ray diffraction(XRD) analysis and further characterized by X-ray powder diffraction, thermogravimetric analysis(TG/DTA), inductively coupled atomic emission spectrometry(ICP-AES), CHN, Solid-UV-Vis spectrometry and scanning electron microscopy(SEM). It crystallizes in the triclinic system, space group P $1 -$ , with a=0.95029(19) nm, b=1.2689(3) nm, c=1.2987(3) nm, α=118.70(3)°, β=97.64(3)°, γ=99.72(3)°, V=1.3117(5) nm³, Z=1. The structure are built up from strict alternation of CoO₄/AlO₄and PO₃(=O) units. It contains 12-membered ring channel along [001] direction. The molar ratio of Co to Al is 1∶25.1. We also calculated the interaction energy and studied the co-template role of those two amines by the molecular dynamics method.

Key words: Heteroatom containing aluminophosphate, Layered structure, Solvothermal synthesis, Co-template role

CLC Number:

O611.4

TrendMD:

ZHU Jingran, LI Ke, YAN Yan, LI Xu, SONG Xiaowei. Co-templates Synthesis and Characterization of a New Two-dimensional Co-containing Aluminophosphate [C₄ $H 1 1$ N]_0.77[C₄ $H 1 2$ N]_0.23[C₃H₁₂N₂]₂[H₃O]₂[Co_0.23Al_5.77P₈ $O 3 4$ ]^†[J]. Chem. J. Chinese Universities, 2014, 35(6): 1130.

Figures/Tables 7

Table 1 Crystal data and structure refinement parameters for compound 1

Empirical formula	C₁₀H_41.23Al_5.77 Co_0.23N₅O₃₄P₈	Calculated density/(Mg·m^-3)	1.479
Crystal system	Triclinic	Absorption coefficient/mm^-1	0.456
Space group	P $1 -$	F(000)	589
a/nm	0.95029(19)	Limiting indices	-12≤h≤12,-15≤k≤16,-16≤l≤16
b/nm	1.2689(3)	Reflections collected/unique[R(int)=0.0442]	12505/5845
c/nm	1.2987(3)	Refinement method	Full-matrix least-squares on F²
α/(°)	118.70(3)	Data/restraints/parameters	5845/82/355
β/(°)	97.64(3)	Goodness-of-fit on F²	1.083
γ/(°)	99.72(3)	Final R indices [I > 2σ(I)]	R₁=0.0532, wR₂=0.1678
V/nm³, Z	1.3117(5), 1	R indices(all data)	R₁=0.0621, wR₂=0.1771

Table 1 Crystal data and structure refinement parameters for compound 1

Empirical formula	C₁₀H_41.23Al_5.77 Co_0.23N₅O₃₄P₈	Calculated density/(Mg·m^-3)	1.479
Crystal system	Triclinic	Absorption coefficient/mm^-1	0.456
Space group	P $1 -$	F(000)	589
a/nm	0.95029(19)	Limiting indices	-12≤h≤12,-15≤k≤16,-16≤l≤16
b/nm	1.2689(3)	Reflections collected/unique[R(int)=0.0442]	12505/5845
c/nm	1.2987(3)	Refinement method	Full-matrix least-squares on F²
α/(°)	118.70(3)	Data/restraints/parameters	5845/82/355
β/(°)	97.64(3)	Goodness-of-fit on F²	1.083
γ/(°)	99.72(3)	Final R indices [I > 2σ(I)]	R₁=0.0532, wR₂=0.1678
V/nm³, Z	1.3117(5), 1	R indices(all data)	R₁=0.0621, wR₂=0.1771

Fig.1 Experimental(a) and simulated(b) XRD patterns of compound 1

Fig.2 SEM image of compound 1

Fig.3 Asymmetric unit of compound 1(without diethylamine) The thermal ellipsoids are shown at 50% probability.

Fig.4 Framework of compound 1 viewed along [001] direction

Fig.5 TG(a) and DTA(b) curves of compound 1

Fig.6 Solid-UV-Vis spectrum of compound 1

References 47

[1]	Wilson S. T., Lok B. M., Messina C. A., Cannan T. R., Flanigen E. M., J. Am. Chem. Soc., 1982, 104, 1146—1147
[2]	Yu J., Xu R., Acc. Chem. Res., 2003, 36(7), 481—490
[3]	Yu J., Xu R., Chem. Soc. Rev., 2006, 35, 593—604
[4]	Yan W., Song X., Xu R., Micropor. Mesopor. Mater., 2009, 123, 50—62
[5]	Yu J., Xu R., Acc. Chem. Res., 2010, 43(9), 1195—1204
[6]	Tong X., Xu J., Li X., Li Y., Yan W., Yu J., Deng F., Sun H., Xu R., Micropor. Mesopor. Mater., 2013, 176, 112—122
[7]	Oliver S., Kuperman A., Lough A., Ozin G. A., Chem. Mater., 1996, 8, 2391—2398
[8]	Wang Z., Yu J., Xu R., Chem. Soc. Rev., 2012, 41, 1729—1741
[9]	Bruker AXS Inc., SAINT, Madison, WI, 2000
[10]	Bruker AXS Inc., SHELXTL, Madison, WI, 2000
[11]	Liu Z., Song X., Li J., Li Y., Yu J., Xu R., Inorg. Chem., 2012, 51, 1969—1974
[12]	Peng L., Li J. Y., Yu J. H., Li Y., Guo M., Xu R. R., Chem. J. Chinese Universities, 2004, 25(11), 1981—1989
	(彭莉, 李激扬, 于吉红, 李乙, 郭敏, 徐如人.高等学校化学学报, 2004,25(11), 1981—1989)
[13]	Lu H. Y., Tong X. Q., Yan Y., Yan W. F., Yu J. H., Xu R. R., Chem. J. Chinese Universities, 2013, 34(7), 1571—1575
	(卢慧英, 仝晓强, 颜岩, 闫文付, 于吉红, 徐如人.高等学校化学学报, 2013,34(7), 1571—1575)
[14]	Shao L., Li Y., Wang X. F., Yu J. H., Chem. J. Chinese Universities, 2013, 34(8), 1806—1811
	(邵浪, 李乙, 王晓方, 于吉红.高等学校化学学报, 2013,34(8), 1806—1811)
[15]	Gao Q., Li B., Chen J., Li S., Xu R., Williams I., Zheng J., Barber D., J. Solid State Chem., 1997, 129, 37—44
[16]	Chippindale A. M., Natarajan S., Thomas J. M., Jones R. H., J. Solid State Chem., 1994, 111, 18—25
[17]	Togashi N., Yu J., Zheng S., Sugiyama K., Hiraga K., Terasaki O., Yan W., Qiu S., Xu R., J. Mater. Chem., 1998, 8, 2827—2830
[18]	Yao Y., Natarajan S., Chen J., Pang W., J. Solid State Chem., 1999, 146, 458—463
[19]	Yu J., Li J., Sugiyama K., Togashi N., Terasaki O., Hiraga K., Zhou B., Qiu S., Xu R., Chem. Mater., 1999, 11, 1727—1732
[20]	Tuel A., Gramlich V., Baerlocher C., Micropor. Mesopor. Mater., 2001, 46, 57—66
[21]	Tuel A., Gramlich V., Baerlocher C., Micropor. Mesopor. Mater., 2002, 56, 119—130
[22]	Jones R.H., Chippindale A. M., Natarajan S., Thomas J. M., J. Chem. Soc.,Chem. Commun., 1994, 565—566
[23]	Tuel A., Jorda J. L., Gramlich V., Baerlocher C., J. Solid State Chem., 2005, 178, 782—791
[24]	Chippindale A.M., Cowley A. R., Huo Q., Jones R. H., Law A. D., Thomas J. M., Xu R., J. Chem. Soc.,Dalton Trans., 1997, 2639—2643
[25]	Yuan H., Zhu G., Chen J., Chen W., Yang G., Xu R., J. Solid State Chem., 2000, 151, 145—149
[26]	Thomas J.M., Jones R. H., Xu R., Chen J., Chippindale A. M., Natarajan S., Cheetham A. K., J. Chem. Soc.,Chem. Commun., 1992, 929—931
[27]	Bruce D. A., Wilkinson A. P., White M. G., Bertrand J. A., J. Solid State Chem., 1996, 125, 228—233
[28]	Jones R.H., Thomas J. M., Xu R., Huo Q., Cheetham A. K., Powell A. V., J. Chem. Soc.,Chem. Commun., 1991, 1266—1268
[29]	Tuel A., Gramlich V., Baerlocher C., J. Solid State Chem., 2004, 177, 2484—2493
[30]	Vidal L., Marichal C., Gramlich V., Patarin J., Babelica Z., Chem. Mater., 1999, 11, 2728—2736
[31]	Yu J., Terasaki O., Williams I. D., Quiv S., Xu R., Supramolecular Science, 1998, 5, 297—302
[32]	Yan W., Yu J., Li Y., Shi Z., Xu R., J. Solid State Chem., 2002, 167, 282—288
[33]	Gray M. J., Jasper J. D., Wilkinson A. D., Chem. Mater., 1997, 9, 976—980
[34]	Morgan K., Gainsford G., Milestone N., J. Chem. Soc.,Chem. Commun., 1995, 425—426
[35]	Oliver S., Kuperman A., Lough A., Ozin G. A., Inorg. Chem., 1996, 35(22), 6373—6380
[36]	Bruce D.A., Wilkinson A. P., White M. G., Bertrand J. A., J. Chem. Soc.,Chem. Commun., 1995, 2059—2060
[37]	Simon N., Loiseau T., Férey G., Solid State Sci., 2000, 2, 389—395
[38]	Williams D. J., Kruger J. S., McLeroy A. F., Wilkinson A. P., Hanson J. C., Chem. Mater., 1999, 11, 2241—2249
[39]	Williams I.D., Gao Q., Chen J., Ngai L., Lin Z., Xu R.,Chem. Commun., 1996, 1781—1782
[40]	Verberckmoes A. A., Uytterhoeven M. G., Schoonheydt R. A., Zeolite, 1997, 19, 180—189
[41]	Guo X., Ma Q., Guo X., Ding W., Chen Y.,Chem. Commun., 2009, 3443—3445
[42]	Guo X., Guo X., Tao W., Chen L., Peng L., Ding W., Chem. Commun., 2011, 47, 10061—10063
[43]	Song X., Li Y., Gan L., Wang Z., Yu J., Xu R., Angew. Chem. Int. Ed., 2009, 48, 314—317
[44]	Rajic N., Logar N. Z., Golobic A., Kaucic V., J. Phys. Chem. Solids, 2003, 64, 1097—1103
[45]	Vidal L., Gramlich V., Patarin J., Gabelica Z., Eur. J. Solid State Inorg. Chem., 1998, 35, 545—563
[46]	Mayo S. L., Olafson B. D., Goddard W. A., J. Phys. Chem., 1990, 94, 8897—8909
[47]	Accelrys Software Inc., Materials Studio V4.0, San Diego, 2005

Co-templates Synthesis and Characterization of a New Two-dimensional Co-containing Aluminophosphate [C₄ $H 1 1$ N]_0.77[C₄ $H 1 2$ N]_0.23[C₃H₁₂N₂]₂[H₃O]₂[Co_0.23Al_5.77P₈ $O 3 4$ ]^†

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 7

References 47

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[2]	CHEN Chongan, YANG Guoyu. Two B₅O_n（n=11， 12） Cluster-based Borates with Deep UV Cutoff Edge [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210711.
[3]	YU Qiangmin, ZHANG Zhiyuan, LUO Yuting, LI Yang, CHENG Huiming, LIU Bilu. Solvothermal Synthesis of 2D Metallic Transition Metal Disulfides for Efficient Electrocatalytic Hydrogen Evolution [J]. Chem. J. Chinese Universities, 2021, 42(2): 654.
[4]	WANG Dongmei,LIU Zihua,LI Guanghua,LIU Yunling,LI Chunxia. Synthesis, Structure and Fluorescent Property of Indium-based Bimetallic Metal-organic Frameworks^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1886.
[5]	MA Benhua, PENG Yu, HUA Jia, SHI Zhan. Synthesis and Characterization of Coordination Polymers Based on 5-Azidoisophthalic Acid^† [J]. Chem. J. Chinese Universities, 2015, 36(2): 215.
[6]	ZHAO Lun, ZHANG Min, SUN Erjun, WANG Xiaofeng, WANG Zichen. Synthesis, Structures and Photochemical Properties of Two New Cd(II) Metal-organic Frameworks Isolated from the Same Reaction System^† [J]. Chem. J. Chinese Universities, 2015, 36(12): 2380.
[7]	LI Tao, XIA Youfu. Preparation and Photovoltaic Performance of Reduced Graphene Oxide-CuInS₂ Composite [J]. Chem. J. Chinese Universities, 2014, 35(3): 461.
[8]	ZHUANG Mixue, WEI Aixiang, LIU Jun, YAN Zhiqiang, ZHAO Yu. Solvothermal Preparation and Growth Mechanism of CuInS₂ Thin Films of Nanosheet Array [J]. Chem. J. Chinese Universities, 2014, 35(11): 2310.
[9]	ZHANG Yue-Biao,ZHOU Hao-Long,HE Chun-Ting,XUE Wei,ZHANG Jie-Peng, CHEN Xiao-Ming*. Synthesis and Properties on Three Coordination Polymers of 4-(Pyridin-3-yl)benzoate with Zn(Ⅱ), Cd(Ⅱ) and Mn(Ⅱ) [J]. Chem. J. Chinese Universities, 2011, 32(3): 497.
[10]	GE Gen-Wu LIU Mei-Pin NI Zhi-Gang Hong-Bin DU. Synthesis, Characterization and Fluorescent Properties of Two 3D Open-framework Rare-earth Sulfates [Ln4(H2O)4(SO4)10](C4N2H12)4(H2O)4(Ln=Gd, Eu) [J]. Chem. J. Chinese Universities, 2011, 32(3): 644.
[11]	HUANG Cai-Xia, GUO Ming-Yi, ZHANG Feng, SUN Fu-Xing, ZHU Guang-Shan*. Solvothermal Synthesis of Mesoporous TiO2 Spheres with Controllable Pore Size [J]. Chem. J. Chinese Universities, 2011, 32(12): 2743.
[12]	TIAN Zhen-Fen¹, SONG Tian-You^1,2, FAN Yong¹, HUANG Liang-Liang¹, WANG Li^1. Solvothermal Synthesis and Characterization of One-dimensional Chained Indium-Sulfate [J]. Chem. J. Chinese Universities, 2009, 30(3): 446.
[13]	WANG Sui-Jun, ZHAO Yu-Juan, ZHAO Chun-Song, XIA Ding-Guo*. Synthesis and Electrochemical Behavior of Li-rich Cathode Materials Li[Ni_xLi_1/3-2x/3Mn_2/3-x/3]O₂(x=1/5, 1/4, 1/3) in the Lithium-ion Battery [J]. Chem. J. Chinese Universities, 2009, 30(12): 2358.
[14]	XIA Dao-Cheng¹, YU Shu-Kun², MA Chun-Yu¹, CHENG Chuan-Hui^1,2, GUO Zhen-Qiang², JI Dong-Mei², FAN Zhao-Qi^1,2, DU Xi-Guang⁴, WANG Xu³, DU Guo-Tong^1,2*. Directly Solvothermal Synthesis of Copper Phthalocyanine Crystals [J]. Chem. J. Chinese Universities, 2008, 29(2): 244.
[15]	REN Hong¹, XU Jia-Ning², YU Lian-Xiang², YE Jun-Wei³, BI Ming-Hui¹, ZHANG Ping², SONG Tian-You¹. Hydrothermal Synthesis and Structure Characterization of a 2D Coordination Polymer [Cu(ox)(4,4'-bpy)]_n [J]. Chem. J. Chinese Universities, 2007, 28(6): 1014.