Synthesis and Structure Characterization of Ruthenium Porphyrin Axial  Complexes

Chem. J. Chinese Universities

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Synthesis and Structure Characterization of Ruthenium Porphyrin Axial Complexes

BAO Xiao-Ping¹; WANG Lei¹; WANG Kai¹; ZHANG Zhi¹; GUO Jian-Ping²; LI Zao-Ying^1*

1. College of Chemistry and Molecular Sciences, Wuhan University,
Wuhan 430072, China;
2. Department of Chemistry, Hong Kong Baptist University, Hong Kong, China

Received:2005-11-10 Revised:1900-01-01 Online:2006-07-10 Published:2006-07-10
Contact: LI Zao-Ying

Abstract

Abstract: A simple synthetic method was described i.e., via the reaction of ruthenium carbonylporphyrin(1) and dioxygenruthenium porphyrin(2) with different aminocarboxylates, a series of ruthenium porphyrins(4a-4c and 5a-5d) with monoaminocarboxylate carbonyl and diaminocarboxylates as axial ligands were obtained respectively. All compounds were confirmed by IR, 1H NMR, MS spectra and the molecular structure of compound(4a) was determined by X-ray singlecrystal diffraction. This study will provide significant help for investigations on interactions between mthenium porphyrin and biomicromolecules.

Key words: Ruthenium porphyrin, Synthesis, Structure characterization, Crystal structure

CLC Number:

O614
O626.13

TrendMD:

BAO Xiao-Ping¹; WANG Lei¹; WANG Kai¹; ZHANG Zhi¹; GUO Jian-Ping²; LI Zao-Ying^1*

. Synthesis and Structure Characterization of Ruthenium Porphyrin Axial Complexes [J]. Chem. J. Chinese Universities, doi: .

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Synthesis and Structure Characterization of Ruthenium Porphyrin Axial Complexes

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